Concept explainers
(a)
Interpretation: The class of given cycloocta-1,4-diene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(a)
Answer to Problem 15.24SP
The given compound is classified as isolated diene.
Explanation of Solution
The structure of given diene is shown in figure 1.
Figure 1
It is conferred from the above structure of
(b)
Interpretation: The class of given cycloocta-1,3-diene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(b)
Answer to Problem 15.24SP
The given compound is classified as conjugated diene.
Explanation of Solution
The structure of given diene is shown in figure 2.
Figure 2
It is conferred from the above structure of
(c)
Interpretation: The class of given cycloocta-1,2-diene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(c)
Answer to Problem 15.24SP
The given compound is classified as cumulated diene.
Explanation of Solution
The structure of given diene is shown in figure 3.
Figure 3
It is conferred from the above structure of
(d)
Interpretation: The class of given cycloocta-1,2,5,7-tetraene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(d)
Answer to Problem 15.24SP
The given compound is classified as conjugated polyene.
Explanation of Solution
The structure of given polyene is shown in figure 4.
Figure 4
It is conferred from the above structure of
(e)
Interpretation: The class of given cyclohexa-1,3,5-triene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(e)
Answer to Problem 15.24SP
The given compound is classified as conjugated polyene.
Explanation of Solution
The structure of the given polyene is shown in figure 5.
Figure 5
It is conferred from the above structure of
(f)
Interpretation: The class of given penta-1,2-4-triene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(f)
Answer to Problem 15.24SP
The given compound is classified as cumulated and conjugated polyene.
Explanation of Solution
The structure of given polyene is shown in figure 6.
Figure 6
It is conferred from the above structure of
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Chapter 15 Solutions
Organic Chemistry, Books a la Carte Edition (9th Edition)
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