Concept explainers
(a)
Interpretation:
The reaction of ethanal with Tollens’ reagent has to be written.
Concept Introduction:
Tollens’ reagent is basic solution of silver ammonia complex. It is mainly used for oxidation of aldehydes. The silver ion is reduced to silver metal as the aldehyde is oxidized to a carboxylate anion. Silver metal precipitates from the solution and coats the flask, producing a smooth silver mirror. The test is often called tollens’ silver mirror test.
Ketones cannot be oxidized acids and do not react with the tollens’ reagent.
The general reaction is,
(b)
Interpretation:
The reaction of propanone with Tollens’ reagent has to be written.
Concept Introduction:
Refer to part (a).

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Chapter 13 Solutions
GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
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