PRINCIPLES+REACTIONS
8th Edition
ISBN: 9781337759632
Author: Masterton
Publisher: CENGAGE L
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Chapter 15, Problem 8QAP
Calculate K for the reactions in Question 4.
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7. A 10.00-g sample of the ionic compound NaA, where A is the anion of a weak acid, was
dissolved in enough water to make 100.0 mL of solution and was then titrated with 0.100 M HCl.
After 500.0 mL HCl was added, the pH was 5.00. The experimenter found that 1.00 L of 0.100 M
HCl was required to reach the stoichiometric point of the titration.
a. What is the molar mass of NaA?
b. Calculate the pH of the solution at the stoichiometric point of titration.
2. Using the procedure described in this module, a student determined the percent KHP in an impure sample of KHP. A 3.150-g sample of impure KHP required 41.50 mL of 0.1352M NaOH solution for titration.
(a) Calculate the number of moles of NaOH required for the titration.
(b) Calculate the number of moles of KHP present in the impure sample of KHP.
(c) Calculate the number of grams of KHP present in the impure sample.
(d) Calculate the percent of KHP in the impure sample, using Equation 8.
Equation 8:
percent KHP in the impure sample, % = ( mass of KHP in the sample,g/ mass of sample analyzed, g) (100%)
7.
The separate samples of nitric and acetic acids are both titrated with a 0.100 M solution of NaOH(aq).
(Y) 25.0mL of 1.0 M HNO3(aq) (Z) 25.0 mL of 1.0 M CH3COOH(aq)
Determine whether each of the following statements concerning this titration is true or false.
(A) A larger volume of NaOH(aq) is needed to reach the equivalence point in the titration of HNO3
(B) The pH at the equivalence point in the HNO3 titration will be lower than the pH at the equivalence point in the CH3COOH titration
(C) Phenolphthalein would be a suitable indicator for both titrations
Group of answer choices
a.) A) False B) True C) True
b.) A) False B) False C) True
c.) A) False B) True C) False
d.) A) True B)True C)True
Chapter 15 Solutions
PRINCIPLES+REACTIONS
Ch. 15 - Write a net ionic equation for the reaction...Ch. 15 - Write a net ionic equation for the reaction...Ch. 15 - Write a balanced net ionic equation for the...Ch. 15 - Write a balanced net ionic equation for the...Ch. 15 - Calculate K for the reactions in Question 1.Ch. 15 - Calculate K for the reactions in Question 2.Ch. 15 - Calculate K for the reactions in Question 3.Ch. 15 - Calculate K for the reactions in Question 4.Ch. 15 - Calculate [H+] and pH in a solution in which...Ch. 15 - Calculate [OH-] and pH in a solution in which the...
Ch. 15 - A buffer is prepared by dissolving 0.0250 mol of...Ch. 15 - Prob. 12QAPCh. 15 - A buffer solution is prepared by adding 15.00 g of...Ch. 15 - A buffer solution is prepared by adding 5.50 g of...Ch. 15 - A solution with a pH of 9.22 is prepared by adding...Ch. 15 - An aqueous solution of 0.057 M weak acid, HX, has...Ch. 15 - Which of the following would form a buffer if...Ch. 15 - Which of the following would form a buffer if...Ch. 15 - Calculate the solubility (in grams per liter) of...Ch. 15 - Calculate the solubility (in grams per liter) of...Ch. 15 - Copper(l) chloride, CuCl, is the starting material...Ch. 15 - Prob. 22QAPCh. 15 - Prob. 23QAPCh. 15 - Ksp for CaSO4 at 100C is estimated to be1.6105. At...Ch. 15 - Prob. 25QAPCh. 15 - At 25C, 10.24 mg of Cr(OH)2 are dissolved in...Ch. 15 - Calcium nitrate is added to a sodium sulfate...Ch. 15 - Cadmium(ll) chloride is added to a solution of...Ch. 15 - Water from a well is found to contain 3.0 mg of...Ch. 15 - Silver(I) sulfate (Ksp=1.2105) is used in the...Ch. 15 - A solution is prepared by mixing 13.00 mL of...Ch. 15 - A solution is prepared by mixing 45.00 mL of 0.022...Ch. 15 - A solution is 0.047 M in both NaF and Na2CO3....Ch. 15 - Solid lead nitrate is added to a solution that is...Ch. 15 - A solution is made up by adding 0.632 g of barium...Ch. 15 - A solution is made up by adding 0.839 g of...Ch. 15 - Prob. 37QAPCh. 15 - To a beaker with 500 mL of water are added 95 mg...Ch. 15 - Write net ionic equations for the reaction of H+...Ch. 15 - Prob. 40QAPCh. 15 - Prob. 41QAPCh. 15 - Write a net ionic equation for the reaction with...Ch. 15 - Prob. 43QAPCh. 15 - Write a net ionic equation for the reaction with...Ch. 15 - Prob. 45QAPCh. 15 - Write an overall net ionic equation and calculate...Ch. 15 - Consider the reaction...Ch. 15 - Consider the reaction BaF2(s)+SO42(aq)BaSO4(s)+2...Ch. 15 - Aluminum hydroxide reacts with an excess of...Ch. 15 - Prob. 50QAPCh. 15 - Calculate the molar solubility of gold(I) chloride...Ch. 15 - Calculate the molar solubility of PbCl2 in 0.2 M...Ch. 15 - For the reaction...Ch. 15 - For the reaction Zn(OH)2(s)+2OH(aq)Zn(OH)42(aq)...Ch. 15 - What are the concentrations of Cu2+, NH3, and...Ch. 15 - Prob. 56QAPCh. 15 - Calcium ions in blood trigger clotting. To prevent...Ch. 15 - Prob. 58QAPCh. 15 - A town adds 2.0 ppm of F- ion to fluoridate its...Ch. 15 - Consider the following hypothetical dissociation:...Ch. 15 - Prob. 61QAPCh. 15 - Consider a 2.0-L aqueous solution of 4.17 M NH3,...Ch. 15 - Marble is almost pure CaCO3. Acid rain has a...Ch. 15 - Prob. 64QAPCh. 15 - Prob. 65QAPCh. 15 - The box below represents one liter of a saturated...Ch. 15 - Consider a saturated solution of BaCO3 at 7.5C....Ch. 15 - Prob. 68QAPCh. 15 - Consider the insoluble salts JQ, K2R, L2S3, MT2,...Ch. 15 - Prob. 70QAPCh. 15 - Consider the equilibrium curve for AgCl shown...Ch. 15 - Dissolving CaCO3 is an endothermic reaction. The...Ch. 15 - Challenge Problems Insoluble hydroxides such as...Ch. 15 - What is the solubility of CaF2 in a buffer...Ch. 15 - What is [Br-] just as AgCl begins to precipitate...Ch. 15 - Prob. 76QAPCh. 15 - Prob. 77QAPCh. 15 - Prob. 78QAP
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- Consider the reaction BaF2(s)+SO42(aq)BaSO4(s)+2 F(aq) (a) Calculate K for the reaction. (b) Will BaSO4 precipitate if Na2SO4 is added to a saturated solution of BaF2?arrow_forwardRefer to Appendix J for solubility products for calcium salts. Determine which of the calcium salts listed is most soluble in moles per liter and which is most soluble in grams per liter.arrow_forwardThe text describes zinc hydroxide as an amphoteric hydroxide, so Zn(OH)2 is soluble in basic solution. What is the molar solubility of Zn(OH)2 in 1.00 M NaOH? What is the pH of the equilibrium solution?arrow_forward
- The solubility of an ionic compound in water can be expressed in terms of the mass that will dissolve in a given volume of water, or in terms of the solubility product, Ksp. If only 0.303 g of Ca(OH)2 dissolves in enough water to give 0.243 L of aqueous solution at a given temperature, what is the Ksp value for calcium hydroxide at this temperature?arrow_forwardThe solubility of an ionic compound in water can be expressed in terms of the mass that will dissolve in a given volume of water, or in terms of the solubility product, Ksp.If only 0.264 g of Ca(OH)2 dissolves in enough water to give 0.165 L of aqueous solution at a given temperature, what is the Ksp value for calcium hydroxide at this temperature?arrow_forwardWhen aqueous solutions of sodium chloride and silver nitrate are mixed, AgCl(s) is formed. When 1M HCL is added to the solution, the precipitate dissapears. EXPLAIN WHY THE PRECIPITATE DISAPEARS WHEN HCL IS ADDED.arrow_forward
- Jj.86.arrow_forward14.arrow_forward24. A solution of volume 0.500 L contains 1.68 g NH3 and 4.05 g (NH4)2SO4. (a) What is the pH of this solution? (b) If 0.88 g NaOH is added to the solution, what will be the pH? (c) How many milliliters of 12 M HCl must be added to 0.500 L of the original solution to change its pH to 9.00?arrow_forward
- What mass of 3Fe(OH)3 would be produce if 250 mL of 0.250M of NaOH were added to a solution containing FeCl3?arrow_forward2. Explain the term 'buffer capacity'.arrow_forwardAn aqueous solution contains 0.28 M hydrofluoric acid. One Liter of this solution could be converted into a buffer by the addition of: (Assume that the volume remains constant as each substance is added.) O 0.139 mol NaOH 0.28 mol NaNO, 0.14 mol HNO, 0.29 mol HNO3 O 0.29 mol NaFarrow_forward
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