EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
3rd Edition
ISBN: 9780133858501
Author: Bruice
Publisher: PEARSON CO
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Chapter 15, Problem 31P
Interpretation Introduction

Interpretation:

The monomer which gives greater yield polymer, 5-hydroxypentanoicacid or 6-hydroxyhexanoicacid has to be explained.

Concept Introduction:

Polymers:

Monomers combine together to form polymers. Monomers are the repeating units of small molecules which link together to form polymers and the process is called as polymerization.

Two types of polymers:

  • Synthetic and biopolymers.
  • DNA is an example for biopolymer and these type of polymers are synthesized by cells.
  • Polymers synthesized by scientists are called synthetic polymers and some examples are nylon, polyester etc.

Two types of synthetic polymers:

  • Chain-growth polymers or addition polymers and Step-growth polymers or Condensation polymers.
  • Chain growth polymers are formed by the monomer addition to the end of a growing chain.
  • Step-growth polymers are formed by combining monomers by removing small molecules of water or alcohol.

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Give the structure(s) of the product(s) the reaction below, and be sure to indicate any relative stereochemistry (you can assume that each of the Diels-Alder reactions will proceed with endo selectivity). Draw out relevant enantiomer(s) if they are expected to form. If no reaction is expected to occur under the indicated conditions, then write "no reaction" or NR, and explain why you would expect nothing to occur. If more than one product is formed, please indicate which one will be the major product or if they will be formed in equal amounts. In all cases, equimolar amounts of both components/reagents are present unless indicated otherwise   I'm struggling to see how this reaction will go! I am wondering if it will cycle on itself but I'm not sure how I drew out a decagon but I'm a bit lost
Give the structure(s) of the product(s) for the reactions below, and be sure to indicate any relative stereochemistry (you can assume that each of the Diels-Alder reactions will proceed with endo selectivity). Draw out relevant enantiomer(s) if they are expected to form. If no reaction is expected to occur under the indicated conditions, then write "no reaction" or NR, and explain why you would expect nothing to occur. If more than one product is formed, please indicate which one will be the major product or if they will be formed in equal amounts. In all cases, equimolar amounts of both components/reagents are present unless indicated otherwise .
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