
Interpretation:
The cell voltage at each volume of
Concept Introduction:-
Cell Voltage:
Cell voltage is the difference between cathode potential and anode potential.
The unreacted concentration in the solution is determined by
Ion-selective electrode:
An ion-selective electrode (ISE) best known as a specific ion electrode (SIE), is a sensor (or transducer) that transforms the activity of a specific ion dissolved in a solution into an electrical potential.
Ion-selective electrode obeys following equation.

Explanation of Solution
Given:
The titration reaction is a reduction reaction.
The cell voltage of the reaction is written as
Cell Voltage:
Cell voltage is the difference between cathode potential and anode potential.
Where,
Another titration reaction is
The solubility constant for
The given equivalence point is
The unreacted
At
At
At
At
After
At
At
At
All the obtained potential are plotted as,
Figure 1
The cell voltage at each volume of
Want to see more full solutions like this?
Chapter 15 Solutions
Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
- HELP NOW PLEASE ! ASAP! URGENT!arrow_forwardHELP NOW PLEASE ! ASAP! URGENT!arrow_forwardWould the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forward
- Pls help.arrow_forward13) When solid barium phosphate is in equilibrium with its ions, the ratio of barium ions to phosphate ions would be: a. 1:1 b. 2:3 c. 3:2 d. 2:1 14) The pH of a 0.05 M solution of HCl(aq) at 25°C is 15) The pH of a 0.20 M solution of KOH at 25°C isarrow_forwardPls help.arrow_forward
- Pls help.arrow_forward16) A 2.0 L flask containing 2.0 x 10-3 mol H2(g), 3.0 x 10-3 mol Cl2(g), and 4.0 x 10-3 mol HCl(g) at equilibrium. This system is represented by the following chemical equation: H2 (g) + Cl2 (g) → 2HCl(g) Calculate the equilibrium constant for this reaction.arrow_forward7) The pH of a 0.05M solution of HCl(aq) at 25°C is a. 1.3 b. 2.3 c. 3.3 d. 12.7arrow_forward
- 11) The Ksp expression for copper (II) sulfate is: a. [Cu2+][SO4²¯] b. [Cu²+]² [SO4²]² c. [Cu²+]²[SO4²] d. [CuSO4] 12) Which of the following is true about a chemical system in equilibrium? a. All chemical reactions have stopped b. The concentration of reactants is equal to the concertation of products c. The forward and reverse reaction rates become equal d. The system will remain at equilibrium regardless of any external factorsarrow_forward21) Explain the difference between the rate of a reaction and the extent of a reaction. Why are both of these concepts important, if you are a chemical engineer that is trying to develop a process to produce a large volume of a specific type of chemical compound?arrow_forwardPls help.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY





