Pearson eText Organic Chemistry -- Instant Access (Pearson+)
Pearson eText Organic Chemistry -- Instant Access (Pearson+)
9th Edition
ISBN: 9780135213728
Author: Leroy Wade, Jan Simek
Publisher: PEARSON+
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Chapter 15.5, Problem 15.6P

Treatment of an alkyl halide with AgNO3 in alcohol often promotes ionization.

Ag+ + R—Cl → AgCl + R+

When 4-chloro-2-methylhex-2-ene reacts with AgNO3 in ethanol two isomeric ethers are formed. Suggest structures, and propose a mechanism for their formation.

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.
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Pearson eText Organic Chemistry -- Instant Access (Pearson+)

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