Chemistry: The Science in Context (Fourth Edition)
Chemistry: The Science in Context (Fourth Edition)
4th Edition
ISBN: 9780393124187
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster, Geoffrey Davies
Publisher: W. W. Norton & Company
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Chapter 14, Problem 14.95QP
Interpretation Introduction

Interpretation: The reaction condition under which a bimolecular reaction obeys pseudo-first-order reaction kinetics is to be stated.

Concept introduction: The reaction kinetics in which the rate of reaction depends upon the concentration of two reactants is called second order reaction. The change in the concentration of one of the reactant in bimolecular reaction affects the rate of the reaction.

To determine: The reaction condition under which a bimolecular reaction obeys pseudo-first-order reaction kinetics.

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Show that a molecule with configuration π4 has a cylindrically symmetric electron distribution. Hint: Let the π orbitals be equal to xf and yf, where f is a function that depends only on the distance from the internuclear axis.
(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.
Can I please get help with #3 & 4? Thanks you so much!

Chapter 14 Solutions

Chemistry: The Science in Context (Fourth Edition)

Ch. 14.4 - Prob. 11PECh. 14.5 - Prob. 12PECh. 14.5 - Prob. 13PECh. 14.6 - Prob. 14PECh. 14 - Prob. 14.1VPCh. 14 - Prob. 14.2VPCh. 14 - Prob. 14.3VPCh. 14 - Prob. 14.4VPCh. 14 - Prob. 14.5VPCh. 14 - Prob. 14.6VPCh. 14 - Prob. 14.7VPCh. 14 - Prob. 14.8VPCh. 14 - Prob. 14.9VPCh. 14 - Prob. 14.10VPCh. 14 - Prob. 14.11VPCh. 14 - Prob. 14.12VPCh. 14 - Prob. 14.13VPCh. 14 - Prob. 14.14VPCh. 14 - Prob. 14.15VPCh. 14 - Prob. 14.16VPCh. 14 - Prob. 14.17QPCh. 14 - Prob. 14.18QPCh. 14 - Prob. 14.19QPCh. 14 - Prob. 14.20QPCh. 14 - Prob. 14.21QPCh. 14 - Prob. 14.22QPCh. 14 - Prob. 14.23QPCh. 14 - Prob. 14.24QPCh. 14 - Prob. 14.25QPCh. 14 - Prob. 14.26QPCh. 14 - Prob. 14.27QPCh. 14 - Prob. 14.28QPCh. 14 - Prob. 14.29QPCh. 14 - Prob. 14.30QPCh. 14 - Prob. 14.31QPCh. 14 - Prob. 14.32QPCh. 14 - Prob. 14.33QPCh. 14 - Prob. 14.34QPCh. 14 - Prob. 14.35QPCh. 14 - Prob. 14.36QPCh. 14 - Prob. 14.37QPCh. 14 - Prob. 14.38QPCh. 14 - Prob. 14.39QPCh. 14 - Prob. 14.40QPCh. 14 - Prob. 14.41QPCh. 14 - Prob. 14.42QPCh. 14 - Prob. 14.43QPCh. 14 - Prob. 14.44QPCh. 14 - Prob. 14.45QPCh. 14 - Prob. 14.46QPCh. 14 - Prob. 14.47QPCh. 14 - Prob. 14.48QPCh. 14 - Prob. 14.49QPCh. 14 - Prob. 14.50QPCh. 14 - Prob. 14.51QPCh. 14 - Prob. 14.52QPCh. 14 - Prob. 14.53QPCh. 14 - Prob. 14.54QPCh. 14 - Prob. 14.55QPCh. 14 - Prob. 14.56QPCh. 14 - Prob. 14.57QPCh. 14 - Prob. 14.58QPCh. 14 - Prob. 14.59QPCh. 14 - Prob. 14.60QPCh. 14 - Prob. 14.61QPCh. 14 - Prob. 14.62QPCh. 14 - Prob. 14.63QPCh. 14 - Prob. 14.64QPCh. 14 - Prob. 14.65QPCh. 14 - Prob. 14.66QPCh. 14 - Prob. 14.67QPCh. 14 - Prob. 14.68QPCh. 14 - Prob. 14.69QPCh. 14 - Prob. 14.70QPCh. 14 - Prob. 14.71QPCh. 14 - Prob. 14.72QPCh. 14 - Prob. 14.73QPCh. 14 - Prob. 14.74QPCh. 14 - Prob. 14.75QPCh. 14 - Prob. 14.76QPCh. 14 - Prob. 14.77QPCh. 14 - Prob. 14.78QPCh. 14 - Prob. 14.79QPCh. 14 - Prob. 14.80QPCh. 14 - Prob. 14.81QPCh. 14 - Prob. 14.82QPCh. 14 - Prob. 14.83QPCh. 14 - Prob. 14.84QPCh. 14 - Prob. 14.85QPCh. 14 - Prob. 14.86QPCh. 14 - Prob. 14.87QPCh. 14 - Prob. 14.88QPCh. 14 - Prob. 14.89QPCh. 14 - Prob. 14.90QPCh. 14 - Prob. 14.91QPCh. 14 - Prob. 14.93QPCh. 14 - Prob. 14.94QPCh. 14 - Prob. 14.95QPCh. 14 - Prob. 14.96QPCh. 14 - Prob. 14.97QPCh. 14 - Prob. 14.98QPCh. 14 - Prob. 14.99QPCh. 14 - Prob. 14.100QPCh. 14 - Prob. 14.101QPCh. 14 - Prob. 14.102QPCh. 14 - Prob. 14.103QPCh. 14 - Prob. 14.104QPCh. 14 - Prob. 14.105QPCh. 14 - Prob. 14.106QPCh. 14 - Prob. 14.107QPCh. 14 - Prob. 14.108QPCh. 14 - Prob. 14.109QPCh. 14 - Prob. 14.110QPCh. 14 - Prob. 14.111QPCh. 14 - Prob. 14.112QPCh. 14 - Prob. 14.113QPCh. 14 - Prob. 14.114QPCh. 14 - Prob. 14.115QPCh. 14 - Prob. 14.116QPCh. 14 - Prob. 14.117QPCh. 14 - Prob. 14.118QPCh. 14 - Prob. 14.119APCh. 14 - Prob. 14.120APCh. 14 - Prob. 14.121APCh. 14 - Prob. 14.122APCh. 14 - Prob. 14.123APCh. 14 - Prob. 14.124APCh. 14 - Prob. 14.125APCh. 14 - Prob. 14.126APCh. 14 - Prob. 14.127APCh. 14 - Prob. 14.128APCh. 14 - Prob. 14.129APCh. 14 - Prob. 14.130APCh. 14 - Prob. 14.131APCh. 14 - Prob. 14.132APCh. 14 - Prob. 14.133APCh. 14 - Prob. 14.134APCh. 14 - Prob. 14.135APCh. 14 - Prob. 14.136APCh. 14 - Prob. 14.137APCh. 14 - Prob. 14.138APCh. 14 - Prob. 14.139APCh. 14 - Prob. 14.140APCh. 14 - Prob. 14.141AP
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Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY