
Concept explainers
Interpretation:
The unit cell of silver, the unit cell dimension and mass density of silver has to be determined.
Concept Introduction:
Bragg’s law:
Where,
Density
Where,

Answer to Problem 15B.3P
The unit cell of silver, the unit cell dimension and mass density of silver has been found out to be FCC,
Explanation of Solution
Given data:
Expected reflections:
According to Bragg’s relationship,
This calculation is according to given data in the question.
Expected
But it is not matching with the calculated value.
Expected
But it is not matching with the calculated value.
Expected
It is matching with the calculated value.
Hence, the cubic unit cell of silver is FCC and the cell dimension is
Now, molar mass of silver is
Therefore, the mass density of silver is found out to be
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Chapter 15 Solutions
Student Solutions Manual to accompany Atkins' Physical Chemistry 11th edition
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