The balanced chemical equation has to be derived from the expression for the equilibrium constant. And the expression for the equilibrium constant has to be found in the given conditions. Concept introduction: A system is said to be in equilibrium when all the measurable properties of the system remains unchanged with the time. Equilibrium constant is the ratio of the rate constants of the forward and reverse reactions at a given temperature. In other words it is the ratio of the concentrations of the products to concentrations of the reactants. Each concentration term is raised to a power, which is same as the coefficients in the chemical reaction . Consider the reaction where the reactant A is giving product P . A ⇌ P Rate of forward reaction = Rate of reverse reaction k f [ A ] =k r [ B ] On rearranging, [ A ] [ B ] = k f k r = K c Where, k f is the rate constant of the forward reaction. k r is the rate constant of the reverse reaction. K c is the equilibrium constant.
The balanced chemical equation has to be derived from the expression for the equilibrium constant. And the expression for the equilibrium constant has to be found in the given conditions. Concept introduction: A system is said to be in equilibrium when all the measurable properties of the system remains unchanged with the time. Equilibrium constant is the ratio of the rate constants of the forward and reverse reactions at a given temperature. In other words it is the ratio of the concentrations of the products to concentrations of the reactants. Each concentration term is raised to a power, which is same as the coefficients in the chemical reaction . Consider the reaction where the reactant A is giving product P . A ⇌ P Rate of forward reaction = Rate of reverse reaction k f [ A ] =k r [ B ] On rearranging, [ A ] [ B ] = k f k r = K c Where, k f is the rate constant of the forward reaction. k r is the rate constant of the reverse reaction. K c is the equilibrium constant.
Solution Summary: The author explains that the balanced chemical equation has to be derived from the expression for the equilibrium constant.
Definition Definition State where the components involved in a reversible reaction, namely reactants and product, do not change concentration any further with time. Chemical equilibrium results when the rate of the forward reaction becomes equal to the rate of the reverse reaction.
Chapter 14, Problem 14.40QP
Interpretation Introduction
Interpretation:
The balanced chemical equation has to be derived from the expression for the equilibrium constant. And the expression for the equilibrium constant has to be found in the given conditions.
Concept introduction:
A system is said to be in equilibrium when all the measurable properties of the system remains unchanged with the time. Equilibrium constant is the ratio of the rate constants of the forward and reverse reactions at a given temperature. In other words it is the ratio of the concentrations of the products to concentrations of the reactants. Each concentration term is raised to a power, which is same as the coefficients in the chemical reaction.
Consider the reaction where the reactant A is giving product P.
A⇌P
Rate of forward reaction = Rate of reverse reactionkf[A]=kr[B]
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In alpha-NbI4, Nb4+ should have the d1 configuration (bond with paired electrons: paramagnetic). Please comment.
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