The qualitative information obtained from the equilibrium constant has to be explained. Concept introduction: Equilibrium constant ( K c ) : A system is said to be in equilibrium when all the measurable properties of the system remains unchanged with the time. Equilibrium constant is the ratio of the concentrations of the products to concentrations of the reactants at a given temperature. Each concentration term is raised to a power, which is same as the coefficients in the chemical reaction . Consider the reaction where the reactant A is giving product B. A ⇌ B The equilibrium constant, K c = [ A ] [ B ]
The qualitative information obtained from the equilibrium constant has to be explained. Concept introduction: Equilibrium constant ( K c ) : A system is said to be in equilibrium when all the measurable properties of the system remains unchanged with the time. Equilibrium constant is the ratio of the concentrations of the products to concentrations of the reactants at a given temperature. Each concentration term is raised to a power, which is same as the coefficients in the chemical reaction . Consider the reaction where the reactant A is giving product B. A ⇌ B The equilibrium constant, K c = [ A ] [ B ]
Solution Summary: The author explains the qualitative information obtained from the equilibrium constant. Equilibrium constant gives relative amounts of reactants and products in a reaction mixture.
Definition Definition Transformation of a chemical species into another chemical species. A chemical reaction consists of breaking existing bonds and forming new ones by changing the position of electrons. These reactions are best explained using a chemical equation.
Chapter 14, Problem 14.7QP
Interpretation Introduction
Interpretation:
The qualitative information obtained from the equilibrium constant has to be explained.
Concept introduction:
Equilibrium constant(Kc): A system is said to be in equilibrium when all the measurable properties of the system remains unchanged with the time. Equilibrium constant is the ratio of the concentrations of the products to concentrations of the reactants at a given temperature. Each concentration term is raised to a power, which is same as the coefficients in the chemical reaction.
Consider the reaction where the reactant A is giving product B.
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Chapter 14 Solutions
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