CHEMISTRY
13th Edition
ISBN: 9781292228860
Author: Timberlake
Publisher: PEARSON
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Answer
2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton
transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted
without ambiguity.
a.
CH3
Ph
OEt
هد
Ph
CH3
Hint: the species on the left is an ynolate, which behaves a lot like an enolate.
b.
CH3
H3C
CH3
CH3
H3C
an unexpected product,
containing a single 9-
membered ring
the expected product,
containing two fused rings
H3C-I
(H3C)2CuLi
an enolate
Chapter 15 Solutions
CHEMISTRY
Ch. 15.1 - Lipids are not soluble in water. Are lipids polar...Ch. 15.1 - Which of the following solvents might be used to...Ch. 15.1 - Prob. 15.3PPCh. 15.1 - Prob. 15.4PPCh. 15.2 - Describe some similarities and differences in the...Ch. 15.2 - Prob. 15.6PPCh. 15.2 - Prob. 15.7PPCh. 15.2 - Draw the line-angle formula for each of the...Ch. 15.2 - Prob. 15.9PPCh. 15.2 - For each of the following fatty acids, give the...
Ch. 15.2 - Prob. 15.11PPCh. 15.2 - How does the double bond influence the dispersion...Ch. 15.2 - Prob. 15.13PPCh. 15.2 - Prob. 15.14PPCh. 15.2 - Prob. 15.15PPCh. 15.2 - Prob. 15.16PPCh. 15.2 - Prob. 15.17PPCh. 15.2 - Prob. 15.18PPCh. 15.3 - Draw the condensed structural formula for the...Ch. 15.3 - Prob. 15.20PPCh. 15.3 - Prob. 15.21PPCh. 15.3 - Draw the condensed structural formula for a mixed...Ch. 15.3 - Prob. 15.23PPCh. 15.3 - Prob. 15.24PPCh. 15.3 - Prob. 15.25PPCh. 15.3 - Prob. 15.26PPCh. 15.3 - How does the perc entage of monounsaturated and...Ch. 15.3 - Prob. 15.28PPCh. 15.4 - Identify each of the following processes as...Ch. 15.4 - Identify each of the following processes as...Ch. 15.4 - Prob. 15.31PPCh. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Prob. 15.33PPCh. 15.4 - Prob. 15.34PPCh. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Prob. 15.37PPCh. 15.4 - Draw the condensed structural formula for all the...Ch. 15.5 - Prob. 15.39PPCh. 15.5 - Prob. 15.40PPCh. 15.5 - Draw the condensed structural formula for the...Ch. 15.5 - Draw the condensed structural formula for the...Ch. 15.5 - Prob. 15.43PPCh. 15.5 - Prob. 15.44PPCh. 15.5 - Prob. 15.45PPCh. 15.5 - Prob. 15.46PPCh. 15.6 - Draw the structure for the steroid nucleus.Ch. 15.6 - Draw the structure for cholesterol.Ch. 15.6 - Prob. 15.49PPCh. 15.6 - Prob. 15.50PPCh. 15.6 - Prob. 15.51PPCh. 15.6 - Prob. 15.52PPCh. 15.6 - Prob. 15.53PPCh. 15.6 - Prob. 15.54PPCh. 15.6 - Prob. 15.55PPCh. 15.6 - What are the similarities and differences between...Ch. 15.6 - Prob. 15.57PPCh. 15.6 - Prob. 15.58PPCh. 15.7 - What is the function if the lipid by layer in a...Ch. 15.7 - Prob. 15.60PPCh. 15.7 - Prob. 15.61PPCh. 15.7 - How do the unsaturated fatty acids in the...Ch. 15.7 - Prob. 15.63PPCh. 15.7 - Prob. 15.64PPCh. 15.7 - Prob. 15.65PPCh. 15.7 - 15.66 Identify the type of transport described by...Ch. 15.7 - Identify the functional groups in Pravachol.Ch. 15.7 - Identify the functional groups in Tri Cor.Ch. 15.7 - Prob. 15.69PPCh. 15.7 - Prob. 15.70PPCh. 15 - Prob. 15.71UTCCh. 15 - Prob. 15.72UTCCh. 15 - Prob. 15.73UTCCh. 15 - Prob. 15.74UTCCh. 15 - Prob. 15.75APPCh. 15 - Prob. 15.76APPCh. 15 - Prob. 15.77APPCh. 15 - Prob. 15.78APPCh. 15 - Identify each of the following as a fatty acid,...Ch. 15 - Identify each of the following as a fatty acid,...Ch. 15 - 15.81 Identify the components (1 to 6 ) contained...Ch. 15 - Prob. 15.82APPCh. 15 - Which of the following are found in cell...Ch. 15 - Which of the following are found in cell...Ch. 15 - Draw the condensed structural formula for a...Ch. 15 - sunflower seed oil can be used to make margarine....Ch. 15 - Prob. 15.87CPCh. 15 - 15.87 Match the lipoprotein (1 to 4) with its...Ch. 15 - 15.89 A sink drain can become clogged with solid...Ch. 15 - 15.90 One of the triacylglycerols in olive oil is...Ch. 15 - 15.91 1.00 mole of glyceryl trioleate (triolein)...Ch. 15 - The plastic known as PETE...Ch. 15 - Using the Internet, look up the condensed...Ch. 15 - The insect repellent DEET is an amide that can be...Ch. 15 - Glyceryl trimyristate (trimyristin) is found in...Ch. 15 - Prob. 31CICh. 15 - Prob. 32CI
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Similar questions
- b. H3C CH3 1. 2. H3O+ H3C MgBr H3Carrow_forwardPredict the major products of this reaction: excess H+ NaOH ? A Note that the first reactant is used in excess, that is, there is much more of the first reactant than the second. If there won't be any products, just check the box under the drawing area instead. Explanation Check Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use Privarrow_forward1. For each of the reaction "railroads" below, you are either asked to give the structure(s) of the starting material(s) or product(s), or provide reagents/conditions to accomplish the transformation, as indicated by the boxes. a. NaOMe H+ .CO,H HO₂C MeOH (excess) MeOH H3C Br يع CH3 1. LiAlH4 2. H3O+ 3. PBг3 H3C 1. Et-Li 2. H3O+ -CO₂Me -CO₂Me OH CH3 CH3 ল CH3arrow_forward
- Predict the intermediate 1 and final product 2 of this organic reaction: NaOMe ག1, ད།་, - + H You can draw 1 and 2 in any arrangement you like. 2 work up Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge) bonds at the chiral center. Explanation Check Click and drag to start drawing a structure. Х © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Parrow_forwardWhat is the total energy cost associated with the compound below adopting the shown conformation? CH3 HH DH CH3arrow_forwardΗΝ, Draw Final Product C cyclohexanone pH 4-5 Edit Enamine H3O+ CH3CH2Br THF, reflux H Edit Iminium Ionarrow_forward
- How many hydrogen atoms are connected to the indicated carbon atom?arrow_forwardIdentify the compound with the longest carbon - nitrogen bond. O CH3CH2CH=NH O CH3CH2NH2 CH3CH2C=N CH3CH=NCH 3 The length of all the carbon-nitrogen bonds are the samearrow_forwardIdentify any polar covalent bonds in epichlorohydrin with S+ and 8- symbols in the appropriate locations. Choose the correct answer below. Η H's+ 6Η Η Η Η Η Ηδ Η Ο Ο HH +Η Η +Η Η Η -8+ CIarrow_forward
- H H:O::::H H H HH H::O:D:D:H HH HH H:O:D:D:H .. HH H:O:D:D:H H H Select the correct Lewis dot structure for the following compound: CH3CH2OHarrow_forwardRank the following compounds in order of decreasing boiling point. ннннн -С-С-Н . н-с- ННННН H ΗΤΗ НННН TTTĪ н-с-с-с-с-о-н НННН НН C' Н н-с-с-с-с-н НН || Ш НННН H-C-C-C-C-N-H ННННН IVarrow_forwardRank the following compounds in order of decreasing dipole moment. |>||>||| ||>|||>| |>|||>|| |||>||>| O ||>>||| H F H F H c=c || H c=c F F IIIarrow_forward
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