ORGANIC CHEMISTRY WITH WILEY PLUS; ORGAN
ORGANIC CHEMISTRY WITH WILEY PLUS; ORGAN
4th Edition
ISBN: 9781119493426
Author: Klein
Publisher: WILEY
Question
Book Icon
Chapter 13.8, Problem 13PTS

(a)

Interpretation Introduction

Interpretation: A starting material and reagents used to form following epoxide needs to be identified.

  ORGANIC CHEMISTRY WITH WILEY PLUS; ORGAN, Chapter 13.8, Problem 13PTS , additional homework tip  1

Concept introduction:

Preparation of epoxide- Epoxides can be prepared using peroxy acids. Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, general reaction is represented as follows:

  ORGANIC CHEMISTRY WITH WILEY PLUS; ORGAN, Chapter 13.8, Problem 13PTS , additional homework tip  2

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. Formation of epoxide via peroxy acid us a stereospecific process thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

(b)

Interpretation Introduction

Interpretation: A starting material and reagents used to form following epoxide needs to be identified.

  ORGANIC CHEMISTRY WITH WILEY PLUS; ORGAN, Chapter 13.8, Problem 13PTS , additional homework tip  3

Concept introduction:

Preparation of epoxide- Epoxides can be prepared using peroxy acids. Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, general reaction is represented as follows:

  ORGANIC CHEMISTRY WITH WILEY PLUS; ORGAN, Chapter 13.8, Problem 13PTS , additional homework tip  4

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. Formation of epoxide via peroxy acid us a stereospecific process thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

(c)

Interpretation Introduction

Interpretation: A starting material and reagents used to form following epoxide needs to be identified.

  ORGANIC CHEMISTRY WITH WILEY PLUS; ORGAN, Chapter 13.8, Problem 13PTS , additional homework tip  5

Concept introduction:

Preparation of epoxide- Epoxides can be prepared using peroxy acids. Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, general reaction is represented as follows:

  ORGANIC CHEMISTRY WITH WILEY PLUS; ORGAN, Chapter 13.8, Problem 13PTS , additional homework tip  6

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. Formation of epoxide via peroxy acid us a stereospecific process thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

(d)

Interpretation Introduction

Interpretation: A starting material and reagents used to form following epoxide needs to be identified.

  ORGANIC CHEMISTRY WITH WILEY PLUS; ORGAN, Chapter 13.8, Problem 13PTS , additional homework tip  7

Concept introduction:

Preparation of epoxide- Epoxides can be prepared using peroxy acids. Alkenes are starting material in the preparation of epoxides with peroxy acids. Here, general reaction is represented as follows:

  ORGANIC CHEMISTRY WITH WILEY PLUS; ORGAN, Chapter 13.8, Problem 13PTS , additional homework tip  8

Peroxy acids generally used in this process are MCPBA and peroxyacetic acid. Formation of epoxide via peroxy acid us a stereospecific process thus, cis substituents in alkene (starting material) remain at cis to each other in the epoxide (product). Similarly, trans substituents in alkene remain at trans to each other.

Blurred answer
Students have asked these similar questions
11 Organic Chemistry Organic Nomenclature Practice Name/Functional Group n-butane Formula Structural Formula (1) C4tt10 H3C C- (2) CH3CH2CH2 CH 3 H₂ -CH3 Н2 name & functional group (1) and (2) OH H₁₂C Н2 name only (1) and (2) name only (1) and (2) H₁C - = - CH₂ Н2 HC=C-C CH3
Under aqueous basic conditions, nitriles will react to form a neutral organic intermediate 1 that has an N atom in it first, and then they will continue to react to form the final product 2: NC H₂O он- H₂O 1 2 OH Draw the missing intermediate 1 and the final product 2 in the box below. You can draw the two structures in any arrangement you like. Click and drag to start drawing a structure.
Assign these COSY Spectrum

Chapter 13 Solutions

ORGANIC CHEMISTRY WITH WILEY PLUS; ORGAN

Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
  • Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305080485
    Author:John E. McMurry
    Publisher:Cengage Learning
    Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305580350
    Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
    Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305080485
Author:John E. McMurry
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning