EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
9th Edition
ISBN: 9780136781776
Author: Wade
Publisher: PEARSON CO
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Chapter 14, Problem 14.41SP

(a)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(b)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

(c)

Interpretation Introduction

To determine: The method of synthesis of given ether.

Interpretation: The method of synthesis of given ether is to be predicted.

Concept introduction: Lithium aluminum hydride (LiAlH4) is a strong reducing agent which reduces ketones to secondary alcohols and aldehydes to primary alcohols. Both LiAlH4 and Grignard reagents react with carbonyl compounds to give alkoxide ion intermediate. These alkoxide intermediates react with primary or methyl alkyl halides or tosylates to give ethers.

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Chapter 14 Solutions

EP ORGANIC CHEMISTRY -MOD.MASTERING 18W

Ch. 14.7 - Explain why bimolecular condensation is a poor...Ch. 14.7 - Prob. 14.12PCh. 14.7 - Prob. 14.13PCh. 14.8 - Prob. 14.14PCh. 14.8 - Prob. 14.15PCh. 14.8 - Prob. 14.16PCh. 14.10A - Prob. 14.17PCh. 14.10A - Prob. 14.18PCh. 14.10B - Prob. 14.19PCh. 14.11B - Show how you would accomplish the following...Ch. 14.11B - Prob. 14.21PCh. 14.12 - Prob. 14.22PCh. 14.12 - Prob. 14.23PCh. 14.12 - Prob. 14.24PCh. 14.13 - Prob. 14.25PCh. 14.13 - Prob. 14.26PCh. 14.14 - Prob. 14.27PCh. 14.15 - Give the expected products of the following...Ch. 14 - Write structural formulas for the following...Ch. 14 - Give common names for the following compounds. a....Ch. 14 - Give IUPAC names for the following compounds. a....Ch. 14 - Glycerol (propane-1,2,3-triol) is a viscous syrup...Ch. 14 - Prob. 14.33SPCh. 14 - Show how you would make the following ethers,...Ch. 14 - (A true story.) An inexperienced graduate student...Ch. 14 - Prob. 14.36SPCh. 14 - a. Show how you would synthesize the pure (R)...Ch. 14 - a. Predict the values of m/z and the structures of...Ch. 14 - The following reaction resembles the...Ch. 14 - Prob. 14.40SPCh. 14 - Prob. 14.41SPCh. 14 - Prob. 14.42SPCh. 14 - Give the structures of the intermediates...Ch. 14 - Prob. 14.44SPCh. 14 - Show how you would synthesize the following ethers...Ch. 14 - Prob. 14.46SPCh. 14 - Prob. 14.47SPCh. 14 - Prob. 14.48SPCh. 14 - An acid-catalyzed reaction was carried out using...Ch. 14 - Propylene oxide is a chiral molecule. Hydrolysis...Ch. 14 - Prob. 14.51SPCh. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - Prob. 14.54SPCh. 14 - In 2012, a group led by Professor Masayuki Satake...
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