ORGANIC CHEMISTRY
6th Edition
ISBN: 9781260826791
Author: SMITH
Publisher: MCG
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Write the empirical formula of at least four binary ionic compounds that could be formed from the following ions:
Ca²+, Al³+, CI¯, s²-
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SQ 3-The balanced chemical equation for the reaction of sodium bicarbonate and citric acid is below.
3 NaHCO3(aq) + C6H807(s) → Na3C6H5O7(aq) + 3H₂O(l) + 3CO2(g)
=
SQ 4-Write the Lewis Structure for all species in the net ionic equation.
Reactants:
Products:
K
SQ 5-Circle the bonds that are broken in the reactants and the bonds that are formed in the products.
Part II: Binary Covalent Compounds
Covalent compounds are produces by nonmetals bonding with one another. You can use the valence
electrons for each element to determine the simplest formula that exists between two elements. For
example, H has 1 valence electron and needs one more to obey the Octet Rule, so it will only make 1
bond when found in a compound. Oxygen has 6 valence electrons and needs two more to obey the
Octet Rule, so it typically makes 2 bonds when found in a compound. Since hydrogen needs just one
electron while oxygen needs two, the correct formula for the simplest compound would be H20.
However, there are often other combinations possible in addition to the simplest formula. For
example, hydrogen and oxygen can also form, H2O2, which is known as hydrogen peroxide. To work
with all the possible combinations, some rules have been developed for naming binary covalent
compounds. The rules are stated below:
1. The least metallic element will always end in the suffix…
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- Each compound contains both ions and covalent bonds. Draw the Lewis structure for each compound. Show with dashes which are covalent bonds and show with charges which are ions. (a) Sodium methoxide, CH3ONa (b) Ammonium chloride, NH4Cl (c) Sodium bicarbonate, NaHCO3 (d) Sodium borohydride, NaBH4 (e) Lithium aluminum hydride, LiAlH4arrow_forward3-78 Nitrous oxide, N20, laughing gas, is a colorless, nontoxic, tasteless, and odorless gas. It is used as an inhalation anesthetic in dental and other surgeries. Because nitrous oxide is soluble in vegetable oils (fats), it is used commercially as a propellant in whipped toppings Nitrous oxide dissolves in fats. The gas is added under pressure to cans of whipped topping. When the valve is opened, the gas expands, thus expanding (whipping) the topping and forcing it out of the can. (a) How many valence electrons are present in a molecule of N20? (b) Write two equivalent contributing structures for this molecule. The connectivity in nitrous oxide is NNO. (c) Explain why the following is not an acceptable contributing structure:arrow_forwardDraw Lewis structures to illustrate the covalent bonding in the following diatomic molecules. a. Cl2 b. HCl c. BrCl d. ClFarrow_forward
- Describe the molecular structure around the indicated atom or atoms: (a) the sulfur atom in sulfuric acid, H2SO4[(HO)2SO2] (b) the chlorine atom in chloric acid, HClO3[HOClO2] (c) the oxygen atom in hydrogen peroxide, HNO3[HONO2] (d) the nitrogen atom in nitric acid, HNO3[HONO2] (e) the oxygen atom in the OH group in nitric acid, HNO3[HONO2] (f) the central oxygen atom in the ozone molecule, O3 (g) each of the carbon atoms in propyne, CH3CCH (h) the carbon atom in Freon, CCl2F2 (i) each of the carbon atoms in aliene, H2CCH2arrow_forwardClassify each of the following bonds as nonpolar covalent, polar covalent, or ionic on the basis of electronegativity differences. a. ClF b. PH c. CH d. CaOarrow_forwardWhat is the difference between sulfuric acid and hydrosulfuric acid?arrow_forward
- Among the following, identify all hydrates and anhydrous compounds: NiSO4.6H2O, KCl, Na3PO4.12H2Oarrow_forwardCholesterol (C27H46O) has the following structure: In such shorthand structures, each point where lines meet represents a carbon atom, and most H atoms are not shown. Draw the complete structure showing all carbon and hydrogen atoms. (There will be four bonds to each carbon atom.)arrow_forward3-77 Ozone, O3, is an unstable blue gas with a characteristic pungent odor. In an ozone molecule, the connectivity of the atoms is OOO and both OO bonds are equivalent. (a) How many valence electrons must be present in an acceptable Lewis structure for an ozone molecule? (b) Write two equivalent resonance contributing structures for ozone. Be certain to show any positive or negative charges that may be present in your contributing structures. By equivalent contributing structures, we mean that each has the same pattern of bonding. (c) Show by the use of curved arrows how the first of your contributing structures may be converted to the second. (d) Based on your contributing structures, predict the OOO bond angle in ozone. (e) Explain why the following is not an acceptable contributing structure for an ozone molecule:arrow_forward
- Successive substitution of F atoms for H atoms in the molecule CH4 produces the molecules CH3F, CH2F2, CHF3, and CF4. a. Draw Lewis structures for each of the five molecules. b. Using VSEPR theory, predict the geometry of each of the five molecules. c. Specify the polarity (polar or nonpolar) for each of the five molecules.arrow_forwardDraw Lewis structures to illustrate the covalent bonding in the following diatomic molecules. a. Br2 b. HBr c. BrF d. IBrarrow_forward2.61 Name the following covalent compounds: (a) N2O5, (b) S2Cl2, (c) NBr3, (d) P4O10arrow_forward
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