Introductory Chemistry (5th Edition) (Standalone Book)
5th Edition
ISBN: 9780321910295
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 15, Problem 74E
Interpretation Introduction
Interpretation: The effect of the given changes is to be predicted by considering the given exothermic reaction.
Concept Introduction:
According to Le-Chatelier’s principle, at equilibrium if the system is disturbed then the system shifts in a direction that minimizes the disturbance.
For an exothermic reaction, the enthalpy is negative because the heat is evolved from the reaction mixture.
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From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
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2H+ + 2e- = H2 E0= 0.000 V
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Ce4+ + e- = Ce3+ E0= 1.70 V
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Chapter 15 Solutions
Introductory Chemistry (5th Edition) (Standalone Book)
Ch. 15 - Q1. Which change is likely to increase the rate of...Ch. 15 - The equilibrium constants at a fixed temperature...Ch. 15 - Q3. The concentrations of A,B, and C for the...Ch. 15 - Q4. What is the correct expression for the...Ch. 15 - Q5. Consider the reaction between NO and to form...Ch. 15 - Q6. The equilibrium constant for this reaction is...Ch. 15 - Prob. 7SAQCh. 15 - Q8. The decomposition of is endothermic.
Which...Ch. 15 - Prob. 9SAQCh. 15 - Prob. 10SAQ
Ch. 15 - 1. Is life in equilibrium with the environment?...Ch. 15 - Prob. 2ECh. 15 - 3. Why do chemists seek to control reaction...Ch. 15 - How do most chemical reactions occur?Ch. 15 - What factors influence reaction rates? How?Ch. 15 - Prob. 6ECh. 15 - 7. What is dynamic chemical equilibrium?
Ch. 15 - Prob. 8ECh. 15 - Explain why the concentrations of reactants and...Ch. 15 - Devise your own analogylike the Narnia and Middle...Ch. 15 - Prob. 11ECh. 15 - Write the expression for the equilibrium constant...Ch. 15 - What does a small equilibrium constant tell you...Ch. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - Prob. 16ECh. 15 - Prob. 17ECh. 15 - Prob. 18ECh. 15 - What is the effect of decreasing the concentration...Ch. 15 - Prob. 20ECh. 15 - Prob. 21ECh. 15 - What is the effect of increasing the pressure of a...Ch. 15 - Prob. 23ECh. 15 - 24. To drive a reaction that has fewer moles of...Ch. 15 - 25. What is the effect of decreasing the pressure...Ch. 15 - 26. What is the effect of increasing the...Ch. 15 - Prob. 27ECh. 15 - Prob. 28ECh. 15 - Prob. 29ECh. 15 - Prob. 30ECh. 15 - Prob. 31ECh. 15 - Prob. 32ECh. 15 - Prob. 33ECh. 15 - Prob. 34ECh. 15 - Does a catalyst affect the value of the...Ch. 15 - Prob. 36ECh. 15 - Prob. 37ECh. 15 - Prob. 38ECh. 15 - The body temperature of cold-blooded animals...Ch. 15 - Prob. 40ECh. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Prob. 44ECh. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Prob. 47ECh. 15 - Prob. 48ECh. 15 - 49. For each equilibrium constant, indicate if you...Ch. 15 - Prob. 50ECh. 15 - Prob. 51ECh. 15 - 52. Consider the reaction.
An equilibrium mixture...Ch. 15 - CALCULATING AND USING EQUILIBRIUM CONSTANTS
53....Ch. 15 - Prob. 54ECh. 15 - Prob. 55ECh. 15 - Prob. 56ECh. 15 - Prob. 57ECh. 15 - Prob. 58ECh. 15 - Prob. 59ECh. 15 - Prob. 60ECh. 15 - Prob. 61ECh. 15 - Prob. 62ECh. 15 - Consider this reaction at equilibrium....Ch. 15 - Prob. 64ECh. 15 - Consider this reaction at equilibrium....Ch. 15 - LE CHTELIER'S PRINCIPLE Consider this reaction at...Ch. 15 - LE CHTELIERS PRINCIPLE Consider the effect of a...Ch. 15 - Prob. 68ECh. 15 - Prob. 69ECh. 15 - Prob. 70ECh. 15 - Prob. 71ECh. 15 - Prob. 72ECh. 15 - Prob. 73ECh. 15 - Prob. 74ECh. 15 - Coal, which is primarily carbon, can be converted...Ch. 15 - 76. Coal can be used to generate hydrogen gas (a...Ch. 15 - 77. For each compound, write an equation showing...Ch. 15 - Prob. 78ECh. 15 - Prob. 79ECh. 15 - Prob. 80ECh. 15 - A saturated solution of MgF2 has [Mg2+]=2.6104M...Ch. 15 - Prob. 82ECh. 15 - Prob. 83ECh. 15 - Prob. 84ECh. 15 - Prob. 85ECh. 15 - Prob. 86ECh. 15 - Prob. 87ECh. 15 - 88. Calculate the molar solubility of .
Ch. 15 - Prob. 89ECh. 15 - Prob. 90ECh. 15 - 91. Consider the reaction.
A solution is made...Ch. 15 - Prob. 92ECh. 15 - Prob. 93ECh. 15 - Prob. 94ECh. 15 - This reaction is exothermic....Ch. 15 - Prob. 96ECh. 15 - 97. Calculate the molar solubility of CuS. How...Ch. 15 - Prob. 98ECh. 15 - Prob. 99ECh. 15 - Prob. 100ECh. 15 - Prob. 101ECh. 15 - Prob. 102ECh. 15 - Consider the reaction: CaCO3CaO(s)+CO2(g) A sample...Ch. 15 - Prob. 104ECh. 15 - A 2.55-L solution is 0.115 M in Mg2+. If K2CO3 is...Ch. 15 - NaOH is added to 122 mL of a 0.17 M solution of...Ch. 15 - Prob. 107ECh. 15 - Prob. 108ECh. 15 - One of the main components of hard water is CaCO3....Ch. 15 - Prob. 110ECh. 15 - The reaction A(g)+B(g)2C(g) has an equilibrium...Ch. 15 - Describe three ways a reaction at equilibrium can...
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