ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
2nd Edition
ISBN: 9781118872925
Author: Klein
Publisher: JOHN WILEY+SONS INC.CUSTOM
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Chapter 1.5, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: For the given set of compounds the location of the partial charges that results due to inductive effect should be identified.

Concept Introduction: The nature of the bond depends on the electronegativity values of the shared electron pair of the involved atoms.

Electronegativity is the important chemical property of the elements in the periodic table.  It is the tendency of the atoms to attract electrons towards it.

If the difference in electronegativity is between 0.5 and 1.7, a bond between two different electronegative atoms becomes polar.  Most electronegative atoms get partial negative charge because they attract electrons from least electronegative atom towards it.  The least electronegative atoms get partial positive charge because it loses electrons towards most electronegative atoms.

The process of the attraction of electrons from electron-donating atoms (less electronegative atoms) towards electron-withdrawing atoms (most electronegative atoms) is called induction.  It can be represented by the following arrow:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  1

Here, chlorine atom has more electronegative than carbon atom.  Chlorine attracts electrons towards it.  This difference in electron density is called inductive effect.  It can be shown by Greek symbol delta ( δ ) as follows:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  2

To find: Categorize all polar covalent bonds in the given compound (a)

(b)

Interpretation Introduction

Interpretation: For the given set of compounds the location of the partial charges that results due to inductive effect should be identified.

Concept Introduction: The nature of the bond depends on the electronegativity values of the shared electron pair of the involved atoms.

Electronegativity is the important chemical property of the elements in the periodic table.  It is the tendency of the atoms to attract electrons towards it.

If the difference in electronegativity is between 0.5 and 1.7, a bond between two different electronegative atoms becomes polar.  Most electronegative atoms get partial negative charge because they attract electrons from least electronegative atom towards it.  The least electronegative atoms get partial positive charge because it loses electrons towards most electronegative atoms.

The process of the attraction of electrons from electron-donating atoms (less electronegative atoms) towards electron-withdrawing atoms (most electronegative atoms) is called induction.  It can be represented by the following arrow:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  3

Here, chlorine atom has more electronegative than carbon atom.  Chlorine attracts electrons towards it.  This difference in electron density is called inductive effect.  It can be shown by Greek symbol delta ( δ ) as follows:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  4

To find: Categorize all polar covalent bonds in the given compound (b)

(c)

Interpretation Introduction

Interpretation: For the given set of compounds the location of the partial charges that results due to inductive effect should be identified.

Concept Introduction: The nature of the bond depends on the electronegativity values of the shared electron pair of the involved atoms.

Electronegativity is the important chemical property of the elements in the periodic table.  It is the tendency of the atoms to attract electrons towards it.

If the difference in electronegativity is between 0.5 and 1.7, a bond between two different electronegative atoms becomes polar.  Most electronegative atoms get partial negative charge because they attract electrons from least electronegative atom towards it.  The least electronegative atoms get partial positive charge because it loses electrons towards most electronegative atoms.

The process of the attraction of electrons from electron-donating atoms (less electronegative atoms) towards electron-withdrawing atoms (most electronegative atoms) is called induction.  It can be represented by the following arrow:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  5

Here, chlorine atom has more electronegative than carbon atom.  Chlorine attracts electrons towards it.  This difference in electron density is called inductive effect.  It can be shown by Greek symbol delta ( δ ) as follows:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  6

To find: Categorize all polar covalent bonds in the given compound (c)

(d)

Interpretation Introduction

Interpretation: For the given set of compounds the location of the partial charges that results due to inductive effect should be identified.

Concept Introduction: The nature of the bond depends on the electronegativity values of the shared electron pair of the involved atoms.

Electronegativity is the important chemical property of the elements in the periodic table.  It is the tendency of the atoms to attract electrons towards it.

If the difference in electronegativity is between 0.5 and 1.7, a bond between two different electronegative atoms becomes polar.  Most electronegative atoms get partial negative charge because they attract electrons from least electronegative atom towards it.  The least electronegative atoms get partial positive charge because it loses electrons towards most electronegative atoms.

The process of the attraction of electrons from electron-donating atoms (less electronegative atoms) towards electron-withdrawing atoms (most electronegative atoms) is called induction.  It can be represented by the following arrow:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  7

Here, chlorine atom has more electronegative than carbon atom.  Chlorine attracts electrons towards it.  This difference in electron density is called inductive effect.  It can be shown by Greek symbol delta ( δ ) as follows:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  8

To find: Categorize all polar covalent bonds in the given compound (d)

(e)

Interpretation Introduction

Interpretation: For the given set of compounds the location of the partial charges that results due to inductive effect should be identified.

Concept Introduction: The nature of the bond depends on the electronegativity values of the shared electron pair of the involved atoms.

Electronegativity is the important chemical property of the elements in the periodic table.  It is the tendency of the atoms to attract electrons towards it.

If the difference in electronegativity is between 0.5 and 1.7, a bond between two different electronegative atoms becomes polar.  Most electronegative atoms get partial negative charge because they attract electrons from least electronegative atom towards it.  The least electronegative atoms get partial positive charge because it loses electrons towards most electronegative atoms.

The process of the attraction of electrons from electron-donating atoms (less electronegative atoms) towards electron-withdrawing atoms (most electronegative atoms) is called induction.  It can be represented by the following arrow:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  9

Here, chlorine atom has more electronegative than carbon atom.  Chlorine attracts electrons towards it.  This difference in electron density is called inductive effect.  It can be shown by Greek symbol delta ( δ ) as follows:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  10

To find: Categorize all polar covalent bonds in the given compound (e)

(f)

Interpretation Introduction

Interpretation: For the given set of compounds the location of the partial charges that results due to inductive effect should be identified.

Concept Introduction: The nature of the bond depends on the electronegativity values of the shared electron pair of the involved atoms.

Electronegativity is the important chemical property of the elements in the periodic table.  It is the tendency of the atoms to attract electrons towards it.

If the difference in electronegativity is between 0.5 and 1.7, a bond between two different electronegative atoms becomes polar.  Most electronegative atoms get partial negative charge because they attract electrons from least electronegative atom towards it.  The least electronegative atoms get partial positive charge because it loses electrons towards most electronegative atoms.

The process of the attraction of electrons from electron-donating atoms (less electronegative atoms) towards electron-withdrawing atoms (most electronegative atoms) is called induction.  It can be represented by the following arrow:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  11

Here, chlorine atom has more electronegative than carbon atom.  Chlorine attracts electrons towards it.  This difference in electron density is called inductive effect.  It can be shown by Greek symbol delta ( δ ) as follows:

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 1.5, Problem 15PTS , additional homework tip  12

To find: Categorize all polar covalent bonds in the given compound (f)

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As you can see in the picture, the instrument uses a Xe source. Given that the instrument is capable of measuring from 200-800nm, if Xe was not used, what other source(s) could be used? Refer to figure 7-3. How many monochrometers does this instrument have? Why? Trace the light as it goes from the Xenon lamp all the way to the circle just slightly to the right and a little bit down from S4. What do you think that circle is? In class we talked about many types of these, which kind do you think this one is for a fluorimeter? Why? Explain. What is/are some strategy(ies) that this instrument has for dealing with noise that you see present in the optics diagram? Why does a fluorescence cuvette have to be clear on four sides?
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ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<

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