EBK EXPLORING CHEMICAL ANALYSIS
EBK EXPLORING CHEMICAL ANALYSIS
5th Edition
ISBN: 9781319416942
Author: Harris
Publisher: VST
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Chapter 16, Problem 16.17P

(a)

Interpretation Introduction

Interpretation:

Value of z in the formula YBa2Cu3O7z has to be determined.

Concept Introduction:

A superconductor is a material wherein electrical conductivity becomes infinite and from which magnetic flux field is expelled. Superconductor has a critical temperature below which resistance drops abruptly to zero.

Iodometric titration is a type of titration reaction in which iodides reacts with another oxidizing agent in acidic or neutral medium. As a result of this, iodides are converted to iodine and this formed iodine is back titrated against another standard reducing agent (usually sodium thiosulphate) of known concentration.

(b)

Interpretation Introduction

Interpretation:

The uncertainty to find x in the formula YBa2Cu3O7z has to be determined.

Concept Introduction:

Refer to part (a).

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Questions 4 and 5
For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions.  Assume all reagents are in excess unless otherwise indicated.
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