(a) Interpretation: All constitutional isomers formed by the monochlorination of given alkane is to be drawn. Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C − H sigma bond of the alkane.

Question

81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia

Answer 1

Question

Chapter 13.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Answer 2

Question

Chapter 13.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 3

Question

Chapter 13.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 4

Question

Chapter 13.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 5

Chapter 13.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 6

Chapter 13.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Answer 7

Chapter 13.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Answer 8

Interpretation Introduction

(b)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 9

Interpretation Introduction

(b)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 10

Interpretation Introduction

(c)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 11

Interpretation Introduction

(c)

Interpretation: All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 12

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Ch. 13.1 - Prob. 1P Ch. 13.1 - Prob. 2P Ch. 13.2 - Prob. 3P Ch. 13.3 - Prob. 4P Ch. 13.3 - Prob. 5P Ch. 13.4 - Prob. 7P Ch. 13.5 - Problem 15.8 Which bond in the each compound is...Ch. 13.6 - Prob. 9P Ch. 13.6 - Prob. 10P Ch. 13.7 - Prob. 11P

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