CHEMISTRY: THE CENTRAL SCIENCE
14th Edition
ISBN: 9780134562230
Author: Brown
Publisher: PEARSON
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Question
Chapter 13.5, Problem 13.8.2PE
Interpretation Introduction
To determine: The freezing temperature of the solution.
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How would you use infrared spectroscopy to distinguish between the following pairs of constitutional isomers?
(a)
CH3C=CCH3
||
and
CH3CH2C=CH
(b)
CH3CCH=CHCH3
and
CH3CCH2CH=CH2
Problem 12-41
The mass spectrum (a) and the infrared spectrum (b) of an unknown hydrocarbon are shown. Propose as many
structures as you can.
(a)
100
Relative abundance (%)
80
60
60
40
200
20
(b)
100
Transmittance (%)
10
20
20
80-
60-
40-
20
40
60
80
100
120
140
m/z
500
4000 3500
3000
2500
2000
1500
Wavenumber (cm-1)
1000
Propagation of uncertainty. You have a stock solution certified by the manufacturer to contain 150.0±0.03 µg SO42-/mL. You would like to dilute it by a factor of 100 to obtain 1.500 µg/mL. Calculate the uncertainty in the two methods of dilution below. Use the following uncertainty values for glassware:
Glassware
Uncertainty
(assume glassware has been calibrated and treat the values below as random error)
1.00 mL volumetric pipet
0.01 mL
10.00 mL volumetric pipet
0.02 mL
100.00 mL volumetric flask
0.08 mL
Transfer 10.00 mL with a volumetric pipet and dilute it to 100 mL with a volumetric flask. Then take 10.00 mL of the resulting solution and dilute it a second time with a 100 mL flask.
2. Transfer 1.00 mL with a volumetric pipet and dilute it to 100 mL with a volumetric flask.
Draw all resonance structures for the following ion:
CH₂
Draw all resonance structures on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars, including
charges where needed. The single bond is active by default.
2D
ד
CONT
HD EXP CON
?
1
[1]
Α
12
Marvin JS
by Chemaxon
A DOO
H
C
N
Br
I UZ OSPF
Chapter 13 Solutions
CHEMISTRY: THE CENTRAL SCIENCE
Ch. 13.3 - Prob. 13.1.1PECh. 13.3 - Prob. 13.1.2PECh. 13.3 - Prob. 13.2.1PECh. 13.3 - Prob. 13.2.2PECh. 13.4 - Prob. 13.3.1PECh. 13.4 - Prob. 13.3.2PECh. 13.4 - Prob. 13.4.1PECh. 13.4 - Prob. 13.4.2PECh. 13.4 - Prob. 13.5.1PECh. 13.4 - Prob. 13.5.2PE
Ch. 13.4 - Prob. 13.6.1PECh. 13.4 - Prob. 13.6.2PECh. 13.5 - Prob. 13.7.1PECh. 13.5 - Prob. 13.7.2PECh. 13.5 - Which aqueous solution will have the lowest...Ch. 13.5 - Prob. 13.8.2PECh. 13.5 - Prob. 13.9.1PECh. 13.5 - Prob. 13.9.2PECh. 13.5 - Prob. 13.10.1PECh. 13.5 - Practice Exercise 2
Camphor (C10 H16 O) melts at...Ch. 13.5 - Prob. 13.11.1PECh. 13.5 - Prob. 13.11.2PECh. 13 - Prob. 1DECh. 13 - Rank the contents of the following containers in...Ch. 13 - This figure shows the interaction of a cation with...Ch. 13 - Consider two ionic solids, both composed of singly...Ch. 13 - Which two statements about gas mixtures are true?...Ch. 13 - Prob. 5ECh. 13 - 13.6 If you compare the solubilities of the noble...Ch. 13 - Prob. 7ECh. 13 - Prob. 8ECh. 13 - Prob. 9ECh. 13 - Prob. 10ECh. 13 - Suppose you had a balloon made of some highly...Ch. 13 - Prob. 12ECh. 13 - Indicate whether each statement is true or false:...Ch. 13 - Indicate whether each statement is true or false:...Ch. 13 - Indicate the type of solute-solvent interaction...Ch. 13 - Indicate the principal type of solute-solvent...Ch. 13 - An ionic compound has a very negative H soln in...Ch. 13 - When ammonium chloride dissolves in water, the...Ch. 13 - Prob. 19ECh. 13 - Prob. 20ECh. 13 - Prob. 21ECh. 13 - KBr is relatively soluble in water, yet its...Ch. 13 - The solubility of Cr (NO3)3 . 9 H2O in water is...Ch. 13 - The solubility of MnSO4 . H2 O in water at 20 C is...Ch. 13 - Prob. 25ECh. 13 - Prob. 26ECh. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Prob. 29ECh. 13 - Prob. 30ECh. 13 - Would you expect stearic acid, CH3 (CH2)16COOH, to...Ch. 13 - Prob. 32ECh. 13 - Prob. 33ECh. 13 - Prob. 34ECh. 13 - Indicate whether each statement is true or false:...Ch. 13 - 13.36 Indicate whether each statement is true or...Ch. 13 - The Henry’s law constant for helium gas in water...Ch. 13 - Prob. 38ECh. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - Prob. 42ECh. 13 - 13.43 Calculate the morality of the following...Ch. 13 - Prob. 44ECh. 13 - Calculate the molality of each of the following...Ch. 13 - (a) What is the molality of a solution formed by...Ch. 13 - Prob. 47ECh. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - The density of toluene (C7H8) is 0.867 g\mL, and...Ch. 13 - Calculate the number of moles of solute present in...Ch. 13 - Calculate the number of moles of solute present in...Ch. 13 - Prob. 53ECh. 13 - Describe how you would prepare each of the...Ch. 13 - Commercial aqueous nitric acid has a density of...Ch. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - Consider two solutions, one formed by adding 10 g...Ch. 13 - Prob. 64ECh. 13 - Prob. 65ECh. 13 - (a) Calculate the vapor pressure of water above a...Ch. 13 - Prob. 67ECh. 13 - At 20 oC, the vapor pressure of benzene (C6 H6) is...Ch. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 - Prob. 71ECh. 13 - Prob. 72ECh. 13 - Using data from Table 13.3, calculate the freezing...Ch. 13 - Prob. 74ECh. 13 - Prob. 75ECh. 13 - Prob. 76ECh. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Prob. 79ECh. 13 - Lauryl alcohol is obtained from coconut oil and is...Ch. 13 - Prob. 81ECh. 13 - Prob. 82ECh. 13 - The osmotic pressure of a 0.010 M aqueous solution...Ch. 13 - Based on the given data in Table 13.4, which...Ch. 13 - (a) Do colloids made only of gases exist? Why or...Ch. 13 - Prob. 86ECh. 13 - An “emulsifying agent” is a compound that helps...Ch. 13 - Aerosols are important components of the...Ch. 13 - Prob. 89ECh. 13 - Soaps consist of compounds such as sodium state,...Ch. 13 - Prob. 91AECh. 13 - Prob. 92AECh. 13 - Most fish need at least 4 ppm dissolved O2 in...Ch. 13 - The presence of the radioactive gas radon (Rn) in...Ch. 13 - Prob. 95AECh. 13 - Prob. 96AECh. 13 - The maximum allowable concentration of lead in...Ch. 13 - Prob. 98AECh. 13 - Prob. 99AECh. 13 - Prob. 100AECh. 13 - Prob. 101AECh. 13 - The normal boiling point of ethanol, is 78.4 0C....Ch. 13 - Prob. 103AECh. 13 - Carbon disulfide (CS2) boils at 46.30 o C and has...Ch. 13 - Prob. 105AECh. 13 - Prob. 106IECh. 13 - At ordinary body temperature (37 o C), the...Ch. 13 - Prob. 108IECh. 13 - Prob. 109IECh. 13 - Prob. 110IECh. 13 - Prob. 111IECh. 13 - Prob. 112IECh. 13 - At 35 o C the vapor pressure of acetone, (CH3)2CO,...Ch. 13 - Prob. 114IE
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