Explanation We are told that the reaction is first order with CHCl3 and one-half order with Cl2. The rate of the reaction can be expressed as follows: rate = k[CHCl 3 ][cl 2 ] 1/2 In reaction A, we will assume there are 3 moles of CHCl 3 and 3 moles of Cl 2 . If we just roughly compare these values by entering them into the rate expression we will get: r a t e = k [ 3 ] [ 3 ] 1 / 2 = 5.2 k Reaction B has 4 moles of CHCl 3 and 2 moles of Cl 2 ...

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ISBN: 9780321834683

Author: Nivaldo J. Tro

Publisher: PEARSON

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Chapter 15, Problem 120E

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To determine: The reaction having the fastest initial rate.

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Chapter 15, Problem 119E

Chapter 15, Problem 121E

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Chapter 15 Solutions

Chemistry: Structure and Properties

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The reaction having the fastest initial rate.

Solution Summary: The author explains that reaction b will have the fastest initial rate.

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To determine: The reaction having the fastest initial rate.

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