Solutions Manual For Chemistry: Structure And Properties
2nd Edition
ISBN: 9780134460697
Author: Tro
Publisher: PEARSON
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Chapter 16, Problem 162E
Interpretation Introduction
To determine:
pH of solution.
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Chapter 16 Solutions
Solutions Manual For Chemistry: Structure And Properties
Ch. 16 - In the opening section of this chapter text, we...Ch. 16 - What are the general physical and chemical...Ch. 16 - What is a carboxylic acid? Give an example?Ch. 16 - What is the Arrhenius definition of an acid? Of a...Ch. 16 - What is a hydronium ion? Does H+ exist in solution...Ch. 16 - What is the Bronsted-Lowry definition of an acid?...Ch. 16 - Why is there more than one definition of acid-base...Ch. 16 - Describe amphoteric behavior and give an example.Ch. 16 - What is a conjugate acid-base pair? Provide an...Ch. 16 - Explain the difference between a strong acid and a...
Ch. 16 - For a binary acid, H-Y, which factors affect the...Ch. 16 - Which factors affect the relative acidity of an...Ch. 16 - What are diprotic and triprotic acids? List an...Ch. 16 - Define the acid ionization constant and explain...Ch. 16 - Write an equation for the autoionization of water...Ch. 16 - What happens to the [OH-] of a solution when the...Ch. 16 - Define pH. What pH range is considered acidic?...Ch. 16 - Define pOH. What pOH range is considered acidic?...Ch. 16 - In most solutions containing a strong or weak...Ch. 16 - When calculating [H3O+] for weak acid solutions,...Ch. 16 - What is the percent ionization of an acid? Explain...Ch. 16 - In calculating [H3O+] for a mixture of a strong...Ch. 16 - Write a generic equation showing how a weak base...Ch. 16 - How can you identified if an anion will act as a...Ch. 16 - What is the relationship between the acid...Ch. 16 - What kinds of cations act as weak acids? List some...Ch. 16 - When calculating the [H3O+] for a polyprotic acid,...Ch. 16 - For a weak diprotic acid H2X, what is the...Ch. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Identify each substance as an acid or a base and...Ch. 16 - Identify each substance as an acid or a base and...Ch. 16 - In each reaction, identify the Bronsted-Lowry...Ch. 16 - In each reaction, identify the Bronsted-Lowry...Ch. 16 - Write the formula for the conjugate base of each...Ch. 16 - Write the formula for the conjugate acid of each...Ch. 16 - Both H2O and H2PO4 are amphoteric. Write an...Ch. 16 - Both HCO3 and HS are amphoteric. Write an equation...Ch. 16 - Prob. 39ECh. 16 - Based on molecular structure, arrange the binary...Ch. 16 - Based on their molecular structure, pick the...Ch. 16 - Based on molecular structure, arrange the oxyacids...Ch. 16 - Prob. 43ECh. 16 - Which is a stronger base, PO43 or AsO43 ? Explain.Ch. 16 - Classify each acid as strong or weak. If the acid...Ch. 16 - Classify each acid as strong or weak. If the acid...Ch. 16 - The three diagrams represent three different...Ch. 16 - Rank the solutions in order of decreasing [H3O+] :...Ch. 16 - Calculate [OH-] in each aqueous solution at 25°C,...Ch. 16 - Calculate [H3O+] in each aqueous solution at 25°C,...Ch. 16 - Calculate the pH and pH of each solution....Ch. 16 - Calculate [H3O+] and [OH-] for each solution. pH =...Ch. 16 - Complete the table. (All solutions are at 25°C.)...Ch. 16 - Prob. 54ECh. 16 - all equilibrium constants, the value of Kw depends...Ch. 16 - The value of KWincreases with temperature. Is the...Ch. 16 - Calculate the pH of each acid solution. Explain...Ch. 16 - Find the concentration of H3O+, to the correct...Ch. 16 - For each strong acid solution, determine [H3O+],...Ch. 16 - Prob. 60ECh. 16 - What mass of HI should be present in 0.250 L of...Ch. 16 - Prob. 62ECh. 16 - What is the pH of solution in which 224 mL of...Ch. 16 - What volume of a concentrated HCl solution, which...Ch. 16 - Determine the [H3O+] and pH of a 0.100 M solution...Ch. 16 - Prob. 66ECh. 16 - Determine the pH of an HNO2 solution of each...Ch. 16 - Determine the pH of an HF solution of each...Ch. 16 - If 15.0 mL of glacial acetic acid (pure HC2H3O2)...Ch. 16 - Calculate the pH of a formic acid solution that...Ch. 16 - A 0.185 M solution of a weak acid (HA) has a pH of...Ch. 16 - Prob. 72ECh. 16 - Determine the percent ionization of a 0.125 M HCN...Ch. 16 - Determine the percent ionization of a 0.225 M...Ch. 16 - Calculate the percent ionization of an acetic acid...Ch. 16 - Calculate the percent ionization of a formic acid...Ch. 16 - A 0.148 M solution of a monoprotic acid has a...Ch. 16 - Prob. 78ECh. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Find the pH of each mixture of acids. 0.115 M in...Ch. 16 - Find the pH of each mixture of acids. 0.075 M in...Ch. 16 - For each strong base solution, determine [OH-],...Ch. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - Determine the [OH-], pH, and pOH of a 0.15 ammonia...Ch. 16 - Determine the [OH-], pH, and pOH of a solution...Ch. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - Determine if each anion is basic or neutral. For...Ch. 16 - Determine whether each anion is basic or neutral....Ch. 16 - Prob. 99ECh. 16 - Determine the [OH-] and pH of a solution is 0.250...Ch. 16 - Determine whether each cation is acidic or...Ch. 16 - Prob. 102ECh. 16 - Determine if each salt will form a solution that...Ch. 16 - Prob. 104ECh. 16 - Prob. 105ECh. 16 - Prob. 106ECh. 16 - Prob. 107ECh. 16 - Prob. 108ECh. 16 - Prob. 109ECh. 16 - Prob. 110ECh. 16 - Prob. 111ECh. 16 - Prob. 112ECh. 16 - Write chemical equations and corresponding...Ch. 16 - Prob. 114ECh. 16 - Prob. 115ECh. 16 - Calculate the [H3O+] and pH of each polyprotic...Ch. 16 - Calculate the concentration of each species in a...Ch. 16 - Calculate the concentration of each species in a...Ch. 16 - Calculate the [H3O+] and pH of each H2S04...Ch. 16 - Consider a 0.10 M solution of a weak polyprotic...Ch. 16 - Classify each species as a Lewis acid or a Lewis...Ch. 16 - Prob. 122ECh. 16 - Prob. 123ECh. 16 - Prob. 124ECh. 16 - Prob. 125ECh. 16 - Based on these molecular views, determine whether...Ch. 16 - The binding of oxygen by hemoglobin in the blood...Ch. 16 - Carbon dioxide dissolves in water according to the...Ch. 16 - People often take Milk of Magnesia to reduce the...Ch. 16 - Lakes that have been acidified by acid rain (which...Ch. 16 - Acid rain over the Great lakes has a pH of about...Ch. 16 - White wines tend to be more acidic than red wines....Ch. 16 - Common aspirin is acetylsalicylic acid, which has...Ch. 16 - The AIDS drug zalcitabine (also known as ddC) is a...Ch. 16 - Determine the pH of each solution. 0.0100MHCIO4...Ch. 16 - Determine the pH of each solution. 0.0650M HNO3...Ch. 16 - Determine the pH of each two-component solution....Ch. 16 - Determine the pH of each two-component solution....Ch. 16 - Write net ionic equations for the reactions that...Ch. 16 - Prob. 140ECh. 16 - The pH of a 1.00 M solution of urea, a weak...Ch. 16 - Prob. 142ECh. 16 - Lactic acid is a weak acid found in milk. Its...Ch. 16 - Prob. 144ECh. 16 - A student mistakenly calculates the pH of a 1.0107...Ch. 16 - When 2.55 g of an unknown weak acid (HA) with a...Ch. 16 - Prob. 147ECh. 16 - To what volume should you dilute 1 L of a solution...Ch. 16 - HA, a weak acid, with Ka=1.0108 , also forms the...Ch. 16 - Prob. 150ECh. 16 - Prob. 151ECh. 16 - To 1.0 L of a 0.30 M solution of HCIO2 is added...Ch. 16 - A mixture of Na2CO3 and NaHCO3 has a mass of 82.2...Ch. 16 - Prob. 154ECh. 16 - Prob. 155ECh. 16 - Prob. 156ECh. 16 - Prob. 157ECh. 16 - Prob. 158ECh. 16 - Without referring to the text, go around your...Ch. 16 - Prob. 160ECh. 16 - Prob. 161ECh. 16 - Prob. 162ECh. 16 - Prob. 163ECh. 16 - Prob. 164ECh. 16 - Identify the conjugate base in the reaction shown...Ch. 16 - Which pair is a Bronsted-Lowry conjugate acid-base...Ch. 16 - Which acid has the largest Ka: HClO2(aq),...Ch. 16 - Consider the given acid ionization constants and...Ch. 16 - What is the OH- concentration in an aqueous...Ch. 16 - An HNO3(aq) solution has a pH of 1.75. What is the...Ch. 16 - Find the pH of a 0.350 M aqueous benzoic acid...Ch. 16 - Find the pH of a 0.155 M HClO2(aq) solution. For...Ch. 16 - 9. Calculate the percent ionization of 1.45 M...Ch. 16 - Consider two aqueous solutions of nitrous acid...Ch. 16 - What is the [OH-] in a 0.200 M solution of...Ch. 16 - Which ion will be basic in aqueous solution? HSO4-...Ch. 16 - Which compound will form an acidic solution when...Ch. 16 - Find the pH of 0.175 M NaCN solution. For HCN,...Ch. 16 - What is the concentration of X2- in a 0.150 M...
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- Using the diagrams shown in Problem 10-37, which of the four acids is the weakest acid?arrow_forwardThe base ethylamine (CH3CH2NH2) has a Kb of. A closely related base, ethanolamine(HOCH2CH2NH2), has a Kb of 3.2105. (a) Which of the two bases is stronger? (b) Calculate the pH of a 0.10M solution of the strong base?arrow_forwardThe pH of a 0.10-M solution of propanoic acid, CH3CH2COOH, a weak organic acid, is measured at equilibrium and found to be 2.93 at 25 °C. Calculate the Ka of propanoic acid.arrow_forward
- What is the pH of a solution obtained by adding 13.0 g of NaOH to 795 mL of a 0.200 M solution of Sr(OH)2? Assume no volume change after NaOH is added.arrow_forwardEstimate the pH that results when the following two solutions are mixed. a) 50 mL of 0.3 M CH3COOH and 50 mL of 0.4 M KOH b) 100 mL of 0.3 M CH3COOH and 50 mL of 0.4 M NaOH c) 150 mL of 0.3 M CH3COOH and 100 mL of 0.3 M Ba(OH)2 d) 200 mL of 0.3 M CH3COOH and 100 mL of 0.3 M Ba(OH)2arrow_forward8-17 For each of the following, tell whether the base is strong or weak. (a) NaOH (b) Sodium acetate (c) KOH (d) Ammonia (e) Waterarrow_forward
- Methylammonium chloride is a salt of methylamine, CH3NH2. A 0.10 M solution of this salt has a pH of 5.82. a Calculate the value for the equilibrium constant for the reaction CH3NH3++H2OCH3NH2+H3O+ b What is the Kb value for methylamine? c What is the pH of a solution in which 0.450 mol of solid methylammonium chloride is added to 1.00 L of a 0.250 M solution of methylamine? Assume no volume change.arrow_forwardFind the value of Kb for the conjugate base of the following organic acids. (a) picric acid used in the manufacture of explosives; K a =0.16 (b) trichloroacetic acid used in the treatment of warts; K a =0.20arrow_forwardFind [OH+], [OH-] and the pH of the following solutions. (a) 30.0 mL of a 0.216 M solution of HCI diluted with enough water to make 125 mL of solution. (b) A solution made by dissolving 275 mL of HBr gas at 25C and 1.00 atm in enough water to make 475 mL of solution. Assume that all the HBr dissolves in water.arrow_forward
- Pure liquid ammonia ionizes in a manner similar to that of water. (a) Write the equilibrium for the autoionization of liquid ammonia. (b) Identify the conjugate acid form and the base form of the solvent. (c) Is NaNH2 an acid or a base in this solvent? (d) Is ammonium bromide an acid or a base in this solvent?arrow_forwardFor conjugate acidbase pairs, how are Ka and Kb related? Consider the reaction of acetic acid in water CH3CO2H(aq)+H2O(l)CH3CO2(aq)+H3O+(aq) where Ka = 1.8 105 a. Which two bases are competing for the proton? b. Which is the stronger base? c. In light of your answer to part b. why do we classify the acetate ion (CH3CO2) as a weak base? Use an appropriate reaction to justify your answer. In general, as base strength increases, conjugate acid strength decreases. Explain why the conjugate acid of the weak base NH3 is a weak acid. To summarize, the conjugate base of a weak acid is a weak base and the conjugate acid of a weak base is a weak acid (weak gives you weak). Assuming Ka for a monoprotic strong acid is 1 106, calculate Kb for the conjugate base of this strong acid. Why do conjugate bases of strong acids have no basic properties in water? List the conjugate bases of the six common strong acids. To tie it all together, some instructors have students think of Li+, K+, Rb+, Cs+, Ca2+, Sr2+, and Ba2+ as the conjugate acids of the strong bases LiOH, KOH. RbOH, CsOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2. Although not technically correct, the conjugate acid strength of these cations is similar to the conjugate base strength of the strong acids. That is, these cations have no acidic properties in water; similarly, the conjugate bases of strong acids have no basic properties (strong gives you worthless). Fill in the blanks with the correct response. The conjugate base of a weak acid is a_____base. The conjugate acid of a weak base is a_____acid. The conjugate base of a strong acid is a_____base. The conjugate acid of a strong base is a_____ acid. (Hint: Weak gives you weak and strong gives you worthless.)arrow_forwardLactic acid, C3H6O3, occurs in sour milk as a result of the metabolism of certain bacteria. Calculate the pH of a solution of 56. mg lactic acid in 250. mL water. Ka for D-lactic acid is 1.5 × 10−4.arrow_forward
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