Introducing Chemistry
6th Edition
ISBN: 9780134557373
Author: Tro
Publisher: PEARSON
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Textbook Question
Chapter 15, Problem 22E
What is the effect of increasing the pressure of a reaction mixture at equilibrium if the reactant side has fewer moles of gas particles than the product side?
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
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CI
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11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
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Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
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occur
WHY?
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H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
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HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
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Br
H
H3
CH₂
H
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H
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H
MISSING 2
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B
C
D
E
F
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Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
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b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
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Chapter 15 Solutions
Introducing Chemistry
Ch. 15 - Q1. Which change is likely to increase the rate of...Ch. 15 - The equilibrium constants at a fixed temperature...Ch. 15 - Q3. The concentrations of A,B, and C for the...Ch. 15 - Q4. What is the correct expression for the...Ch. 15 - Q5. Consider the reaction between NO and to form...Ch. 15 - Q6. The equilibrium constant for this reaction is...Ch. 15 - Prob. 7SAQCh. 15 - Q8. The decomposition of is endothermic.
Which...Ch. 15 - Prob. 9SAQCh. 15 - Prob. 10SAQ
Ch. 15 - Prob. 1ECh. 15 - Prob. 2ECh. 15 - 3. Why do chemists seek to control reaction...Ch. 15 - How do most chemical reactions occur?Ch. 15 - What factors influence reaction rates? How?Ch. 15 - Prob. 6ECh. 15 - 7. What is dynamic chemical equilibrium?
Ch. 15 - Prob. 8ECh. 15 - Explain why the concentrations of reactants and...Ch. 15 - Devise your own analogylike the Narnia and Middle...Ch. 15 - Prob. 11ECh. 15 - Write the expression for the equilibrium constant...Ch. 15 - What does a small equilibrium constant tell you...Ch. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - Prob. 16ECh. 15 - Prob. 17ECh. 15 - Prob. 18ECh. 15 - What is the effect of decreasing the concentration...Ch. 15 - Prob. 20ECh. 15 - Prob. 21ECh. 15 - What is the effect of increasing the pressure of a...Ch. 15 - Prob. 23ECh. 15 - Prob. 24ECh. 15 - 25. What is the effect of decreasing the pressure...Ch. 15 - 26. What is the effect of increasing the...Ch. 15 - 27. What is the effect of increasing the...Ch. 15 - Prob. 28ECh. 15 - Prob. 29ECh. 15 - Prob. 30ECh. 15 - Prob. 31ECh. 15 - Prob. 32ECh. 15 - Prob. 33ECh. 15 - Prob. 34ECh. 15 - Does a catalyst affect the value of the...Ch. 15 - Prob. 36ECh. 15 - Prob. 37ECh. 15 - Prob. 38ECh. 15 - The body temperature of cold-blooded animals...Ch. 15 - The rate of a particular reaction doubles when the...Ch. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Prob. 44ECh. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Prob. 47ECh. 15 - Prob. 48ECh. 15 - 49. For each equilibrium constant, indicate if you...Ch. 15 - Prob. 50ECh. 15 - Prob. 51ECh. 15 - 52. Consider the reaction.
An equilibrium mixture...Ch. 15 - Consider the reaction. 2H2S(g)2H2(g)+S2(g) An...Ch. 15 - Prob. 54ECh. 15 - Prob. 55ECh. 15 - Consider the reaction. CaCO3(s)CaCO(s)+CO2(g) An...Ch. 15 - Prob. 57ECh. 15 - Prob. 58ECh. 15 - Prob. 59ECh. 15 - Prob. 60ECh. 15 - Prob. 61ECh. 15 - Prob. 62ECh. 15 - Consider this reaction at equilibrium....Ch. 15 - Prob. 64ECh. 15 - Consider this reaction at equilibrium....Ch. 15 - Prob. 66ECh. 15 - Consider the effect of a volume change on this...Ch. 15 - Prob. 68ECh. 15 - Prob. 69ECh. 15 - Prob. 70ECh. 15 - Prob. 71ECh. 15 - Prob. 72ECh. 15 - Prob. 73ECh. 15 - Prob. 74ECh. 15 - Coal, which is primarily carbon, can be converted...Ch. 15 - 76. Coal can be used to generate hydrogen gas (a...Ch. 15 - 77. For each compound, write an equation showing...Ch. 15 - Prob. 78ECh. 15 - Prob. 79ECh. 15 - Prob. 80ECh. 15 - A saturated solution of MgF2 has [Mg2+]=2.6104M...Ch. 15 - Prob. 82ECh. 15 - Prob. 83ECh. 15 - Prob. 84ECh. 15 - Prob. 85ECh. 15 - Prob. 86ECh. 15 - Prob. 87ECh. 15 - 88. Calculate the molar solubility of .
Ch. 15 - Prob. 89ECh. 15 - Prob. 90ECh. 15 - 91. Consider the reaction.
A solution is made...Ch. 15 - Prob. 92ECh. 15 - Prob. 93ECh. 15 - Prob. 94ECh. 15 - This reaction is exothermic....Ch. 15 - Prob. 96ECh. 15 - 97. Calculate the molar solubility of CuS. How...Ch. 15 - Calculate the molar solubility of FeCO3. How many...Ch. 15 - Prob. 99ECh. 15 - Prob. 100ECh. 15 - Prob. 101ECh. 15 - Prob. 102ECh. 15 - Consider the reaction: CaCO3CaO(s)+CO2(g) A sample...Ch. 15 - Prob. 104ECh. 15 - A 2.55-L solution is 0.115 M in Mg2+. If K2CO3 is...Ch. 15 - Prob. 106ECh. 15 - Prob. 107ECh. 15 - Prob. 108ECh. 15 - One of the main components of hard water is CaCO3....Ch. 15 - Prob. 110ECh. 15 - The reaction A(g)+B(g)2C(g) has an equilibrium...Ch. 15 - Describe three ways a reaction at equilibrium can...Ch. 15 - Solid CaCO3 decomposes into solid CaO and gaseous...
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