Chapter 16, Problem 16.39P

(a)

Interpretation Introduction

Interpretation:

Integrated rate laws used to determine reaction order has to be explained and also the reaction order in each of the cases.

Concept introduction:

Integrated Rate law of zero order reaction: The reaction rate is directly proportional to the concentration of R raised to the first power.

${\text{[R]}}_{\text{t}}\text{= -k t}\text{+}{\text{[R]}}_{\text{0}}$

Integrated Rate law of first order reaction: $\text{ln}\frac{{\text{[R]}}_{\text{t}}}{{\text{[R]}}_{\text{0}}}\text{ = -k t}$

Integrated Rate law of Second order reaction: $\frac{\text{1}}{{\text{[R]}}_{\text{t}}}\text{ - }\frac{\text{1}}{{\text{[R]}}_{\text{0}}}\text{ = kt}$

(b)

Interpretation Introduction

Interpretation:

Integrated rate laws used to determine reaction order has to be explained and also the reaction order in each of the cases.

Concept introduction:

Integrated Rate law of zero order reaction: The reaction rate is directly proportional to the concentration of R raised to the first power.

${\text{[R]}}_{\text{t}}\text{= -k t}\text{+}{\text{[R]}}_{\text{0}}$

Integrated Rate law of first order reaction: $\text{ln}\frac{{\text{[R]}}_{\text{t}}}{{\text{[R]}}_{\text{0}}}\text{ = -k t}$

Integrated Rate law of Second order reaction: $\frac{\text{1}}{{\text{[R]}}_{\text{t}}}\text{ - }\frac{\text{1}}{{\text{[R]}}_{\text{0}}}\text{ = kt}$

(c)

Interpretation Introduction

Interpretation:

Integrated rate laws used to determine reaction order has to be explained and also the reaction order in each of the cases.

Concept introduction:

Integrated Rate law of zero order reaction: The reaction rate is directly proportional to the concentration of R raised to the first power.

${\text{[R]}}_{\text{t}}\text{= -k t}\text{+}{\text{[R]}}_{\text{0}}$

Integrated Rate law of first order reaction: $\text{ln}\frac{{\text{[R]}}_{\text{t}}}{{\text{[R]}}_{\text{0}}}\text{ = -k t}$

Integrated Rate law of Second order reaction: $\frac{\text{1}}{{\text{[R]}}_{\text{t}}}\text{ - }\frac{\text{1}}{{\text{[R]}}_{\text{0}}}\text{ = kt}$