Us Solutions Manual To Accompany Elements Of Physical Chemistry 7e
Us Solutions Manual To Accompany Elements Of Physical Chemistry 7e
7th Edition
ISBN: 9780198802259
Author: ATKINS
Publisher: Oxford University Press
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Chapter 15, Problem 15C.4ST
Interpretation Introduction

Interpretation:

Magnetic behaviour of Zn(s) and NO(g) has to be predicted.

Concept Introduction

Paramagnetic and Diamagnetic compounds

Paramagnetic compounds are attracted to magnetic fields and they have unpaired electrons.  Lithium, tantalum, magnesium are examples of paramagnetic materials.

Diamagnetic compounds are repelled from magnetic fields and their electrons are paired. Bismuth, antimony, copper, gold are examples of diamagnetic materials.

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3. a. Use the MS to propose at least two possible molecular formulas. For an unknown compound: 101. 27.0 29.0 41.0 50.0 52.0 55.0 57.0 100 57.5 58.0 58.5 62.0 63.0 64.0 65.0 74.0 40 75.0 76.0 20 20 40 60 80 100 120 140 160 180 200 220 m/z 99.5 68564810898409581251883040 115.0 116.0 77404799 17417M 117.0 12.9 118.0 33.5 119.0 36 133 0 1.2 157.0 2.1 159.0 16 169.0 219 170.0 17 171.0 21.6 172.0 17 181.0 1.3 183.0 197.0 100.0 198.0 200. 784 Relative Intensity 2 2 8 ō (ppm) 6 2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1. For an unknown compound with a molecular formula of C8H100: a. What is the DU? (show your work) b. Solve the structure and assign each of the following spectra. 8 6 2 ō (ppm) 4 2 0 200 150 100 50 ō (ppm) LOD D 4000 3000 2000 1500 1000 500 HAVENUMBERI -11
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