Chemistry: A Molecular Approach; Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition (4th Edition)
4th Edition
ISBN: 9780134568188
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 14, Problem 76E
(a)
Interpretation Introduction
To determine: Whether the reaction in which X and Y collide occurs in a single step.
(b)
Interpretation Introduction
To determine: Whether the given mechanism is valid for the reaction or not.
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Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.
-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
Chapter 14 Solutions
Chemistry: A Molecular Approach; Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition (4th Edition)
Ch. 14 - Prob. 1SAQCh. 14 - Q2. Dinitrogen monoxide decomposes into nitrogen...Ch. 14 - Q3. This plot shows the rate of the decomposition...Ch. 14 - Q4. For the reaction 2 A + B → C, the initial rate...Ch. 14 - Prob. 5SAQCh. 14 - Prob. 6SAQCh. 14 - Prob. 7SAQCh. 14 - Prob. 8SAQCh. 14 - Q9. The rate constant of a reaction is measured at...Ch. 14 - Prob. 10SAQ
Ch. 14 - Prob. 11SAQCh. 14 - Q12. Which statement is true regarding the...Ch. 14 - Prob. 13SAQCh. 14 - Q14. Use collision theory to determine which...Ch. 14 - Q15. Carbon monoxide and chlorine gas react to...Ch. 14 - Prob. 1ECh. 14 - Prob. 2ECh. 14 - Prob. 3ECh. 14 - 4. Why is the reaction rate for reactants defined...Ch. 14 - Prob. 5ECh. 14 - Prob. 6ECh. 14 - Prob. 7ECh. 14 - 8. For a reaction with multiple reactants, how is...Ch. 14 - 9. Explain the difference between the rate law for...Ch. 14 - 10. Write integrated rate laws for zero-order,...Ch. 14 - Prob. 11ECh. 14 - 12. How do reaction rates typically depend on...Ch. 14 - Prob. 13ECh. 14 - 14. What is an Arrhenius plot? Explain the...Ch. 14 - Prob. 15ECh. 14 - Prob. 16ECh. 14 - 17. In a reaction mechanism, what is an elementary...Ch. 14 - 18. What are the two requirements for a proposed...Ch. 14 - 19. What is an intermediate within a reaction...Ch. 14 - Prob. 20ECh. 14 - 21. Explain the difference between homogeneous...Ch. 14 - Prob. 22ECh. 14 - Prob. 23ECh. 14 - Prob. 24ECh. 14 - 25. Consider the reaction:
2 HBr(g) → H2(g) +...Ch. 14 - 26. Consider the reaction:
2 N2O(g) → 2 N2(g) +...Ch. 14 - 27. For the reaction 2 A(g) + B(g) → 3 C(g),
a....Ch. 14 - 28. For the reaction A(g) + B(g) → 2 C(g),
a....Ch. 14 - 29. Consider the reaction:
Cl2(g) + 3 F2(g) → 2...Ch. 14 - Prob. 30ECh. 14 - Prob. 31ECh. 14 - Prob. 32ECh. 14 - Prob. 33ECh. 14 - 34. Consider the reaction:
2 H2O2(aq) → 2 H2O(l) +...Ch. 14 - Prob. 35ECh. 14 - Prob. 36ECh. 14 - Prob. 37ECh. 14 - 38. This reaction is first order in N2O5:
N2O5(g)...Ch. 14 - Prob. 39ECh. 14 - Prob. 40ECh. 14 - Prob. 41ECh. 14 - 42. Consider the data showing the initial rate of...Ch. 14 - Prob. 43ECh. 14 - Prob. 44ECh. 14 - 45. The tabulated data were collected for this...Ch. 14 - 46. The tabulated data were collected for this...Ch. 14 - 47. Indicate the order of reaction consistent with...Ch. 14 - 48. Indicate the order of reaction consistent with...Ch. 14 - 49. The tabulated data show the concentration of...Ch. 14 - Prob. 50ECh. 14 - 51. The tabulated data show the concentration of...Ch. 14 - 52. The reaction A → products was monitored as a...Ch. 14 - Prob. 53ECh. 14 - Prob. 54ECh. 14 - Prob. 55ECh. 14 - Prob. 56ECh. 14 - 57. The half-life for the radioactive decay of...Ch. 14 - 58. The half-life for the radioactive decay of...Ch. 14 - Prob. 59ECh. 14 - Prob. 60ECh. 14 - Prob. 61ECh. 14 - Prob. 62ECh. 14 - Prob. 63ECh. 14 - Prob. 64ECh. 14 - 65. The data shown here were collected for the...Ch. 14 - Prob. 66ECh. 14 - 67. The tabulated data were collected for the...Ch. 14 - 68. The tabulated data show the rate constant of a...Ch. 14 - 69. A reaction has a rate constant of 0.0117/s at...Ch. 14 - 70. A reaction has a rate constant of 0.000122/s...Ch. 14 - Prob. 71ECh. 14 - Prob. 72ECh. 14 - Prob. 73ECh. 14 - Prob. 74ECh. 14 - Prob. 75ECh. 14 - Prob. 76ECh. 14 - Prob. 77ECh. 14 - Prob. 78ECh. 14 - 79. Many heterogeneous catalysts are deposited on...Ch. 14 - 80. Suppose that the reaction A → products is...Ch. 14 - 81. Suppose that a catalyst lowers the activation...Ch. 14 - Prob. 82ECh. 14 - Prob. 83ECh. 14 - Prob. 84ECh. 14 - Prob. 85ECh. 14 - Prob. 86ECh. 14 - Prob. 87ECh. 14 - Prob. 88ECh. 14 - Prob. 89ECh. 14 - Prob. 90ECh. 14 - 91. Iodine atoms combine to form I2 in liquid...Ch. 14 - 92. The hydrolysis of sucrose (C12H22O11) into...Ch. 14 - Prob. 93ECh. 14 - Prob. 94ECh. 14 - Prob. 95ECh. 14 - Prob. 96ECh. 14 - 97. The desorption (leaving of the surface) of a...Ch. 14 - Prob. 98ECh. 14 - 99. The kinetics of this reaction were studied as...Ch. 14 - Prob. 100ECh. 14 - Prob. 101ECh. 14 - 102. Consider the two reactions:
a. Why is the...Ch. 14 - 103. Anthropologists can estimate the age of a...Ch. 14 - 104. Geologists can estimate the age of rocks by...Ch. 14 - Prob. 105ECh. 14 - 106. Consider the reaction:
2 NH3(aq) + OCl–(aq) →...Ch. 14 - Prob. 107ECh. 14 - Prob. 108ECh. 14 - Prob. 109ECh. 14 - Prob. 110ECh. 14 - Prob. 111ECh. 14 - Prob. 112ECh. 14 - 113. In this chapter we have seen a number of...Ch. 14 - Prob. 114ECh. 14 - 115. The previous exercise shows how the...Ch. 14 - Prob. 116ECh. 14 - Prob. 117ECh. 14 - Prob. 118ECh. 14 - Prob. 119ECh. 14 - Prob. 120ECh. 14 - Prob. 121ECh. 14 - Prob. 122ECh. 14 - Prob. 123QGWCh. 14 - 124. A certain compound, A, reacts to form...Ch. 14 - 125. The color of food is an important component...
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