ORGANIC CHEMISTRY-PRINT COMPANION (LL)
ORGANIC CHEMISTRY-PRINT COMPANION (LL)
3rd Edition
ISBN: 9781119444251
Author: Klein
Publisher: WILEY
Question
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Chapter 13.7, Problem 12CC

a)

Interpretation Introduction

Interpretation: The name of compound should be assigned along with chirality centre and configuration.

Concept Introduction:

The compounds that contain an Oxygen atom incorporated in a ring are called as cyclic ethers. Special parent names are given to represent the ring size.

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  1   ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  2   ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  3  ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  4

There are two methods of naming Epoxides.

First method: Oxygen atom is taken as substituent on the parent chain and the precise location of the Epoxide group is identified with two numbers given by the term Epoxy.

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  5

Second method: Oxirane is considered as parent ring and those groups that are connected to Oxirane ring are given as substituents.

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  6

b)

Interpretation Introduction

Interpretation: The name of compound should be assigned along with chirality centre and configuration.

Concept Introduction:

The compounds that contain an Oxygen atom incorporated in a ring are called as cyclic ethers. Special parent names are given to represent the ring size.

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  7   ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  8   ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  9  ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  10

There are two methods of naming Epoxides.

First method: Oxygen atom is taken as substituent on the parent chain and the precise location of the Epoxide group is identified with two numbers given by the term Epoxy.

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  11

Second method: Oxirane is considered as parent ring and those groups that are connected to Oxirane ring are given as substituents.

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  12

c)

Interpretation Introduction

Interpretation: The name of compound should be assigned along with chirality centre and configuration.

Concept Introduction:

The compounds that contain an Oxygen atom incorporated in a ring are called as cyclic ethers. Special parent names are given to represent the ring size.

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  13   ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  14   ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  15  ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  16

There are two methods of naming Epoxides.

First method: Oxygen atom is taken as substituent on the parent chain and the precise location of the Epoxide group is identified with two numbers given by the term Epoxy.

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  17

Second method: Oxirane is considered as parent ring and those groups that are connected to Oxirane ring are given as substituents.

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 13.7, Problem 12CC , additional homework tip  18

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Chapter 13 Solutions

ORGANIC CHEMISTRY-PRINT COMPANION (LL)

Ch. 13.5 - Prob. 9CCCh. 13.6 - Prob. 10CCCh. 13.7 - Prob. 11CCCh. 13.7 - Prob. 12CCCh. 13.8 - Prob. 3LTSCh. 13.8 - Prob. 13PTSCh. 13.8 - Prob. 14ATSCh. 13.9 - Prob. 15CCCh. 13.10 - Prob. 4LTSCh. 13.10 - Prob. 16PTSCh. 13.10 - Prob. 17ATSCh. 13.10 - Prob. 5LTSCh. 13.10 - Prob. 18PTSCh. 13.10 - The sequence below shows an enantioselective...Ch. 13.11 - Prob. 20CCCh. 13.11 - Prob. 21CCCh. 13.12 - Prob. 6LTSCh. 13.12 - Prob. 22PTSCh. 13.12 - Prob. 23ATSCh. 13.12 - Prob. 7LTSCh. 13.12 - Prob. 24PTSCh. 13.12 - Prob. 25ATSCh. 13 - Prob. 26PPCh. 13 - Prob. 27PPCh. 13 - Prob. 28PPCh. 13 - Prob. 29PPCh. 13 - Prob. 30PPCh. 13 - Prob. 31PPCh. 13 - Prob. 32PPCh. 13 - Methylmagnesium bromide reacts rapidly with...Ch. 13 - Prob. 34PPCh. 13 - Prob. 35PPCh. 13 - Prob. 36PPCh. 13 - Prob. 37PPCh. 13 - Prob. 38PPCh. 13 - Prob. 39PPCh. 13 - Prob. 40PPCh. 13 - Prob. 41PPCh. 13 - Prob. 42PPCh. 13 - Prob. 43PPCh. 13 - Prob. 44PPCh. 13 - Prob. 45PPCh. 13 - Prob. 46IPCh. 13 - Prob. 47IPCh. 13 - Prob. 48IPCh. 13 - Prob. 49IPCh. 13 - Prob. 50IPCh. 13 - Prob. 51IPCh. 13 - Prob. 52IPCh. 13 - Prob. 53IPCh. 13 - Prob. 54IPCh. 13 - Prob. 55IPCh. 13 - Prob. 56IPCh. 13 - Prob. 57IPCh. 13 - Prob. 58IPCh. 13 - Prob. 59IPCh. 13 - Prob. 60IPCh. 13 - Prob. 61IPCh. 13 - Prob. 62IPCh. 13 - Prob. 63IPCh. 13 - Prob. 64IPCh. 13 - Prob. 65IPCh. 13 - Prob. 66IPCh. 13 - Prob. 67IPCh. 13 - Prob. 68IPCh. 13 - Prob. 69IPCh. 13 - Prob. 70IPCh. 13 - The following procedure13 is part of a synthetic...Ch. 13 - Prob. 72CPCh. 13 - Prob. 73CPCh. 13 - Prob. 74CPCh. 13 - Prob. 75CP
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