CHEMISTRY THE CENTRAL SCIENCE 14TH EDI
14th Edition
ISBN: 9780134863016
Author: Brown
Publisher: PEARSON
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Chapter 15, Problem 5E
Interpretation Introduction
To determine:
The reaction that has a larger equilibrium constant.
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3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing
mechanism below, but make sure to draw the product of each proposed step (3 points).
CN
+ En
CN
3) Propagation of uncertainty. Every measurement has uncertainty. In this problem, we'll
evaluate the uncertainty in every step of a titration of potassium hydrogen phthalate (a
common acid used in titrations, abbreviated KHP, formula CsH5KO4) with NaOH of an
unknown concentration.
The calculation that ultimately needs to be carried out is:
concentration NaOH
1000 x mass KHP × purity KHP
molar mass KHP x volume NaOH
Measurements:
a) You use a balance to weigh 0.3992 g of KHP. The uncertainty is ±0.15 mg (0.00015
g).
b) You use a buret to slowly add NaOH to the KHP until it reaches the endpoint. It takes
18.73 mL of NaOH. The uncertainty of the burst is 0.03 mL..
c) The manufacturer states the purity of KHP is 100%±0.05%.
d) Even though we don't think much about them, molar masses have uncertainty as well.
The uncertainty comes from the distribution of isotopes, rather than random
measurement error. The uncertainty in the elements composing KHP are:
a. Carbon:
b. Hydrogen:
±0.0008…
Don't used hand raiting and don't used Ai solution
Chapter 15 Solutions
CHEMISTRY THE CENTRAL SCIENCE 14TH EDI
Ch. 15.2 - Prob. 15.1.1PECh. 15.2 - Prob. 15.1.2PECh. 15.2 - Prob. 15.2.1PECh. 15.2 - Prob. 15.2.2PECh. 15.3 - Prob. 15.3.1PECh. 15.3 - Practice Exercise 2 For the reaction H2 (g) + I2...Ch. 15.3 - Prob. 15.4.1PECh. 15.3 - Prob. 15.4.2PECh. 15.4 - Prob. 15.5.1PECh. 15.4 - Prob. 15.5.2PE
Ch. 15.4 - Practice Exercise 1
If 8.0 g of NH4HS(s)...Ch. 15.4 - Prob. 15.6.2PECh. 15.5 - Practice Exercise 1
A mixture of gaseous sulfur...Ch. 15.5 - Prob. 15.7.2PECh. 15.5 - Practice Exercise 1 In Section 15.1, we discussed...Ch. 15.5 - Practice Exercise 2
The gaseous compound BrCl...Ch. 15.6 - Prob. 15.9.1PECh. 15.6 - Practice Exercise 2 At 1000 k, the value of Kp for...Ch. 15.6 - Prob. 15.10.1PECh. 15.6 - Prob. 15.10.2PECh. 15.6 - Practice Exercise 1 For the equilibrium Br2(g) +...Ch. 15.6 - Prob. 15.11.2PECh. 15.7 - Practice Exercise 1 For the reaction 4 NH3(g) + 5...Ch. 15.7 - Prob. 15.12.2PECh. 15 - Prob. 1DECh. 15 - Based on the following energy profile, predict...Ch. 15 - 15.2 The following diagrams represent a...Ch. 15 - Prob. 3ECh. 15 - Prob. 4ECh. 15 - Prob. 5ECh. 15 - 15.6 Ethene (C2H4) reacts with healogens (X2) by...Ch. 15 - When lead(IV) oxide is heated above 300 O C, it...Ch. 15 - Prob. 8ECh. 15 - The reactin A2(g) + B(g) + A(g) + AB(g) has an...Ch. 15 - Prob. 10ECh. 15 - Prob. 11ECh. 15 - The following graph represents the yield of the...Ch. 15 - Suppose that the gas-phase reactions A B and B A...Ch. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - Write the expression for KC for the following...Ch. 15 - When the following reaction come to equilibrium,...Ch. 15 - Prob. 18ECh. 15 - Prob. 19ECh. 15 - Prob. 20ECh. 15 - If Kc = 0.042 for PC13(g) + C12 (g) PC15 (g) at...Ch. 15 - Prob. 22ECh. 15 - 15.23 The equilibrium constant for the...Ch. 15 - Prob. 24ECh. 15 - Prob. 25ECh. 15 - Prob. 26ECh. 15 - The following equilibria were attained at 823 K:...Ch. 15 - Consider the equilibrium N2(g) + O2(g) + Br2(g) 2...Ch. 15 - Mercury(I) oxide decomposes into elemental mercury...Ch. 15 - Prob. 30ECh. 15 - Prob. 31ECh. 15 - Prob. 32ECh. 15 - Prob. 33ECh. 15 - Phosphorus trichloride gas and chlorine gas react...Ch. 15 - A mixture of 0.10 mol of NO, 0.050 mol of H2, and...Ch. 15 - Prob. 36ECh. 15 - A mixture of 0.2000 mol of CO2, 0.1000 mol of H2,...Ch. 15 - 15.38 A flask is charged with 1.500 atm of N2O4(g)...Ch. 15 - Prob. 39ECh. 15 - Prob. 40ECh. 15 - a. If QC KC, in which direction will a reaction...Ch. 15 - Prob. 42ECh. 15 - At 100 OC , the equilibrium constant for the...Ch. 15 - 15.44 As shown in Table 15.2, KP for the...Ch. 15 - At 100 C, K = 0.078 for the reaction SO2Cl2 (g) ...Ch. 15 - Prob. 46ECh. 15 - Prob. 47ECh. 15 - Prob. 48ECh. 15 - At 800 k, the equilibrium constant for I2 (g) ...Ch. 15 - Prob. 50ECh. 15 - At 2000 OC, the equilibrium constant for the...Ch. 15 - For the equilibrium Br2 (g) + Cl2 (g) 2BrCl(g) At...Ch. 15 - At 373 k, Kp = 0.416 for the equilibrium 2NOBr (g)...Ch. 15 - At 218 oC, KC= 1.2 X 10-4 for the equilibrium NH4...Ch. 15 - Prob. 55ECh. 15 - At 80 oC, K =1.87 X 10-3 for the reaction PH3 BCl3...Ch. 15 - Prob. 57ECh. 15 - Prob. 58ECh. 15 - Prob. 59ECh. 15 - Prob. 60ECh. 15 - Consider the following equilibrium for which H<0...Ch. 15 - Prob. 62ECh. 15 - 15.63 How do the following changes affect the...Ch. 15 - Prob. 64ECh. 15 - Consider the following equilibrium between oxides...Ch. 15 - Prob. 66ECh. 15 - Ozone, O3, decomposes to molecular oxygen in the...Ch. 15 - Prob. 68ECh. 15 - Prob. 69ECh. 15 - 15.70 True or false: When the temperature of an...Ch. 15 - Prob. 71AECh. 15 - Prob. 72AECh. 15 - 15.73 A mixture of CH4 and H2O is passed over a...Ch. 15 - Prob. 74AECh. 15 - Prob. 75AECh. 15 - Prob. 76AECh. 15 - Prob. 77AECh. 15 - Prob. 78AECh. 15 - Prob. 79AECh. 15 - For the equilibrium PH3BCI3 (s) PH3 (g) + BCI3...Ch. 15 - Prob. 81AECh. 15 - Prob. 82AECh. 15 - Prob. 83AECh. 15 - At 900 o C, Kc = 0.0108 for the reaction CaCO3(g) ...Ch. 15 - Prob. 85AECh. 15 - The equilibrium constant Kc for C(s) +CO2 2CO(g)...Ch. 15 - Prob. 87AECh. 15 - Le Chatelier noted that many industrial processes...Ch. 15 - Prob. 89AECh. 15 - Prob. 90AECh. 15 - [15.91] An equilibrium mixture of H2, I2, and HI...Ch. 15 - Consider the hypothetical reaction A(g) + 2B(g) 2...Ch. 15 - Prob. 93AECh. 15 - Prob. 94AECh. 15 - Prob. 95IECh. 15 - The following equilibria were measured at 823 K:...Ch. 15 - Prob. 97IECh. 15 - Prob. 98IECh. 15 - At 800 K, the equilibrium constant for the...Ch. 15 - Prob. 100IECh. 15 - Prob. 101IECh. 15 - Prob. 102IE
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