Chemistry: A Molecular Approach
3rd Edition
ISBN: 9780321809247
Author: Nivaldo J. Tro
Publisher: Prentice Hall
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Chapter 15, Problem 93E
Interpretation Introduction
To determine: The
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20. The Brusselator. This hypothetical system was first proposed by a group work-
ing in Brussels [see Prigogine and Lefever (1968)] in connection with spatially
nonuniform chemical patterns. Because certain steps involve trimolecular reac
tions, it is not a model of any real chemical system but rather a prototype that
has been studied extensively. The reaction steps are
A-X.
B+X-Y+D.
2X+ Y-3X,
X-E.
305
It is assumed that concentrations of A, B, D, and E are kept artificially con
stant so that only X and Y vary with time.
(a) Show that if all rate constants are chosen appropriately, the equations de
scribing a Brusselator are:
dt
A-(B+ 1)x + x²y,
dy
=Bx-x²y.
di
Problem 3. Provide a mechanism for the following transformation:
H₂SO A
Me.
Me
Me
Me
Me
You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
хе
i
Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
☐
Chapter 15 Solutions
Chemistry: A Molecular Approach
Ch. 15 - Prob. 1SAQCh. 15 - Q2. Which pair is a Brønsted–Lowry conjugate...Ch. 15 - Prob. 3SAQCh. 15 - Prob. 4SAQCh. 15 - Q5. An HNO3(aq) solution has a pH of 1.75. What is...Ch. 15 - Q6. Find the pH of a 0.350 M aqueous benzoic acid...Ch. 15 - Q7. Find the pH of a 0.155 M HClO2(aq) solution....Ch. 15 - Prob. 8SAQCh. 15 - Prob. 9SAQCh. 15 - Prob. 10SAQ
Ch. 15 - Prob. 11SAQCh. 15 - Prob. 12SAQCh. 15 - Prob. 13SAQCh. 15 - Prob. 14SAQCh. 15 - Q15. Which acid has the largest Ka: HClO2(aq),...Ch. 15 - 1. What causes heartburn? What are some possible...Ch. 15 - 2. What are the general physical and chemical...Ch. 15 - Prob. 3ECh. 15 - Prob. 4ECh. 15 - Prob. 5ECh. 15 - Prob. 6ECh. 15 - Prob. 7ECh. 15 - Prob. 8ECh. 15 - Prob. 9ECh. 15 - Prob. 10ECh. 15 - 11. What are diprotic and triprotic acids? List an...Ch. 15 - 12. Define the acid ionization constant and...Ch. 15 - 13. Write an equation for the autoionization of...Ch. 15 - 14. What happens to the [OH–] of a solution when...Ch. 15 - Prob. 15ECh. 15 - Prob. 16ECh. 15 - Prob. 17ECh. 15 - Prob. 18ECh. 15 - Prob. 19ECh. 15 - Prob. 20ECh. 15 - Prob. 21ECh. 15 - 22. How can you determine if an anion will act as...Ch. 15 - 23. What is the relationship between the acid...Ch. 15 - 24. What kinds of cations act as weak acids? List...Ch. 15 - 25. When calculating the [H3O+] for a polyprotic...Ch. 15 - Prob. 26ECh. 15 - Prob. 27ECh. 15 - Prob. 28ECh. 15 - Prob. 29ECh. 15 - Prob. 30ECh. 15 -
31. What is acid rain? What causes it, and where...Ch. 15 - Prob. 32ECh. 15 - 33. Identify each substance as an acid or a base...Ch. 15 - 34. Identify each substance as an acid or a base...Ch. 15 - 35. In each reaction, identify the Brønsted–Lowry...Ch. 15 - Prob. 36ECh. 15 - 37. Write the formula for the conjugate base of...Ch. 15 - 38. Write the formula for the conjugate acid of...Ch. 15 - 39. Both H2O and H2PO4– are amphoteric. Write an...Ch. 15 - 40. Both HCO3– and HS– are amphoteric. Write an...Ch. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Prob. 43ECh. 15 - Prob. 44ECh. 15 - Prob. 45ECh. 15 - Prob. 46ECh. 15 - 47. Calculate [OH–] in each aqueous solution at 25...Ch. 15 - Prob. 48ECh. 15 - Prob. 49ECh. 15 - 50. Calculate [H3O+] and [OH–] for each solution...Ch. 15 - Prob. 51ECh. 15 - Prob. 52ECh. 15 - 53. Like all equilibrium constants, the value of...Ch. 15 - Prob. 54ECh. 15 - 55. Calculate the pH of each acid solution....Ch. 15 - Prob. 56ECh. 15 - Prob. 57ECh. 15 - 58. Determine the pH of each solution.
a. 0.048 M...Ch. 15 - Prob. 59ECh. 15 - Prob. 60ECh. 15 - 61. What is the pH of a solution in which 224 mL...Ch. 15 - Prob. 62ECh. 15 - Prob. 63ECh. 15 - 64. Determine the [H3O+] and pH of a 0.200 M...Ch. 15 - 65. Determine the pH of an HNO2 solution of each...Ch. 15 - 66. Determine the pH of an HF solution of each...Ch. 15 - Prob. 67ECh. 15 - Prob. 68ECh. 15 - Prob. 69ECh. 15 - Prob. 70ECh. 15 - 71. Determine the percent ionization of a 0.125 M...Ch. 15 - Prob. 72ECh. 15 - Prob. 73ECh. 15 - Prob. 74ECh. 15 - Prob. 75ECh. 15 - Prob. 76ECh. 15 - Prob. 77ECh. 15 - Prob. 78ECh. 15 - Prob. 79ECh. 15 - Prob. 80ECh. 15 - Prob. 81ECh. 15 - Prob. 82ECh. 15 - Prob. 83ECh. 15 - Prob. 84ECh. 15 - Prob. 85ECh. 15 - Prob. 86ECh. 15 - Prob. 87ECh. 15 - Prob. 88ECh. 15 - Prob. 89ECh. 15 - Prob. 90ECh. 15 - Prob. 91ECh. 15 - Prob. 92ECh. 15 - Prob. 93ECh. 15 - Prob. 94ECh. 15 - Prob. 95ECh. 15 - Prob. 96ECh. 15 - 97. Determine the [OH–] and pH of a solution that...Ch. 15 - Prob. 98ECh. 15 - Prob. 99ECh. 15 - Prob. 100ECh. 15 - Prob. 101ECh. 15 - 102. Determine if each salt will form a solution...Ch. 15 - Prob. 103ECh. 15 - Prob. 104ECh. 15 - 105. Determine the pH of each solution.
a. 0.10 M...Ch. 15 - 106. Determine the pH of each solution.
a. 0.20 M...Ch. 15 - Prob. 107ECh. 15 - Prob. 108ECh. 15 - Prob. 109ECh. 15 - Prob. 110ECh. 15 - Prob. 111ECh. 15 - 112. Calculate the [H3O+] and pH of each...Ch. 15 - 113. Calculate the concentration of all species in...Ch. 15 - 114. Calculate the concentration of all species in...Ch. 15 - 115. Calculate the [H3O+] and pH of each H2SO4...Ch. 15 - Prob. 116ECh. 15 - Prob. 117ECh. 15 - Prob. 118ECh. 15 - 119. Based on their molecular structure, pick the...Ch. 15 - Prob. 120ECh. 15 - Prob. 121ECh. 15 - 122. Which is a stronger base, PO43– or AsO43–?...Ch. 15 - 123. Classify each species as either a Lewis acid...Ch. 15 - 124. Classify each species as either a Lewis acid...Ch. 15 - Prob. 125ECh. 15 - Prob. 126ECh. 15 - Prob. 127ECh. 15 - Prob. 128ECh. 15 - Prob. 129ECh. 15 - Prob. 130ECh. 15 - Prob. 131ECh. 15 - Prob. 132ECh. 15 - 133. Acid rain over the Great Lakes has a pH of...Ch. 15 - 134. White wines tend to be more acidic than red...Ch. 15 - 135. Common aspirin is acetylsalicylic acid, which...Ch. 15 - Prob. 136ECh. 15 - Prob. 137ECh. 15 - Prob. 138ECh. 15 - Prob. 139ECh. 15 - 140. Determine the pH of each two-component...Ch. 15 - Prob. 141ECh. 15 - Prob. 142ECh. 15 - 143. The pH of a 1.00 M solution of urea, a weak...Ch. 15 - 144. A solution is prepared by dissolving 0.10 mol...Ch. 15 - 145. Lactic acid is a weak acid found in milk. Its...Ch. 15 - Prob. 146ECh. 15 - Prob. 147ECh. 15 - Prob. 148ECh. 15 - Prob. 149ECh. 15 - 150. To what volume should you dilute 1 L of a...Ch. 15 - Prob. 151ECh. 15 - Prob. 152ECh. 15 -
153. Calculate the pH of a solution prepared from...Ch. 15 - 154. To 1.0 L of a 0.30 M solution of HClO2 is...Ch. 15 - 155. A mixture of Na2CO3 and NaHCO3 has a mass of...Ch. 15 - 156. A mixture of NaCN and NaHSO4 consists of a...Ch. 15 - 157. Without doing any calculations, determine...Ch. 15 - 158. Without doing any calculations, determine...Ch. 15 - Prob. 159E
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