INTOR TO CHEMISTRY LLF
5th Edition
ISBN: 9781264501731
Author: BAUER
Publisher: MCG
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Chapter 15, Problem 123QP
Interpretation Introduction
Interpretation:
The statement that describes a way in which fission and fusion reactions are similar is to be identified.
Introduction:
The nuclear reactions that produce a large amount of energy are fission and fusion reactions. The nuclear fission reaction involves the spontaneous splitting of heavy nucleus, forming two or more lighter nuclei. The nuclear fusion reaction involves a combination of lighter nuclei to form heavier nucleus.
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Given the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 low
A 2-step reaction has the following mechanism:
|
1. (fast) R2
R+R
2. (slow) R+Q
K₂ P
k_1
What series does it have?
(A). v=
-
= (k + k1 − k-1)[R2][Q]
(B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q]
(C). v=k₂[R]²[Q]²
(D). v = k[R₂]1/2[Q]
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 15 Solutions
INTOR TO CHEMISTRY LLF
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