ORGANIC CHEM PRINT STUDY GDE & SSM
4th Edition
ISBN: 9781119810650
Author: Klein
Publisher: WILEY
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Question
Chapter 15, Problem 51PP
Interpretation Introduction
Interpretation: For the given set of compounds the chemical shift values to be compared and arranged in an increasing order.
Concept Introduction:
Chemical shift: The frequency of the proton signal in the spectrum with reference to the standard compound which may be TMS(Tetramethylsilane) shows signal at 0 ppm(parts per million).
Bench mark values for protons in different electronic environment:
| Types of protons | Chemical shift |
| Alkynyl |
|
| Vinyl |
|
| Aryl |
|
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Which one of the following atoms should have the largest electron affinity?
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1s² 2s² 2p6 3s¹
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A student wants to make the following product in good yield from a single transformation step, starting from benzene.
Add any organic reagents the student is missing on the left-hand side of the arrow, and any addition reagents that are necessary above or below the arrow. If
this product can't be made in good yield with a single transformation step, check the box below the drawing area.
Note for advanced students: you may assume that an excess of benzene is used as part of the reaction conditions.
: ☐
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I
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This product can't be made in a single transformation step.
Chapter 15 Solutions
ORGANIC CHEM PRINT STUDY GDE & SSM
Ch. 15.4 - Prob. 1LTSCh. 15.4 - Prob. 1PTSCh. 15.4 - Prob. 2PTSCh. 15.4 - Prob. 3PTSCh. 15.4 - Prob. 4ATSCh. 15.4 - Prob. 2LTSCh. 15.5 - Prob. 3LTSCh. 15.6 - Prob. 4LTSCh. 15.6 - Prob. 11PTSCh. 15.6 - Prob. 12PTS
Ch. 15.6 - Prob. 13PTSCh. 15.7 - Prob. 5LTSCh. 15.7 - Prob. 15PTSCh. 15.8 - Prob. 6LTSCh. 15.8 - Prob. 19PTSCh. 15.10 - Prob. 8LTSCh. 15.10 - Prob. 23PTSCh. 15.10 - Prob. 24PTSCh. 15 - Prob. 32PPCh. 15 - Prob. 33PPCh. 15 - Prob. 34PPCh. 15 - Prob. 35PPCh. 15 - Prob. 36PPCh. 15 - Prob. 37PPCh. 15 - Prob. 38PPCh. 15 - Prob. 39PPCh. 15 - Prob. 40PPCh. 15 - Prob. 41PPCh. 15 - Prob. 42PPCh. 15 - Prob. 43PPCh. 15 - Prob. 44PPCh. 15 - Prob. 45PPCh. 15 - Prob. 51PPCh. 15 - Prob. 52PPCh. 15 - Prob. 53PPCh. 15 - Prob. 54PPCh. 15 - Prob. 55PPCh. 15 - Prob. 56PPCh. 15 - Prob. 57PPCh. 15 - Prob. 72IPCh. 15 - Prob. 73IPCh. 15 - Prob. 74IPCh. 15 - Prob. 75IPCh. 15 - Prob. 76IPCh. 15 - Prob. 77IPCh. 15 - Prob. 78IPCh. 15 - Prob. 79IPCh. 15 - Prob. 80IPCh. 15 - Prob. 81IP
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