Concept explainers
(a)
Interpretation: The class of given cycloocta-1,4-diene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(a)
Answer to Problem 15.24SP
The given compound is classified as isolated diene.
Explanation of Solution
The structure of given diene is shown in figure 1.
Figure 1
It is conferred from the above structure of
(b)
Interpretation: The class of given cycloocta-1,3-diene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(b)
Answer to Problem 15.24SP
The given compound is classified as conjugated diene.
Explanation of Solution
The structure of given diene is shown in figure 2.
Figure 2
It is conferred from the above structure of
(c)
Interpretation: The class of given cycloocta-1,2-diene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(c)
Answer to Problem 15.24SP
The given compound is classified as cumulated diene.
Explanation of Solution
The structure of given diene is shown in figure 3.
Figure 3
It is conferred from the above structure of
(d)
Interpretation: The class of given cycloocta-1,2,5,7-tetraene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(d)
Answer to Problem 15.24SP
The given compound is classified as conjugated polyene.
Explanation of Solution
The structure of given polyene is shown in figure 4.
Figure 4
It is conferred from the above structure of
(e)
Interpretation: The class of given cyclohexa-1,3,5-triene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(e)
Answer to Problem 15.24SP
The given compound is classified as conjugated polyene.
Explanation of Solution
The structure of the given polyene is shown in figure 5.
Figure 5
It is conferred from the above structure of
(f)
Interpretation: The class of given penta-1,2-4-triene as isolated, conjugated, cumulated, or a combination is to be stated.
Concept introduction: Conjugated systems have alternate single and double bonds that results in lower the energy and increase the stability of a molecule. Isolated dienes or polyenes are the compounds that comprise double bonds at the large distances separated by more than one single bond, whereas cumulated dienes or polyenes are the compounds that do not possess any single bond in between the two double bonds.
(f)
Answer to Problem 15.24SP
The given compound is classified as cumulated and conjugated polyene.
Explanation of Solution
The structure of given polyene is shown in figure 6.
Figure 6
It is conferred from the above structure of
Want to see more full solutions like this?
Chapter 15 Solutions
Organic Chemistry, Books a la Carte Edition (9th Edition)
- consider the rate of the reaction below to be r. Whats the rate after each reaction? Br + NaCN CN + NaBr a. Double the concentration of alkyl bromide b. Halve the concentration of the electrophile & triple concentration of cyanide c. Halve the concentration of alkyl chloridearrow_forwardPredict the organic reactant that is involved in the reaction below, and draw the skeletal ("line") structures of the missing organic reactant. Please include all steps & drawings & explanations.arrow_forwardWhat are the missing reagents for the spots labeled 1 and 3? Please give a detailed explanation and include the drawings and show how the synthesis proceeds with the reagents.arrow_forward
- What is the organic molecule X of the following acetal hydrolysis? Please draw a skeletal line structure and include a detailed explanation and drawing of how the mechanism proceeds. Please include any relevant information that is needed to understand the process of acetal hydrolysis.arrow_forwardWhat are is the organic molecule X and product Y of the following acetal hydrolysis? Please draw a skeletal line structure and include a detailed explanation and drawing of how the mechanism proceeds. Please include any relevant information that is needed to understand the process of acetal hydrolysis.arrow_forwardAt 300 K, in the decomposition reaction of a reactant R into products, several measurements of the concentration of R over time have been made (see table). Without using graphs, calculate the order of the reaction. t/s [R]/(mol L-1) 0 0,5 171 0,16 720 0,05 1400 0,027arrow_forward
- Predict the organic products that form in the reaction below, and draw the skeletal ("line") structures of the missing organic products. Please include all steps & drawings & explanations.arrow_forwardWhat are the missing reagents for the spots labeled 1 and 3? Please give a detailed explanation and include the drawings and show how the synthesis proceeds with the reagents.arrow_forwardWhat are the products of the following acetal hydrolysis? Please draw a skeletal line structure and include a detailed explanation and drawing of how the mechanism proceeds. Please include any relevant information that is needed to understand the process of acetal hydrolysis.arrow_forward
- What would happen if you added the HCI to the Grignard reagent before adding benzophenone? Draw a reaction mechanism to support your answer.arrow_forwardAt 300 K, in the decomposition reaction of a reactant R into products, several measurements of the concentration of R over time have been made (see table). Calculate the order of the reaction. t/s [R]/ (mol L-1) 0 0,5 171 0,16 720 0,05 1400 0,027arrow_forwardWrite the correct IUPAC names of the molecules in the picturearrow_forward
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
EBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENT