Bundle: Chemistry: An Atoms First Approach, 2nd, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
2nd Edition
ISBN: 9781305717633
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 15, Problem 7RQ
Interpretation Introduction
Interpretation: The figure showing the separation of common cations by selective precipitation is given. The chemistry involved with each step in Figure
Concept introduction: The qualitative analysis for the detection of cations present in a mixture involves the categorization of common cations into five groups and then these groups are further treated for the separation of cations present in the mixture and for their identification.
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
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Potential Energy (kJ)
600
400
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0
-200-
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-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
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you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 15 Solutions
Bundle: Chemistry: An Atoms First Approach, 2nd, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 15 - To what reaction does the solubility product...Ch. 15 - Prob. 2RQCh. 15 - Prob. 3RQCh. 15 - Prob. 4RQCh. 15 - Prob. 5RQCh. 15 - Prob. 6RQCh. 15 - Prob. 7RQCh. 15 - Prob. 8RQCh. 15 - Prob. 9RQCh. 15 - Prob. 10RQ
Ch. 15 - Prob. 1ALQCh. 15 - Prob. 2ALQCh. 15 - Prob. 3ALQCh. 15 - A friend tells you: The constant Ksp of a salt is...Ch. 15 - Prob. 5ALQCh. 15 - Prob. 6ALQCh. 15 - Prob. 7ALQCh. 15 - For which of the following is the Ksp value of the...Ch. 15 - Ag2S(s) has a larger molar solubility than CuS...Ch. 15 - Prob. 10QCh. 15 - Prob. 11QCh. 15 - When Na3PO4(aq) is added to a solution containing...Ch. 15 - The common ion effect for ionic solids (salts) is...Ch. 15 - Prob. 14QCh. 15 - Prob. 15QCh. 15 - The stepwise formation constants for a complex ion...Ch. 15 - Prob. 17QCh. 15 - Prob. 18QCh. 15 - Write balanced equations for the dissolution...Ch. 15 - Write balanced equations for the dissolution...Ch. 15 - Prob. 21ECh. 15 - Use the following data to calculate the Ksp value...Ch. 15 - Approximately 0.14 g nickel(II) hydroxide,...Ch. 15 - The solubility of the ionic compound M2X3, having...Ch. 15 - Prob. 25ECh. 15 - Prob. 26ECh. 15 - Calculate the solubility of each of the following...Ch. 15 - Prob. 28ECh. 15 - Cream of tartar, a common ingredient in cooking,...Ch. 15 - Prob. 30ECh. 15 - Prob. 31ECh. 15 - Calculate the molar solubility of Cd(OH)2, Ksp =...Ch. 15 - Calculate the molar solubility of Al(OH)3, Ksp = 2...Ch. 15 - Calculate the molar solubility of Co(OH)3, Ksp =...Ch. 15 - Prob. 35ECh. 15 - For each of the following pairs of solids,...Ch. 15 - Calculate the solubility (in moles per liter) of...Ch. 15 - Calculate the solubility of Co(OH)2(s) (Ksp = 2.5 ...Ch. 15 - The Ksp for silver sulfate (Ag2SO4) is 1.2 105....Ch. 15 - Prob. 40ECh. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Prob. 43ECh. 15 - The solubility of Pb(IO3)(s) in a 0.10-M KIO3...Ch. 15 - Prob. 45ECh. 15 - For which salt in each of the following groups...Ch. 15 - What mass of ZnS (Ksp = 2.5 1022) will dissolve...Ch. 15 - The concentration of Mg2+ in seawater is 0.052 M....Ch. 15 - Will a precipitate form when 100.0 mL of 4.0 104...Ch. 15 - A solution contains 1.0 105 M Ag+ and 2.0 106 M...Ch. 15 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 15 - Prob. 52ECh. 15 - Calculate the final concentrations of K+(aq),...Ch. 15 - Prob. 54ECh. 15 - A 50.0-mL sample of 0.00200 M AgNO3 is added to...Ch. 15 - Prob. 56ECh. 15 - A solution contains 1.0 105 M Na3PO4. What is the...Ch. 15 - The Ksp of Al(OH)3 is 2 1032. At what pH will a...Ch. 15 - A solution is 1 104 M in NaF, Na2S, and Na3PO4....Ch. 15 - A solution contains 0.25 M Ni(NO3)2 and 0.25 M...Ch. 15 - Write equations for the stepwise formation of each...Ch. 15 - Write equations for the stepwise formation of each...Ch. 15 - In the presence of CN, Fe3+ forms the complex ion...Ch. 15 - In the presence of NH3, Cu2+ forms the complex ion...Ch. 15 - Prob. 65ECh. 15 - Prob. 66ECh. 15 - The overall formation constant for HgI42 is 1.0 ...Ch. 15 - Prob. 68ECh. 15 - A solution is formed by mixing 50.0 mL of 10.0 M...Ch. 15 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 15 - a. Calculate the molar solubility of AgI in pure...Ch. 15 - Solutions of sodium thiosulfate are used to...Ch. 15 - Kf for the complex ion Ag(NH3)2+ is 1.7 107. Ksp...Ch. 15 - Prob. 74ECh. 15 - Prob. 75ECh. 15 - The solubility of copper(II) hydroxide in water...Ch. 15 - A solution contains 0.018 mole each of I, Br, and...Ch. 15 - Prob. 78AECh. 15 - Tooth enamel is composed of the mineral...Ch. 15 - Prob. 80AECh. 15 - What mass of Ca(NO3)2 must be added to 1.0 L of a...Ch. 15 - Calculate the mass of manganese hydroxide present...Ch. 15 - Prob. 83AECh. 15 - The active ingredient of Pepto-Bismol is the...Ch. 15 - Prob. 85AECh. 15 - The equilibrium constant for the following...Ch. 15 - Calculate the concentration of Pb2+ in each of the...Ch. 15 - Will a precipitate of Cd(OH)2 form if 1.0 mL of...Ch. 15 - Prob. 89AECh. 15 - Describe how you could separate the ions in each...Ch. 15 - Prob. 91AECh. 15 - Prob. 92AECh. 15 - Prob. 93CWPCh. 15 - Prob. 94CWPCh. 15 - Prob. 95CWPCh. 15 - The solubility of Pb(IO3)2(s) in a 7.2 102-M KIO3...Ch. 15 - A 50.0-mL sample of 0.0413 M AgNO3(aq) is added to...Ch. 15 - Prob. 98CWPCh. 15 - Prob. 99CPCh. 15 - Consider a solution made by mixing 500.0 mL of 4.0...Ch. 15 - a. Calculate the molar solubility of AgBr in pure...Ch. 15 - Prob. 102CPCh. 15 - Prob. 103CPCh. 15 - Calcium oxalate (CaC2O4) is relatively insoluble...Ch. 15 - What is the maximum possible concentration of Ni2+...Ch. 15 - A mixture contains 1.0 103 M Cu2+ and 1.0 103 M...Ch. 15 - Sodium tripolyphosphate (Na5P3O10) is used in many...Ch. 15 - You add an excess of solid MX in 250g water. You...Ch. 15 - a. Calculate the molar solubility of SrF2 in...Ch. 15 - Prob. 110IPCh. 15 - Prob. 111IPCh. 15 - Prob. 112IPCh. 15 - Aluminum ions react with the hydroxide ion to form...
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