Organic Chemistry, Third Edition Binder Ready Version
3rd Edition
ISBN: 9781119110453
Author: Klein
Publisher: WILEY
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Chapter 14, Problem 73IP
Interpretation Introduction
Interpretation:
The true statement from the given has to be identified.
Concept Introduction:
IR spectral studies: It is a spectroscopic technique which is used to determine the
In the process of oxidation, primary alcohols get converted to
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יווי
10
20
30
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60
70
3.5
3
2.5
2
1.5
1
[ppm]
3.5
3
2.5
2
1.5
1
6 [ppm]
1
1.5
-2.5
3.5
2H2S(g)+3O2(g)→2SO2(g)+2H2O(g)
A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion.
Question
Which of the following predicts the theoretical yield of SO2(g) from the reaction?
Responses
1.2 g
Answer A: 1.2 grams
A
41 g
Answer B: 41 grams
B
77 g
Answer C: 77 grams
C
154 g
Answer D: 154 grams
D
Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Chapter 14 Solutions
Organic Chemistry, Third Edition Binder Ready Version
Ch. 14.3 - Prob. 1CCCh. 14.3 - Prob. 2CCCh. 14.3 - Prob. 3CCCh. 14.3 - Prob. 4CCCh. 14.4 - Prob. 5CCCh. 14.4 - Prob. 6CCCh. 14.4 - Prob. 7CCCh. 14.5 - Prob. 8CCCh. 14.5 - Prob. 9CCCh. 14.5 - Prob. 10CC
Ch. 14.5 - Prob. 11CCCh. 14.6 - Prob. 1LTSCh. 14.6 - Prob. 12PTSCh. 14.6 - Prob. 13ATSCh. 14.7 - Prob. 2LTSCh. 14.7 - Prob. 14PTSCh. 14.7 - Prob. 15ATSCh. 14.7 - Prob. 16ATSCh. 14.7 - Prob. 17ATSCh. 14.9 - Prob. 18CCCh. 14.9 - Prob. 19CCCh. 14.10 - Prob. 3LTSCh. 14.10 - Prob. 20PTSCh. 14.10 - Prob. 21ATSCh. 14.11 - Prob. 22CCCh. 14.11 - Prob. 23CCCh. 14.12 - Prob. 24CCCh. 14.12 - Prob. 25CCCh. 14.12 - Prob. 26CCCh. 14.12 - Prob. 27CCCh. 14.13 - Prob. 28CCCh. 14.13 - Prob. 29CCCh. 14.16 - Prob. 4LTSCh. 14.16 - Prob. 30PTSCh. 14.16 - Prob. 31PTSCh. 14.16 - Strigol is an important plant hormone that is...Ch. 14 - Prob. 33PPCh. 14 - Prob. 34PPCh. 14 - Prob. 35PPCh. 14 - Prob. 36PPCh. 14 - Prob. 37PPCh. 14 - Prob. 38PPCh. 14 - Prob. 39PPCh. 14 - Prob. 40PPCh. 14 - Prob. 41PPCh. 14 - Prob. 42PPCh. 14 - Prob. 43PPCh. 14 - The mass spectrum of 2-bromopentane shows many...Ch. 14 - Prob. 45PPCh. 14 - Prob. 46PPCh. 14 - Prob. 47PPCh. 14 - Prob. 48PPCh. 14 - Prob. 49PPCh. 14 - Prob. 50PPCh. 14 - Prob. 51PPCh. 14 - Prob. 52PPCh. 14 - Prob. 53PPCh. 14 - Prob. 54PPCh. 14 - Prob. 55PPCh. 14 - Prob. 56PPCh. 14 - Prob. 57IPCh. 14 - Prob. 58IPCh. 14 - Prob. 59IPCh. 14 - Prob. 60IPCh. 14 - Prob. 61IPCh. 14 - Prob. 62IPCh. 14 - Prob. 63IPCh. 14 - Prob. 64IPCh. 14 - Prob. 65IPCh. 14 - Prob. 66IPCh. 14 - Prob. 67IPCh. 14 - Prob. 68IPCh. 14 - Compound A exists in equilibrium with its...Ch. 14 - The following two isomers were each subjected to...Ch. 14 - Myosmine can be isolated from tobacco, along with...Ch. 14 - Prob. 72IPCh. 14 - Prob. 73IPCh. 14 - Prob. 74IPCh. 14 - Prob. 75IPCh. 14 - Prob. 76CPCh. 14 - Prob. 77CPCh. 14 - Prob. 78CPCh. 14 - Prob. 79CP
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- Nonearrow_forward4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO dimethylsulfoxide).arrow_forwardThe emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…arrow_forward
- 7. Draw a curved arrow mechanism for the following reaction. HO cat. HCI OH in dioxane with 4A molecular sievesarrow_forwardTry: Convert the given 3D perspective structure to Newman projection about C2 - C3 bond (C2 carbon in the front). Also, show Newman projection of other possible staggered conformers and circle the most stable conformation. Use the template shown. F H3C Br Harrow_forwardNonearrow_forward
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