(a) Interpretation: The most stable radical that can result from cleavage of C − H bond in the given molecule is to be drawn. Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1 ° , 2 ° or 3 ° depending upon the number of alkyl groups attached to it. As number of alkyl substitutents increases, the stability of radical also increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

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Answer 1

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Chapter 13.1, Problem 2P

Interpretation Introduction

(a)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. As number of alkyl substitutents increases, the stability of radical also increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(b)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(c)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(d)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

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Г C-RSA CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0.0 b.092 0.797 1.088 1.813 C-RSA CHROMATOPAC CH=1 Report No. =13 ** CALCULATION REPORT ** DATA=1: @CHRM1.000 11/03/05 08:09:52 CH PKNO TIME 1 2 0.797 3 1.088 4 1.813 AREA 1508566 4625442 2180060 HEIGHT 207739 701206 V 287554 V MK IDNO CONC NAME 18.1447 55.6339 26.2213 TOTAL 8314067 1196500 100 C-R8A CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0. 0 087 337. 0.841 1.150 C-R8A CHROMATOPAC CH=1 Report No. =14 DATA=1: @CHRM1.000 11/03/05 08:12:40 ** CALCULATION REPORT ** CH PKNO TIME AREA 1 3 0.841 1099933 41.15 4039778 HEIGHT MK IDNO 170372 649997¯¯¯ CONC NAME 21.4007 78.5993 TOTAL 5139711 820369 100 3 C-R8A CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0.100 0:652 5.856 3 1.165 C-RSA CHROMATOPAC CH-1 Report No. =15 DATA=1: @CHRM1.000 11/03/05 08:15:26 ** CALCULATION REPORT ** CH PKNO TIME AREA HEIGHT MK IDNO CONC NAME 1 3 3 0.856 4 1.165 TOTAL 1253386 4838738 175481 708024 V 20.5739 79.4261 6092124…

Draw the product of the reaction shown below. Ignore small byproducts that would evaporate please.

Relative Abundance 20- Problems 501 (b) The infrared spectrum has a medium-intensity peak at about 1650 cm. There is also a C-H out-of-plane bending peak near 880 cm. 100- 80- 56 41 69 M(84) LL 15 20 25 30 35 55 60 65 70 75 80 85 90 m/z

Answer 2

Question

Chapter 13.1, Problem 2P

Interpretation Introduction

(a)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. As number of alkyl substitutents increases, the stability of radical also increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(b)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(c)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(d)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

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Answer 3

Question

Chapter 13.1, Problem 2P

Interpretation Introduction

(a)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. As number of alkyl substitutents increases, the stability of radical also increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(b)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(c)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(d)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

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Answer 4

Question

Chapter 13.1, Problem 2P

Interpretation Introduction

(a)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. As number of alkyl substitutents increases, the stability of radical also increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(b)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(c)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(d)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

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Answer 5

Chapter 13.1, Problem 2P

Interpretation Introduction

(a)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. As number of alkyl substitutents increases, the stability of radical also increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(b)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(c)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Interpretation Introduction

(d)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Answer 6

Chapter 13.1, Problem 2P

Interpretation Introduction

(a)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. As number of alkyl substitutents increases, the stability of radical also increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Answer 7

Chapter 13.1, Problem 2P

Interpretation Introduction

(a)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. As number of alkyl substitutents increases, the stability of radical also increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Answer 8

Interpretation Introduction

(b)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Answer 9

Interpretation Introduction

(b)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Answer 10

Interpretation Introduction

(c)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Answer 11

Interpretation Introduction

(c)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Answer 12

Interpretation Introduction

(d)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Answer 13

Interpretation Introduction

(d)

Interpretation: The most stable radical that can result from cleavage of C−H bond in the given molecule is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Answer 14

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Answer 17

Ch. 13.1 - Prob. 1P Ch. 13.1 - Prob. 2P Ch. 13.2 - Prob. 3P Ch. 13.3 - Prob. 4P Ch. 13.3 - Prob. 5P Ch. 13.4 - Prob. 7P Ch. 13.5 - Problem 15.8 Which bond in the each compound is...Ch. 13.6 - Prob. 9P Ch. 13.6 - Prob. 10P Ch. 13.7 - Prob. 11P

Solution Summary: The author explains that a free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond.

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