
Interpretation:
The structure of aldrin formed by the Diels-Alder reaction of hexachloro-1,3-cyclopentadiene with norbornadiene is to be given.
Concept introduction:
In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond and if the diene adapts a s-cis conformation during the reaction. The addition takes place in endo manner.
To give:
The structure of aldrin formed by the Diels-Alder reaction of hexachloro-1,3-cyclopentadiene with norbornadiene.

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Chapter 14 Solutions
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