CHEMISTRY: AN INTRODUCTION TO GENERAL, O
13th Edition
ISBN: 9780137444298
Author: Timberlake
Publisher: PEARSON
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Chapter 15.6, Problem 15.50PP
Interpretation Introduction
To determine: The role of lipoproteins in transporting lipids in the bloodstream.
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19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water?
Group of answer choices
LiBr
LiI
LiF
LiCl
Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism
of the reactions.
Br
MeOH
OSO2CH3
MeOH
Chapter 15 Solutions
CHEMISTRY: AN INTRODUCTION TO GENERAL, O
Ch. 15.1 - Lipids are not soluble in water. Are lipids polar...Ch. 15.1 - Which of the following solvents might be used to...Ch. 15.1 - Prob. 15.3PPCh. 15.1 - Prob. 15.4PPCh. 15.2 - Describe some similarities and differences in the...Ch. 15.2 - Prob. 15.6PPCh. 15.2 - Prob. 15.7PPCh. 15.2 - Draw the line-angle formula for each of the...Ch. 15.2 - Prob. 15.9PPCh. 15.2 - For each of the following fatty acids, give the...
Ch. 15.2 - Prob. 15.11PPCh. 15.2 - How does the double bond influence the dispersion...Ch. 15.2 - Prob. 15.13PPCh. 15.2 - Prob. 15.14PPCh. 15.2 - Prob. 15.15PPCh. 15.2 - Prob. 15.16PPCh. 15.2 - Prob. 15.17PPCh. 15.2 - Prob. 15.18PPCh. 15.3 - Draw the condensed structural formula for the...Ch. 15.3 - Prob. 15.20PPCh. 15.3 - Prob. 15.21PPCh. 15.3 - Draw the condensed structural formula for a mixed...Ch. 15.3 - Prob. 15.23PPCh. 15.3 - Prob. 15.24PPCh. 15.3 - Prob. 15.25PPCh. 15.3 - Prob. 15.26PPCh. 15.3 - How does the perc entage of monounsaturated and...Ch. 15.3 - Prob. 15.28PPCh. 15.4 - Identify each of the following processes as...Ch. 15.4 - Identify each of the following processes as...Ch. 15.4 - Prob. 15.31PPCh. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Prob. 15.33PPCh. 15.4 - Prob. 15.34PPCh. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Prob. 15.37PPCh. 15.4 - Draw the condensed structural formula for all the...Ch. 15.5 - Prob. 15.39PPCh. 15.5 - Prob. 15.40PPCh. 15.5 - Draw the condensed structural formula for the...Ch. 15.5 - Draw the condensed structural formula for the...Ch. 15.5 - Prob. 15.43PPCh. 15.5 - Prob. 15.44PPCh. 15.5 - Prob. 15.45PPCh. 15.5 - Prob. 15.46PPCh. 15.6 - Draw the structure for the steroid nucleus.Ch. 15.6 - Draw the structure for cholesterol.Ch. 15.6 - Prob. 15.49PPCh. 15.6 - Prob. 15.50PPCh. 15.6 - Prob. 15.51PPCh. 15.6 - Prob. 15.52PPCh. 15.6 - Prob. 15.53PPCh. 15.6 - Prob. 15.54PPCh. 15.6 - Prob. 15.55PPCh. 15.6 - What are the similarities and differences between...Ch. 15.6 - Prob. 15.57PPCh. 15.6 - Prob. 15.58PPCh. 15.7 - What is the function if the lipid by layer in a...Ch. 15.7 - Prob. 15.60PPCh. 15.7 - Prob. 15.61PPCh. 15.7 - How do the unsaturated fatty acids in the...Ch. 15.7 - Prob. 15.63PPCh. 15.7 - Prob. 15.64PPCh. 15.7 - Prob. 15.65PPCh. 15.7 - 15.66 Identify the type of transport described by...Ch. 15.7 - Identify the functional groups in Pravachol.Ch. 15.7 - Identify the functional groups in Tri Cor.Ch. 15.7 - Prob. 15.69PPCh. 15.7 - Prob. 15.70PPCh. 15 - Prob. 15.71UTCCh. 15 - Prob. 15.72UTCCh. 15 - Prob. 15.73UTCCh. 15 - Prob. 15.74UTCCh. 15 - Prob. 15.75APPCh. 15 - Prob. 15.76APPCh. 15 - Prob. 15.77APPCh. 15 - Prob. 15.78APPCh. 15 - Identify each of the following as a fatty acid,...Ch. 15 - Identify each of the following as a fatty acid,...Ch. 15 - 15.81 Identify the components (1 to 6 ) contained...Ch. 15 - Prob. 15.82APPCh. 15 - Which of the following are found in cell...Ch. 15 - Which of the following are found in cell...Ch. 15 - Draw the condensed structural formula for a...Ch. 15 - sunflower seed oil can be used to make margarine....Ch. 15 - Prob. 15.87CPCh. 15 - 15.87 Match the lipoprotein (1 to 4) with its...Ch. 15 - 15.89 A sink drain can become clogged with solid...Ch. 15 - 15.90 One of the triacylglycerols in olive oil is...Ch. 15 - 15.91 1.00 mole of glyceryl trioleate (triolein)...Ch. 15 - The plastic known as PETE...Ch. 15 - Using the Internet, look up the condensed...Ch. 15 - The insect repellent DEET is an amide that can be...Ch. 15 - Glyceryl trimyristate (trimyristin) is found in...Ch. 15 - Prob. 31CICh. 15 - Prob. 32CI
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