Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 14, Problem 45P

For each of the following pairs of compounds, identify one IR absorption band that could be used to distinguish between them:

Chapter 14, Problem 45P, For each of the following pairs of compounds, identify one IR absorption band that could be used to , example  1

Chapter 14, Problem 45P, For each of the following pairs of compounds, identify one IR absorption band that could be used to , example  2

  1. a. CH3CH2CH2OH and CH3CH3OCH3

Chapter 14, Problem 45P, For each of the following pairs of compounds, identify one IR absorption band that could be used to , example  3

Chapter 14, Problem 45P, For each of the following pairs of compounds, identify one IR absorption band that could be used to , example  4

  1. b. cis-2-butene and trans-2-butene

Chapter 14, Problem 45P, For each of the following pairs of compounds, identify one IR absorption band that could be used to , example  5

Chapter 14, Problem 45P, For each of the following pairs of compounds, identify one IR absorption band that could be used to , example  6

  1. c. i CH3CH2CH=CHCH3 and CH3CH2C=CCH3

Chapter 14, Problem 45P, For each of the following pairs of compounds, identify one IR absorption band that could be used to , example  7

Chapter 14, Problem 45P, For each of the following pairs of compounds, identify one IR absorption band that could be used to , example  8

Chapter 14, Problem 45P, For each of the following pairs of compounds, identify one IR absorption band that could be used to , example  9

NOTE TO THE STUDENT

• There are additional spectroscopy problems in the Study Guide and Solution Manual.

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1. 6. Draw the products for the following reaction: 2. Diels-Aider reaction NOH O OH
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Chapter 14 Solutions

Organic Chemistry

Ch. 14.6 - Sketch the mass spectrum expected for...Ch. 14.6 - The mass spectra of 1-methoxybutane,...Ch. 14.6 - Prob. 14PCh. 14.6 - Identify the ketones responsible for the mass...Ch. 14.6 - Prob. 16PCh. 14.6 - Using curved arrows, show the principal fragments...Ch. 14.6 - The reaction of (Z)-2-pentene with water and a...Ch. 14.9 - Prob. 19PCh. 14.9 - Prob. 20PCh. 14.9 - Prob. 21PCh. 14.13 - Prob. 22PCh. 14.14 - Which occur at a larger wavenumber: a. the C O...Ch. 14.14 - Prob. 24PCh. 14.14 - Prob. 25PCh. 14.14 - Rank the following compounds from highest...Ch. 14.14 - Which shows an O H stretch at a larger...Ch. 14.15 - Prob. 28PCh. 14.15 - a. An oxygen-containing compound shows an...Ch. 14.15 - Prob. 30PCh. 14.15 - For each of the following pair of compounds, name...Ch. 14.16 - Which of the following compounds has a vibration...Ch. 14.16 - Prob. 33PCh. 14.17 - A compound with molecular formula C4H6O gives the...Ch. 14.19 - Prob. 35PCh. 14.19 - Prob. 36PCh. 14.20 - Predict the max of the following compound:Ch. 14.20 - Prob. 38PCh. 14.21 - a. At pH = 7 one of the ions shown here is purple...Ch. 14.21 - Prob. 40PCh. 14.22 - Prob. 41PCh. 14.22 - Prob. 42PCh. 14 - In the mass spectrum of the following compounds,...Ch. 14 - Prob. 44PCh. 14 - For each of the following pairs of compounds,...Ch. 14 - Draw structures for a saturated hydrocarbon that...Ch. 14 - a. How could you use IR spectroscopy to determine...Ch. 14 - Assuming that the force constant is approximately...Ch. 14 - In the following boxes, list the types of bonds...Ch. 14 - A mass spectrum shows significant peaks at m/z. =...Ch. 14 - Prob. 51PCh. 14 - Prob. 52PCh. 14 - Prob. 53PCh. 14 - How can you use UV spectroscopy to distinguish...Ch. 14 - Rank the following compounds from highest...Ch. 14 - Rank the following compounds from highest...Ch. 14 - What peaks in their mass spectra can be used to...Ch. 14 - Each of the IR spectra shown below is accompanied...Ch. 14 - Prob. 59PCh. 14 - Prob. 60PCh. 14 - How can IR spectroscopy distinguish between...Ch. 14 - 62. Draw the structure of a carboxylic acid that...Ch. 14 - Prob. 63PCh. 14 - Give approximate wavenumbers for the major...Ch. 14 - Prob. 65PCh. 14 - Prob. 66PCh. 14 - Prob. 67PCh. 14 - The IR spectrum of a compound with molecular...Ch. 14 - Which one of the following live compounds produced...Ch. 14 - Prob. 70PCh. 14 - Phenolphthalein is an acid-base indicator. In...Ch. 14 - Which one of the following five compounds produced...Ch. 14 - The IR and mass spectra for three different...
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IR Spectroscopy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=_TmevMf-Zgs;License: Standard YouTube License, CC-BY