CHEMISTRY: ATOMS FIRST VOL 1 W/CONNECT
14th Edition
ISBN: 9781259327933
Author: Burdge
Publisher: MCG
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Chapter 14, Problem 14.39QP
What is the role of ATP in biological reactions?
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Chapter 14 Solutions
CHEMISTRY: ATOMS FIRST VOL 1 W/CONNECT
Ch. 14.3 - Determine the change in entropy for 1.0 mole of an...Ch. 14.3 - Determine the change in entropy (Ssys) for the...Ch. 14.3 - To what fraction of its original volume must a...Ch. 14.3 - From the standard entropy values in Appendix 2,...Ch. 14.3 - Prob. 2PPACh. 14.3 - In each of the following reactions, there is one...Ch. 14.3 - For each reaction shown in the diagrams, indicate...Ch. 14.3 - For each process, determine the sign of S for the...Ch. 14.3 - Prob. 3PPACh. 14.3 - Make a qualitative prediction of the sign of Hsoln...
Ch. 14.3 - Consider the gas-phase reaction of A2 (blue) and...Ch. 14.3 - Prob. 14.3.1SRCh. 14.3 - Prob. 14.3.2SRCh. 14.3 - Prob. 14.3.3SRCh. 14.4 - Determine if each of the following is a...Ch. 14.4 - For each of the following, calculate Suniv and...Ch. 14.4 - (a) Calculate Suniv and determine if the reaction...Ch. 14.4 - The following table shows the signs of Ssys,...Ch. 14.4 - Prob. 14.4.1SRCh. 14.4 - Prob. 14.4.2SRCh. 14.4 - Prob. 14.4.3SRCh. 14.5 - According to Table 14 4, a reaction will be...Ch. 14.5 - A reaction will be spontaneous only at low...Ch. 14.5 - Given that the reaction 4Fe(s) + 3O2(g) + 6H2O(l) ...Ch. 14.5 - Prob. 5PPCCh. 14.5 - Prob. 14.6WECh. 14.5 - Prob. 6PPACh. 14.5 - For each reaction, determine the value of Gf that...Ch. 14.5 - Prob. 6PPCCh. 14.5 - Prob. 14.7WECh. 14.5 - Prob. 7PPACh. 14.5 - Prob. 7PPBCh. 14.5 - Prob. 7PPCCh. 14.5 - Prob. 14.5.1SRCh. 14.5 - Prob. 14.5.2SRCh. 14.5 - Prob. 14.5.3SRCh. 14 - Explain what is meant by a spontaneous process....Ch. 14 - Which of the following processes are spontaneous...Ch. 14 - Prob. 14.3QPCh. 14 - Prob. 14.4QPCh. 14 - Prob. 14.5QPCh. 14 - Prob. 14.6QPCh. 14 - Prob. 14.7QPCh. 14 - Consider two gas samples at STP: one consisting of...Ch. 14 - Now consider the reaction F2(g)2F(g)at constant...Ch. 14 - Which of the following best describes why entropy...Ch. 14 - Which of the following best explains why entropy...Ch. 14 - How does the entropy of a system change for each...Ch. 14 - How does the entropy of a system change for each...Ch. 14 - Predict whether the entropy change is positive or...Ch. 14 - Prob. 14.11QPCh. 14 - Prob. 14.12QPCh. 14 - Prob. 14.13QPCh. 14 - Using the data in Appendix 2, calculate the...Ch. 14 - Using the data in Appendix 2, calculate the...Ch. 14 - For each pair of substances listed here, choose...Ch. 14 - Arrange the following substances (1 mole each) in...Ch. 14 - State the second law of thermodynamics in words,...Ch. 14 - State the third law of thermodynamics in words,...Ch. 14 - Calculate Ssurr for each of the reactions in...Ch. 14 - Calculate Ssurr for each of the reactions in...Ch. 14 - Using data from Appendix 2, calculate Srxn and...Ch. 14 - Using data from Appendix 2, calculate Srxn and...Ch. 14 - When a folded protein in solution is heated to a...Ch. 14 - Define free energy. What are its units?Ch. 14 - Why is it more convenient to predict the direction...Ch. 14 - What is the significance of the sign of Gsys?Ch. 14 - From the following combinations of H and S,...Ch. 14 - Prob. 14.29QPCh. 14 - Calculate G for the following reactions at 25C....Ch. 14 - Calculate G for the following reactions at 25C....Ch. 14 - From the values of H and S, predict which of the...Ch. 14 - Find the temperatures at which reactions with the...Ch. 14 - The molar heats of fusion and vaporization of...Ch. 14 - The molar heats of fusion and vaporization of...Ch. 14 - Use the values listed in Appendix 2 to calculate G...Ch. 14 - Certain bacteria in the soil obtain the necessary...Ch. 14 - What is a coupled reaction? What is its importance...Ch. 14 - What is the role of ATP in biological reactions?Ch. 14 - Prob. 14.40QPCh. 14 - Predict the signs of H, S, and G of the system for...Ch. 14 - A student placed 1 g of each of three compounds A,...Ch. 14 - The enthalpy change in the denaturation of a...Ch. 14 - Consider the following facts: Water freezes...Ch. 14 - Ammonium nitrate (NH4NO3) dissolves spontaneously...Ch. 14 - The standard enthalpy of formation and the...Ch. 14 - (a) Troutons rule states that the ratio of the...Ch. 14 - Referring to Problem 14.47, explain why the ratio...Ch. 14 - Prob. 14.49QPCh. 14 - Prob. 14.50QPCh. 14 - Prob. 14.51QPCh. 14 - Prob. 14.52QPCh. 14 - Prob. 14.53QPCh. 14 - The molar heat of vaporization of ethanol is 39 3...Ch. 14 - As an approximation, we can assume that proteins...Ch. 14 - When a native protein in solution is heated to a...Ch. 14 - A 74.6-g ice cube floats in the Arctic Sea. The...Ch. 14 - A reaction for which H and S are both negative is...Ch. 14 - The sublimation of carbon dioxide at 78C is given...Ch. 14 - Many hydrocarbons exist as structural isomers,...Ch. 14 - Consider the following reaction at 298 K. 2H2(s) +...Ch. 14 - Which of the following is not accompanied by an...Ch. 14 - Which of the following are not state functions: S,...Ch. 14 - Give a detailed example of each of the following,...Ch. 14 - Hydrogenation reactions (e.g., the process of...Ch. 14 - At 0 K. the entropy of carbon monoxide crystal is...Ch. 14 - Which of the following thermodynamic functions are...Ch. 14 - Using Gf values from Appendix 2, calculate the...Ch. 14 - Prob. 14.2KSPCh. 14 - Using Grxnvalues from Appendix 2, calculate the...Ch. 14 - Prob. 14.4KSP
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- Please draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forwardA 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardFirefly luciferin exhibits three rings. Identify which of the rings are aromatic. Identify which lone pairs are involved in establishing aromaticity. The lone pairs are labeled A-D below.arrow_forward
- A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardGiven a complex reaction with rate equation v = k1[A] + k2[A]2, what is the overall reaction order?arrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forward
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- TRANSMITTANCE เบบ Please identify the one structure below that is consistent with the 'H NMR and IR spectra shown and draw its complete structure in the box below with the protons alphabetically labeled as shown in the NMR spectrum and label the IR bands, including sp³C-H and sp2C-H stretch, indicated by the arrows. D 4000 OH LOH H₂C CH3 OH H₂C OCH3 CH3 OH 3000 2000 1500 HAVENUMBERI-11 1000 LOCH3 Draw your structure below and label its equivalent protons according to the peak labeling that is used in the NMR spectrum in order to assign the peaks. Integrals indicate number of equivalent protons. Splitting patterns are: s=singlet, d=doublet, m-multiplet 8 3Hb s m 1Hd s 3Hf m 2Hcd 2Had 1He 鄙视 m 7 7 6 5 4 3 22 500 T 1 0arrow_forwardRelative Transmittance 0.995 0.99 0.985 0.98 Please draw the structure that is consistent with all the spectral data below in the box and alphabetically label the equivalent protons in the structure (Ha, Hb, Hc ....) in order to assign all the proton NMR peaks. Label the absorption bands in the IR spectrum indicated by the arrows. INFRARED SPECTRUM 1 0.975 3000 2000 Wavenumber (cm-1) 1000 Structure with assigned H peaks 1 3 180 160 140 120 100 f1 (ppm) 80 60 40 20 0 C-13 NMR note that there are 4 peaks between 120-140ppm Integral values equal the number of equivalent protons 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 fl (ppm)arrow_forwardCalculate the pH of 0.0025 M phenol.arrow_forward
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