Atkins' Physical Chemistry
Atkins' Physical Chemistry
11th Edition
ISBN: 9780198769866
Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES
Publisher: Oxford University Press
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Chapter 16, Problem 16A.10AE
Interpretation Introduction

Interpretation:

The vapor pressure of the solid compound with molar mass 100 g mol1 has to be calculated.

Concept introduction:

The process of conversion of particles of a substance from a liquid state to gaseous state below the boiling point of the substance is known as evaporation.  At a temperature lower than the boiling point of a liquid, the particles are in equilibrium with liquid state and gaseous state.  The particles in the gas state exert vapor pressure.

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Please answer the question and provide a detailed drawing of the structure. If there will not be a new C – C bond, then the box under the drawing area will be checked.  Will the following reaction make a molecule with a new C – C bond as its major product:  Draw the major organic product or products, if the reaction will work. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry.
Please do not use AI.  AI cannot "see" the molecules properly, and it therefore gives the wrong answer while giving incorrect descriptions of the visual images we're looking at.  All of these compounds would be produced (I think).  In my book, I don't see any rules about yield in this case, like explaining that one product would be present in less yield for this reason or that reason.  Please explain why some of these produce less yield than others.
Please answer the question and provide detailed explanations.

Chapter 16 Solutions

Atkins' Physical Chemistry

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