OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months)
OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months)
11th Edition
ISBN: 9781305106734
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell; Shawn O. Farrell; Omar Torres
Publisher: Cengage Learning US
bartleby

Concept explainers

bartleby

Videos

Question
Book Icon
Chapter 15, Problem 15.18P
Interpretation Introduction

(a)

Interpretation:

To write the structural formula of the lowest molecular weight chiral molecule of alkane.

Concept Introduction:

A molecule is said to be chiral if it cannot be superimposed on its mirror image and if it does not possess an alternate axis of symmetry.

A carbon atom bonded in a tetrahedral structure to four different substituents in a molecule, it is called as a chiral centre or stereocentre.

If an organic molecule has more than one chiral carbon or chiral centre then the molecule may be achiral or chiral and it is depend upon whether the molecule has element of symmetry or not.

The elements of symmetry are-

  • A plane of symmetry
  • A centre of symmetry
  • n-fold alternating axis of symmetry.

Expert Solution
Check Mark

Answer to Problem 15.18P

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  1

Explanation of Solution

Since alkanes consist of only carbon and hydrogen, the lowest molecular weight alkane can have four different groups attached to it namely- hydrogen, methyl group, ethyl group, and propyl group.

So the molecule so formed is: 3-Methyl-Hexane.

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  2

3-Methyl-Hexane.

Interpretation Introduction

(b)

Interpretation:

To write the structural formula of the lowest molecular weight chiral molecule of alkene.

Concept Introduction:

A molecule is said to be chiral if it cannot be superimposed on its mirror image and if it does not possess an alternate axis of symmetry.

A carbon atom bonded in a tetrahedral structure to four different substituents in a molecule, it is called as a chiral centre or stereocentre.

If an organic molecule has more than one chiral carbon or chiral centre then the molecule may be achiral or chiral and it is depend upon whether the molecule has element of symmetry or not.

The elements of symmetry are-

  • A plane of symmetry
  • A centre of symmetry
  • n-fold alternating axis of symmetry.

Expert Solution
Check Mark

Answer to Problem 15.18P

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  3

Explanation of Solution

Since alkenes consist of only carbon and hydrogen, with a double bond, the lowest molecular weight alkene can have four different groups attached to it namely- hydrogen, methyl group, vinyl group, and ethyl group.

So the molecule so formed is: 3-Methyl-Pent-1-ene.

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  4

Interpretation Introduction

(c)

Interpretation:

To write the structural formula of the lowest molecular weight chiral molecule of alcohol.

Concept Introduction:

A molecule is said to be chiral if it cannot be superimposed on its mirror image and if it does not possess an alternate axis of symmetry.

A carbon atom bonded in a tetrahedral structure to four different substituents in a molecule, it is called as a chiral centre or stereocentre.

If an organic molecule has more than one chiral carbon or chiral centre then the molecule may be achiral or chiral and it is depend upon whether the molecule has element of symmetry or not.

The elements of symmetry are-

  • A plane of symmetry
  • A centre of symmetry
  • n-fold alternating axis of symmetry.

Expert Solution
Check Mark

Answer to Problem 15.18P

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  5

Explanation of Solution

Since alcohol consist of carbon and hydrogen and oxygen, the lowest molecular weight alcohol can have four different groups attached to it namely- hydrogen, methyl group, hydroxyl group, and ethyl group.

So, the molecule so formed is: 2-Butanol.

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  6

Interpretation Introduction

(d)

Interpretation:

To write the structural formula of the lowest molecular weight chiral molecule of alcohol.

Concept Introduction:

A molecule is said to be chiral if it cannot be superimposed on its mirror image and if it does not possess an alternate axis of symmetry.

A carbon atom bonded in a tetrahedral structure to four different substituents in a molecule, it is called as a chiral centre or stereocentre.

If an organic molecule has more than one chiral carbon or chiral centre then the molecule may be achiral or chiral and it is depend upon whether the molecule has element of symmetry or not.

The elements of symmetry are-

  • A plane of symmetry
  • A centre of symmetry
  • n-fold alternating axis of symmetry.

Expert Solution
Check Mark

Answer to Problem 15.18P

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  7

Explanation of Solution

Since aldehyde consists of carbon and hydrogen and oxygen, the lowest molecular weight aldehyde can have four different groups attached to it namely- hydrogen, methyl group, -CHO group, and ethyl group.

So the molecule so formed is: 2-Methyl-Butan-1-al.

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  8

Interpretation Introduction

(e)

Interpretation:

To write the structural formula of the lowest molecular weight chiral molecule of alcohol.

Concept Introduction:

A molecule is said to be chiral if it cannot be superimposed on its mirror image and if it does not possess an alternate axis of symmetry.

A carbon atom bonded in a tetrahedral structure to four different substituents in a molecule, it is called as a chiral centre or stereocentre.

If an organic molecule has more than one chiral carbon or chiral centre then the molecule may be achiral or chiral and it is depend upon whether the molecule has element of symmetry or not.

The elements of symmetry are-

  • A plane of symmetry
  • A centre of symmetry
  • n-fold alternating axis of symmetry.

Expert Solution
Check Mark

Answer to Problem 15.18P

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  9

Explanation of Solution

Since ketone consist of carbon and hydrogen and oxygen, the lowest molecular weight ketone can have four different groups attached to it namely- hydrogen, methyl group, -C=O group, and ethyl group.

So, the molecule so formed is: 3-Methyl-Pentan-2-one.

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  10

Interpretation Introduction

(f)

Interpretation:

To write the structural formula of the lowest molecular weight chiral molecule of alcohol.

Concept Introduction:

A molecule is said to be chiral if it cannot be superimposed on its mirror image and if it does not possess an alternate axis of symmetry.

A carbon atom bonded in a tetrahedral structure to four different substituents in a molecule, it is called as a chiral centre or stereocentre.

If an organic molecule has more than one chiral carbon or chiral centre then the molecule may be achiral or chiral and it is depend upon whether the molecule has element of symmetry or not.

The elements of symmetry are-

  • A plane of symmetry
  • A centre of symmetry
  • n-fold alternating axis of symmetry.

Expert Solution
Check Mark

Answer to Problem 15.18P

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  11

Explanation of Solution

Since carboxylic acid consist of carbon and hydrogen and oxygen, the lowest molecular weight carboxylic acid can have four different groups attached to it namely- hydrogen, methyl group, carboxylic acid group and ethyl group.

So, the molecule so formed is: 2-Methyl-Butan-1-oic acid.

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months), Chapter 15, Problem 15.18P , additional homework tip  12

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
22:22 Tue 11 Jan * 84% Done Assignment 3 (3 of 9) 1. Identify the functional groups in the following molecules: (a) (b) (c) H. H С—ОН С-ОН Н-С—ОН C=C H H HO-C-H C-CH3 Н-С—ОН Acrylic acid (2 functional groups) H-C-OH Aspirin (3 functional groups) CH2OH Glucose (6 functional groups) 2. Identify the carbon atoms in the following molecules as primary, secondary tertiary, or quaternary: (a) CH3 (b) CH3CHCH3 (c) CH3 CH3 CH3CHCH2CH2CH3 CH3CH2CHCH2CH3 CH3CHCH,CCH3 ČH3 3. Give IUPAC names for the following alkanes: (a) CH3 (b) CH3 CH3CHCH2CH2CH3 CH3CH2ĊCH3 ČH3 (c) H3C CH3 (d) CH2CH3 CH3 CH3CHCCH2CH2CH3 CH3CH2CHCH2CH2CHCH3 CH3 (e) CH3 CH2CH3 (f) H3C CH3 CH3CH2CH2CHCH2CCH3 CH3C-CCH2CH2CH3 CH3 H3C CH3 4. Draw structures for the following substances: (a) 2-Methylheptane (c) 4-Ethyl-3,4-dimethyloctane (e) 1,1-Dimethylcyclopentane (b) 4-Ethyl-2-methylhexane (d) 2,4,4-Trimethylheptane (f) 4-Isopropyl-3-methylheptane
Using only C, H, and O, write structural formulas for the lowest-molecular-weight chiral. Q) Alkane
(a) Consider structure Y. OH CH3 C-0-CH3 Structure Y i. Redraw structure Y, circle and name all the functional groups that exist in Y. ii. Label the chiral carbons in asterisks(*).

Chapter 15 Solutions

OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months)

Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
  • Text book image
    Introduction to General, Organic and Biochemistry
    Chemistry
    ISBN:9781285869759
    Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
    Publisher:Cengage Learning
    Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305580350
    Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
    Publisher:Cengage Learning
Text book image
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Acid-Base Titration | Acids, Bases & Alkalis | Chemistry | FuseSchool; Author: FuseSchool - Global Education;https://www.youtube.com/watch?v=yFqx6_Y6c2M;License: Standard YouTube License, CC-BY