The mechanism for the rearrangement reaction of cyclohexa − 1 , 4 − diene into cyclohexa − 1 , 3 − diene in the presence of an acidic solution along with the reason of energetically favourable reaction. Interpretation: The mechanism for the rearrangement reaction of cyclohexa − 1 , 4 − diene into cyclohexa − 1 , 3 − diene in the presence of an acidic solution is to be proposed and the reason corresponds to the statement that is why the reaction is energetically favourable to be explained. Concept introduction: Tautomerization is the process in which molecular formula of compounds remain same but connectivity of atoms or substituents in compounds become different. The stability of compound is the major factor that determines the formation of a compound. The compounds that have low energy are energetically favourable. Conjugated systems possess alternate single and double bonds that results in lower energy of molecule and increase in stability of a molecule.

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1/2 - 51% + » GAY Organic Reactions Assignment /26 Write the type of reaction that is occurring on the line provided then complete the reaction. Only include the major products and any byproducts (e.g. H₂O) but no minor products. Please use either full structural diagrams or the combination method shown in the lesson. Skeletal/line diagrams will not be accepted. H3C 1. 2. CH3 A Acid OH Type of Reaction: NH Type of Reaction: + H₂O Catalyst + HBr 3. Type of Reaction: H3C 4. Type Reaction: 5. H3C CH2 + H2O OH + [0] CH3 Type of Reaction: 6. OH CH3 HO CH3 + Type of Reaction: 7. Type of Reaction: + [H]

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Question

Chapter 15.2, Problem 15.2P

Interpretation Introduction

To determine: The mechanism for the rearrangement reaction of cyclohexa−1,4−diene into cyclohexa−1,3−diene in the presence of an acidic solution along with the reason of energetically favourable reaction.

Interpretation: The mechanism for the rearrangement reaction of cyclohexa−1,4−diene into cyclohexa−1,3−diene in the presence of an acidic solution is to be proposed and the reason corresponds to the statement that is why the reaction is energetically favourable to be explained.

Concept introduction: Tautomerization is the process in which molecular formula of compounds remain same but connectivity of atoms or substituents in compounds become different. The stability of compound is the major factor that determines the formation of a compound. The compounds that have low energy are energetically favourable.

Conjugated systems possess alternate single and double bonds that results in lower energy of molecule and increase in stability of a molecule.

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1/2 - 51% + » GAY Organic Reactions Assignment /26 Write the type of reaction that is occurring on the line provided then complete the reaction. Only include the major products and any byproducts (e.g. H₂O) but no minor products. Please use either full structural diagrams or the combination method shown in the lesson. Skeletal/line diagrams will not be accepted. H3C 1. 2. CH3 A Acid OH Type of Reaction: NH Type of Reaction: + H₂O Catalyst + HBr 3. Type of Reaction: H3C 4. Type Reaction: 5. H3C CH2 + H2O OH + [0] CH3 Type of Reaction: 6. OH CH3 HO CH3 + Type of Reaction: 7. Type of Reaction: + [H]

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