General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
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Chapter 15, Problem 15.3QP
Interpretation Introduction
Interpretation:
An acid and base according to the Bronsted-Lowry concept has to be defined and an acid-base equation and acid-base spices involved in the equation has to be identified.
Concept introduction:
Acid:
According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.
Base:
According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ
Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions
about this system:
?
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
0.035 atm
✓
G
00.
18
Ar
Highlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area.
HO-
HO-
-0
OH
OH
HO
NG
HO-
HO-
OH
OH
OH
OH
NG
OH
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+
Suppose the molecule in the drawing area below were reacted with H₂ over a platinum catalyst. Edit the molecule to show what would happen to it. That is, turn
it into the product of the reaction.
Also, write the name of the product molecule under the drawing area.
Name: ☐
H
C=0
X
H-
OH
HO-
H
HO-
-H
CH₂OH
×
Chapter 15 Solutions
General Chemistry - Standalone book (MindTap Course List)
Ch. 15.2 - For the reaction H2CO3(aq)+CN(aq)HCN(aq)+HCO3(aq)...Ch. 15.2 - Prob. 15.1CCCh. 15.3 - Identify the Lewis acid and the Lewis base in each...Ch. 15.4 - Prob. 15.3ECh. 15.4 - Prob. 15.2CCCh. 15.5 - Which member of each of the following pairs is the...Ch. 15.7 - A solution of barium hydroxide at 25C is 0.125 M...Ch. 15.7 - Prob. 15.6ECh. 15.7 - Rank the following solutions from most acidic to...Ch. 15.8 - What is the pH of a sample of gastric juice...
Ch. 15.8 - A saturated solution of calcium hydroxide has a...Ch. 15.8 - A brand of carbonated beverage has a pH of 3.16....Ch. 15.8 - A 0.010 M solution of ammonia, NH3, has a pH of...Ch. 15.8 - Prob. 15.4CCCh. 15 - Which of the following are strong acids? Which are...Ch. 15 - Describe any thermochemical (heat of reaction)...Ch. 15 - Prob. 15.3QPCh. 15 - Prob. 15.4QPCh. 15 - Write an equation in which H2PO3 acts as an acid...Ch. 15 - Describe four ways in which the BrnstedLowry...Ch. 15 - Prob. 15.7QPCh. 15 - Explain why an acidbase reaction favors the weaker...Ch. 15 - Give two important factors that determine the...Ch. 15 - Prob. 15.10QPCh. 15 - Prob. 15.11QPCh. 15 - Prob. 15.12QPCh. 15 - Prob. 15.13QPCh. 15 - Prob. 15.14QPCh. 15 - The conjugate base of hydrofluoric acid dissolved...Ch. 15 - In the following reaction, identify the Lewis...Ch. 15 - Calculate the hydronium-ion concentration at 25C...Ch. 15 - The pH of a solution is 9.55 at 25C What is the...Ch. 15 - Acids You make a solution by dissolving 0.0010 mol...Ch. 15 - Strong Acids, Weak Acids, and pH Two 0.10-mol...Ch. 15 - Prob. 15.21QPCh. 15 - Prob. 15.22QPCh. 15 - Prob. 15.23QPCh. 15 - Compare the structures of HNO2 and H2CO3. Which...Ch. 15 - Prob. 15.25QPCh. 15 - Prob. 15.26QPCh. 15 - A strong monoprotic acid, with the molecular...Ch. 15 - A weak acid, HA, is dissolved in water. Which one...Ch. 15 - Write the balanced reaction of hydroxide ion with...Ch. 15 - Write the balanced reaction of hypobromous acid,...Ch. 15 - Give the conjugate base to each of the following...Ch. 15 - Give the conjugate base to each of the following...Ch. 15 - Give the conjugate acid to each of the following...Ch. 15 - Give the conjugate acid to each of the following...Ch. 15 - For the following reactions, label each species as...Ch. 15 - For the following reactions, label each species as...Ch. 15 - The following shows ball-and-stick models of the...Ch. 15 - The following shows ball-and-stick models of the...Ch. 15 - Complete each of the following equations. Then...Ch. 15 - Complete each of the following equations. Then...Ch. 15 - In the following reactions, identify each reactant...Ch. 15 - In the following reactions, label each reactant as...Ch. 15 - Natural gas frequently contains hydrogen sulfide,...Ch. 15 - Coal and other fossil fuels usually contain sulfur...Ch. 15 - Complete the following equation. Using Table 15.2,...Ch. 15 - Complete the following equation. Using Table 15.2,...Ch. 15 - Use Table 15.2 to decide whether the species on...Ch. 15 - Use Table 15.2 to decide whether the species on...Ch. 15 - Prob. 15.49QPCh. 15 - In the following reaction of tetrafluoroboric...Ch. 15 - For each of the following pairs, give the stronger...Ch. 15 - Order each of the following pairs by acid...Ch. 15 - What are the concentrations of H3O+ and OH in each...Ch. 15 - What are the concentrations of H3O+ and OH in each...Ch. 15 - A solution of hydrochloric acid is 0.059 M HCl....Ch. 15 - A solution is 0.030 M HNO3 (nitric acid). What is...Ch. 15 - What are the hydronium-ion and the hydroxide-ion...Ch. 15 - A saturated solution of magnesium hydroxide is 3.2...Ch. 15 - The following are solution concentrations....Ch. 15 - The following are solution concentrations....Ch. 15 - A shampoo solution at 25C has a hydroxide-ion...Ch. 15 - An antiseptic solution at 25C has a hydroxide-ion...Ch. 15 - Which of the following pH values indicate an...Ch. 15 - Which of the following pH values indicate an...Ch. 15 - For each of the following, state whether the...Ch. 15 - Prob. 15.66QPCh. 15 - Obtain the pH corresponding to the following...Ch. 15 - Obtain the pH corresponding to the following...Ch. 15 - A sample of vinegar has a hydronium-ion...Ch. 15 - Some lemon juice has a hydronium-ion concentration...Ch. 15 - Obtain the pH corresponding to the following...Ch. 15 - Obtain the pH corresponding to the following...Ch. 15 - A solution of washing soda (sodium carbonate,...Ch. 15 - A solution of lye (sodium hydroxide, NaOH) has a...Ch. 15 - The pH of a cup of coffee (at 25C) was found to be...Ch. 15 - A wine was tested for acidity, and its pH was...Ch. 15 - A detergent solution has a pH of 11.80 at 25C....Ch. 15 - Morphine is a narcotic that is used to relieve...Ch. 15 - A 1.00-L aqueous solution contained 5.80 g of...Ch. 15 - A 1.00-L aqueous solution contained 6.78 g of...Ch. 15 - A certain sample of rainwater gives a yellow color...Ch. 15 - A drop of thymol blue gave a yellow color with a...Ch. 15 - Identify each of the following as an acid or a...Ch. 15 - Which of the following substances are acids in...Ch. 15 - Write a reaction for each of the following in...Ch. 15 - Write a reaction for each of the following in...Ch. 15 - Prob. 15.87QPCh. 15 - Prob. 15.88QPCh. 15 - Prob. 15.89QPCh. 15 - Prob. 15.90QPCh. 15 - Prob. 15.91QPCh. 15 - List the following compounds in order of...Ch. 15 - A solution is 0.18 M KOH. What are the...Ch. 15 - A solution is 0.25 M Sr(OH)2. What are the...Ch. 15 - Prob. 15.95QPCh. 15 - A sample of lemon juice has a hydronium-ion...Ch. 15 - Prob. 15.97QPCh. 15 - A sample of grape juice has a pH of 4.15. What is...Ch. 15 - A 4.640-g sample of a mixture of sodium hydrogen...Ch. 15 - A 2.500-g sample of a mixture of sodium carbonate...Ch. 15 - Prob. 15.101QPCh. 15 - The dihydrogen phosphate ion has the ability to...Ch. 15 - Prob. 15.103QPCh. 15 - Prob. 15.104QPCh. 15 - Prob. 15.105QPCh. 15 - Show how methylamine, CH3NH2, is a BrnstedLowry...Ch. 15 - Prob. 15.107QPCh. 15 - Prob. 15.108QPCh. 15 - Prob. 15.109QPCh. 15 - Prob. 15.110QPCh. 15 - Prob. 15.111QPCh. 15 - Hydrazine, N2H4 (having the structure H2NNH2), and...Ch. 15 - Prob. 15.113QPCh. 15 - Liquid ammonia undergoes autoionization similar to...Ch. 15 - Ethanol (ethyl alcohol), CH3CH2OH, can act as a...Ch. 15 - Ethanol, CH3CH2OH, can undergo auto-ionization....Ch. 15 - Aluminum chloride, AlCl3, reacts with...Ch. 15 - Consider each of the following pairs of compounds,...Ch. 15 - Arrange each of the following in order of...Ch. 15 - The following is a table of some of the oxoacids...Ch. 15 - Suppose you have 557 mL of 0.0300 M HCl, and you...Ch. 15 - Prob. 15.122QPCh. 15 - You want to make up 3.00 L of aqueous hydrochloric...Ch. 15 - Prob. 15.124QPCh. 15 - Prob. 15.125QPCh. 15 - Pure liquid ammonia ionizes in a way similar to...Ch. 15 - A solution contains 4.25g of ammonia per 250.0 mL...Ch. 15 - A solution contains 0.675 g of ethylamine,...Ch. 15 - Prob. 15.129QPCh. 15 - Hypophosphorous acid, H3PO2, and phosphoric acid,...Ch. 15 - Boron trifluoride, BF3, and ammonia, NH3, react to...Ch. 15 - Boron trifluoride, BF3, and diethyl ether,...
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