(a) Interpretation: The major product formed when given cycloalkane is heated with Br 2 is to be drawn. Concept introduction: Free radicals are classified as 1 ° , 2 ° or 3 ° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals. Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C − H sigma bond of the alkane.

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Answer 1

Question

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Give the IUPAC name of each compound.

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1. What orbitals (around Carbon) are used to form each bond in the following molecules: A. CH3CH3 B. CH2CH2 2. Draw the structure corresponding to each IUPAC name: 3-ethyl-1,1-dimethylcyclohexane, 6-isopropyl-2,3-dimethylnonane

Answer 2

Question

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 3

Question

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 4

Question

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 5

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 6

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 7

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 8

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 9

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 10

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 11

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 12

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 13

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 13.1 - Prob. 1P Ch. 13.1 - Prob. 2P Ch. 13.2 - Prob. 3P Ch. 13.3 - Prob. 4P Ch. 13.3 - Prob. 5P Ch. 13.4 - Prob. 7P Ch. 13.5 - Problem 15.8 Which bond in the each compound is...Ch. 13.6 - Prob. 9P Ch. 13.6 - Prob. 10P Ch. 13.7 - Prob. 11P

Solution Summary: The author illustrates the major product formed when given cycloalkane is heated with Br_ 2.

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