Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 13, Problem 7E
Explain why an equilibrium between
would not be established if the container were not a closed vessel shown in Figure 13.4.
Figure 13.4.A sealed tube containing an equilibrium mixture of liquid and gaseous bromine. (credit: http://images-of-elements.com/bromine.php)
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may you please show all steps! i am having a hard time understanding and applying in this format, thank you!
10. Complete the substitution reaction of 2 pentanol with these reagents.
Reagents & Reaction Conditions use practice sheet. Please write only
major products, minor product like water, other gases are not
required.
Hint: In substitution of alcohol, we generally substitute OH group
with Halogens like cl, Br, F using some reagent containing
halogens. Ensure to add halogens to the same carbon number
where you are removing OH from
Examples
Alcohols can be converted to Alkyl Halides with HX acids
HBr
H₂O
HCI
+ H₂O
HI
+
H₂O
CH,CH₂OH + SOCI₂
CH,CH₂OH + PCI₁₂
A
BBYJU'S
CH CHCI + SO₂+ HCI
CH₂CH CIP(OH), + HCI
CH,CH₂OH + PCI CHCHCI + POCI + HCI
CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr
1. Reaction with HBr with 2 Pentanol
2.Reaction with HI with 2 pentanol
© Byjus.com
3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role)
4.Reaction with SOCI,, with 2 Pentanol
5.Reaction with PBr; or PCl, with 2 pentanol
3. Is 2-methyl-2-propanol a primary, secondary, or tertiary alcohol? Write
out the
structures of 2-methyl-2-propanol and also any oxidation products of 2-
methyl-2-
propanol. If there is more than one oxidation product, give the structure of
each
of the products.
4. 2-Propanol is the IUPAC systematic name of this alcohol. It has a
common name
by which it is much better known (You'll see it in the grocery store or
pharmacy).
Give that common name
5. Aldehydes can be synthesized by the oxidation of. Please choose from
below choices
A. Primary alcohols
B. Secondary alcohols
C. Organic acids
D. Inorganic acids
6. Tertiary alcohol Can undergo oxidation. yes or no. ? If yes then answer the
product.
Chapter 13 Solutions
Chemistry Atoms First2e
Ch. 13 - What does it mean to describe a reaction as...Ch. 13 - When writing an equation, how is a reversible...Ch. 13 - If a reaction is reversible, when can it be said...Ch. 13 - Is a system at equilibrium if the rate constants...Ch. 13 - If the concentrations of products and reactants...Ch. 13 - Explain why there may be an infinite number of...Ch. 13 - Explain why an equilibrium between Br2(l)andBr2(g)...Ch. 13 - If you observe the following reaction at...Ch. 13 - Among the solubility rules previously discussed is...Ch. 13 - Among the solubility rules previously discussed is...
Ch. 13 - Benzene is one of the compounds used as octane...Ch. 13 - Show that the complete chemical equation, the...Ch. 13 - For a titration to be effective, the reaction must...Ch. 13 - For a precipitation reaction to be useful in a...Ch. 13 - Write the mathematical expression for the reaction...Ch. 13 - Write the mathematical expression for the reaction...Ch. 13 - The initial concentrations or pressures of...Ch. 13 - The initial concentrations or pressures of...Ch. 13 - The following reaction has KP=4.5010-5at720K ....Ch. 13 - Determine if the following system is at...Ch. 13 - Which of the systems described in Exercise 13.15...Ch. 13 - Which of the systems described in Exercise 13.16...Ch. 13 - For which of the reactions in Exercise 13.15 does...Ch. 13 - For which of the reactions in Exercise 13.16 does...Ch. 13 - Convert the values of KC to values of KP to the...Ch. 13 - Covert the values of Kc to the values of KP or the...Ch. 13 - What is the value of the equilibrium constant...Ch. 13 - Write the expression of the reaction quotient for...Ch. 13 - Write the reaction quotient expression for the...Ch. 13 - What is the approximate value of the equilibrium...Ch. 13 - The following equation represents a reversible...Ch. 13 - Explain how to recognize the conditions under...Ch. 13 - What property of a reaction can we use to predict...Ch. 13 - The following reaction occurs when a burner on a...Ch. 13 - A necessary step in the manufacture of sulfuric...Ch. 13 - Suggest four ways in which the concentration of...Ch. 13 - Suggest four ways in which the concentration of...Ch. 13 - How will an increase in temperature affect each of...Ch. 13 - How will an increase in temperature affect each of...Ch. 13 - Methanol can be prepared from carbon monoxide and...Ch. 13 - Nitrogen and oxygen react at high temperatures....Ch. 13 - Water gas, a mixture of H2 and CO, is an important...Ch. 13 - Pure iron metal can be produced by the reduction...Ch. 13 - Ammonia is a weak base that reacts with water...Ch. 13 - Acetic acid is a weak acid that reacts with water...Ch. 13 - Suggest two ways in which the equilibrium...Ch. 13 - How can the pressure of water vapor be increased...Ch. 13 - A solution is saturated with silver sulfate and...Ch. 13 - The amino acid alanine has two isomers, -alanine...Ch. 13 - A reaction is represented by this equation:...Ch. 13 - A reaction is represented by this equation:...Ch. 13 - What is the value of the equilibrium constant at...Ch. 13 - Hydrogen is prepared commercially by the reaction...Ch. 13 - A 0.72-m01 sample of PCl5 is put into a 1.00-L...Ch. 13 - At 1 atm and 25 C, NO2 with an initial...Ch. 13 - Calculate the value of the equilibrium constant Kp...Ch. 13 - When heated, iodine vapor dissociates according to...Ch. 13 - A sample of ammonium chloride was heated in a...Ch. 13 - At a temperature of 60 C, the vapor pressure of...Ch. 13 - Complete the changes in concentrations (or...Ch. 13 - Complete the changes in concentrations (or...Ch. 13 - Why are there no changes specified for Ni in...Ch. 13 - Why are there no changes specified for NH4HS in...Ch. 13 - Analysis of the gases in a sealed reaction vessel...Ch. 13 - Calculate the number of moles of HI that are at...Ch. 13 - What is the pressure of BrCl in an equilibrium...Ch. 13 - What is the pressure of CO2 in a mixture at...Ch. 13 - Cobalt metal can be prepared by reducing cobalt...Ch. 13 - Carbon reactswith water vapor at elevated...Ch. 13 - Sodium sulfate 10-hydrate, Na2SO410H2O, dehydrates...Ch. 13 - Calcium chloride 6-hydrate, CaC12.6H2O, dehydrates...Ch. 13 - A student solved the following problem and found...Ch. 13 - A student solved the following problem and found...Ch. 13 - Assume that the change in concentration of N2O4 is...Ch. 13 - Assume that the change in concentration of COC12...Ch. 13 - Assume that the change in pressure of H2S is small...Ch. 13 - What are all concentrations after a mixture that...Ch. 13 - Calculate the number of grams of HI that are at...Ch. 13 - Butane exists as two isomers, n -butane and...Ch. 13 - What is the minimum mass of CaCO3 required to...Ch. 13 - The equilibrium constant (Kc) for this reaction is...Ch. 13 - In a 3.0-L vessel, the following equilibrium...Ch. 13 - The equilibrium constant (Kc) for this reaction is...Ch. 13 - Antimony pentachloride decomposes according to...Ch. 13 - Consider the equilibrium...Ch. 13 - The binding of oxygen by hemoglobin (Hb), giving...Ch. 13 - Liquid N2o3 is dark blue at low temperatures, but...Ch. 13 - A 1.00-L vessel at 400C contains the following...Ch. 13 - Calculate the equilibrium constant at 25 C for...Ch. 13 - Calculate the equilibrium constant at the...Ch. 13 - Calculate the equilibrium constant at the...Ch. 13 - Consider the following reaction at 298 K:...Ch. 13 - Determine the normal boiling point (inkelvin) of...Ch. 13 - Under what conditions is N2O3(g)NO(g)+NO2(g)...Ch. 13 - At room temperature, the equilibrium constant (Kw)...Ch. 13 - Hydrogen sulfide is a pollutant found in natural...Ch. 13 - Consider the decomposition of CaCO3(s) into...Ch. 13 - In the laboratory, hydrogen chloride (HCl(g)) and...Ch. 13 - Benzene can be prepared from acetylene....Ch. 13 - Carbon dioxide decomposes into CO and O2 at...Ch. 13 - Carbon tetrachloride, an important industrial...Ch. 13 - Acetic acid, CH3CO2H, Can form a dimer,...
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- Finish the reactions hand written pleasearrow_forwardPart A Identify each alcohol as primary, secondary, or tertiary Drag the appropriate items to their respective bins. CH₂ H₂C- -C-OH HO CH₂ Primary Он OH CH₂ OH CCH₂OH CH₂ сн Secondary Tertiary Reset Help CH,CH₂ (CH)CHCH,OH CH,CH,CH,CCH, CHOH CH₂ Different types of alcohol groups Alcohol and its reaction: 8. Combing two alcohol molecules below and completing the reaction with Product .( Hint Reaction called etherification as ether is formed and name the ether once you complete the reaction. Hint.: R-O-H+H-O-RR-O-R Do the reaction: CH₂OH + CH₂OH---→ + H-O-H 9. Write the reaction of formation of alcohol from alkene by adding water: Addition reaction also called hydration reaction as we are adding water which occur always in presence of acid Hint: Break the double bond and add H and OH if symmetrical then add anywhere if unsymmetrical then follow Markovnikov rule H should go to that double bone carbon which has more hydrogen CH2=CH2 + H₂O-→arrow_forwardComplete the reaction hand written pleasearrow_forward
- Predict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forwardb) Use curved arrows to show the reaction of the radical with hydrogen bromide. Br: Br H .. Answer Bankarrow_forwardIndicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+arrow_forward
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