Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition)

8th Edition

ISBN: 9780134649771

Author: Paula Yurkanis Bruice

Publisher: PEARSON

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Textbook Question

Chapter 14.10, Problem 21P

The ¹H NMR spectra of two carboxylic acids with molecular formula C₃H₅O₂Cl are shown below. Identify the carboxylic acids. (The “offset” notation means that the farthest-left signal has been moved to the right by the indicated amount to fit on the spectrum; thus, the signal at 9.8 ppm offset by 2.4 ppm has an actual chemical shift of 9.8 + 2.4 = 12.2 ppm.)

Chapter 14.10, Problem 21P, The 1H NMR spectra of two carboxylic acids with molecular formula C3H5O2Cl are shown below. Identify

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

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Chapter 14.10, Problem 20P

Chapter 14.11, Problem 22P

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Chapter 14 Solutions

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition)

Ch. 14.1 - Prob. 1P Ch. 14.1 - Prob. 2P Ch. 14.4 - How many signals would you expect to see in the 1H...Ch. 14.4 - How many signals would you expect to see in the 1H...Ch. 14.4 - How could you distinguish the 1H NMR spectra of...Ch. 14.4 - Draw an isomer of dichlorocyclopropane that gives...Ch. 14.5 - Prob. 7P Ch. 14.5 - Prob. 8P Ch. 14.5 - Prob. 9P Ch. 14.5 - Where would you expect to find the 1H NMR signal...

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Solution Summary: The author explains that the spectrum of a compound provides vital information that is required to predict the structure of the compound.

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Chapter 14 Solutions