ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG.
ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG.
12th Edition
ISBN: 9781119766919
Author: Solomons
Publisher: WILEY
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Chapter 14, Problem 43P

Draw all of the π molecular orbitals for (3E)-1,3,5-hexatriene, order them from lowest to highest in energy, and indicate the number of electrons that would be found in each in the ground state for the molecule. After doing so, open the computer molecular model for (3E)-1,3,5-hexatriene and display the calculated molecular orbitals. How well does the appearance and sequence of the orbitals you drew (e.g., number of nodes, overall symmetry of each, etc.) compare with the orbitals in the calculated model? Are the same orbitals populated with electrons in your analysis as in the calculated model?

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?

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ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG.

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