Student Solutions Manual for Zumdahl/DeCoste's Introductory Chemistry: A Foundation, 9th
9th Edition
ISBN: 9781337399470
Author: ZUMDAHL, Steven S.; DeCoste, Donald J.
Publisher: Cengage Learning
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Chapter 14, Problem 22QAP
Interpretation Introduction
Interpretation:
The unusual high boiling point of water as compared to
Concept Introduction:
Hydrogen bonds are bridge bonds which are longer than normal covalent bonds formed by highly electronegative and smaller atoms like fluorine, oxygen and nitrogen.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 14 Solutions
Student Solutions Manual for Zumdahl/DeCoste's Introductory Chemistry: A Foundation, 9th
Ch. 14.2 - trong>Exercise 14.1 Calculate the total energy...Ch. 14.3 - Prob. 1CTCh. 14.6 - trong>Exercise 14.2 Name the type of crystalline...Ch. 14 - ou seal a container half-filled with water. Which...Ch. 14 - xplain the following: You add 100mLof water to a...Ch. 14 - Prob. 3ALQCh. 14 - Prob. 4ALQCh. 14 - Prob. 5ALQCh. 14 - Prob. 6ALQCh. 14 - Prob. 7ALQ
Ch. 14 - ow do the following physical properties depend on...Ch. 14 - ook at Fig. 14.2. Why doesn't temperature increase...Ch. 14 - Prob. 10ALQCh. 14 - Prob. 11ALQCh. 14 - Prob. 12ALQCh. 14 - Prob. 13ALQCh. 14 - Prob. 14ALQCh. 14 - Prob. 15ALQCh. 14 - True or false? Methane (CH4) is more likely In...Ch. 14 - Prob. 17ALQCh. 14 - Prob. 18ALQCh. 14 - Prob. 19ALQCh. 14 - Which would you predict should be larger for a...Ch. 14 - Prob. 21ALQCh. 14 - Prob. 22ALQCh. 14 - Prob. 23ALQCh. 14 - ases have (higher/lower) densities than liquids or...Ch. 14 - Prob. 2QAPCh. 14 - Prob. 3QAPCh. 14 - he enthalpy (H)of vaporization of water is about...Ch. 14 - Prob. 5QAPCh. 14 - Prob. 6QAPCh. 14 - Prob. 7QAPCh. 14 - Prob. 8QAPCh. 14 - Prob. 9QAPCh. 14 - Prob. 10QAPCh. 14 - Prob. 11QAPCh. 14 - The energy required to melt 1 mole of a solid is...Ch. 14 - The following data have ban collected for...Ch. 14 - The molar heat of fusion of aluminum metal is...Ch. 14 - Prob. 15QAPCh. 14 - Prob. 16QAPCh. 14 - The molar heats of fusion and vaporization for...Ch. 14 - It requires 113Jto melt 1.00gof sodium metal at...Ch. 14 - Consider the iodine monochloride molecule, ICI....Ch. 14 - Prob. 20QAPCh. 14 - Prob. 21QAPCh. 14 - Prob. 22QAPCh. 14 - Prob. 23QAPCh. 14 - Prob. 24QAPCh. 14 - What type of intermolecular forces is active in...Ch. 14 - Prob. 26QAPCh. 14 - Prob. 27QAPCh. 14 - The heats of fusion of three substances are listed...Ch. 14 - When dry ammonia gas (NH3)is bubbled into a...Ch. 14 - Prob. 30QAPCh. 14 - Prob. 31QAPCh. 14 - If you've ever opened a bottle of rubbing alcohol...Ch. 14 - Prob. 33QAPCh. 14 - Prob. 34QAPCh. 14 - Which substance in each pair would be expected to...Ch. 14 - Which substance in each pair would be expected to...Ch. 14 - Prob. 37QAPCh. 14 - Two molecules that contain the same number of each...Ch. 14 - Prob. 39QAPCh. 14 - Prob. 40QAPCh. 14 - How do ionic solids differ in structure from...Ch. 14 - A common prank on college campuses is to switch...Ch. 14 - Prob. 43QAPCh. 14 - What types of forces exist between the individual...Ch. 14 - Prob. 45QAPCh. 14 - Prob. 46QAPCh. 14 - Prob. 47QAPCh. 14 - Prob. 48QAPCh. 14 - Prob. 49QAPCh. 14 - Prob. 50QAPCh. 14 - Prob. 51APCh. 14 - Prob. 52APCh. 14 - Prob. 53APCh. 14 - Prob. 54APCh. 14 - Prob. 55APCh. 14 - Prob. 56APCh. 14 - Prob. 57APCh. 14 - Prob. 58APCh. 14 - Prob. 59APCh. 14 - Prob. 60APCh. 14 - Given the densities and conditions of ice, liquid...Ch. 14 - Prob. 62APCh. 14 - Which of the substances in each of the following...Ch. 14 - Prob. 64APCh. 14 - Prob. 65APCh. 14 - Prob. 66APCh. 14 - Prob. 67APCh. 14 - Prob. 68APCh. 14 - Describe, on both a microscopic and a macroscopic...Ch. 14 - Cake mixes and other packaged foods that require...Ch. 14 - Prob. 71APCh. 14 - Prob. 72APCh. 14 - The molar heat of vaporization of carbon...Ch. 14 - Prob. 74APCh. 14 - Prob. 75APCh. 14 - Prob. 76APCh. 14 - Prob. 77APCh. 14 - Prob. 78APCh. 14 - Prob. 79APCh. 14 - Prob. 80APCh. 14 - Prob. 81APCh. 14 - Prob. 82APCh. 14 - Prob. 83APCh. 14 - Prob. 84APCh. 14 - Describe in detail the microscopic processes that...Ch. 14 - Prob. 86APCh. 14 - Formaldehyde has the formula CH2O, where C is the...Ch. 14 - Prob. 88APCh. 14 - Prob. 89APCh. 14 - Describe, on a microscopic basis, the processes of...Ch. 14 - Prob. 91APCh. 14 - Prob. 92APCh. 14 - Which of the following compound(s) exhibit only...Ch. 14 - Which of the following statements about...Ch. 14 - Prob. 95CPCh. 14 - Prob. 96CPCh. 14 - Prob. 97CPCh. 14 - Which of the following statements is(are) true?...
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