EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 9781260475685
Author: SMITH
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 13, Problem 54P

Consider the following bromination: ( CH 3 ) 3 CH + Br 2 Δ ( CH 3 ) 3 CBr + HBr .

a. Calculate Δ H ο for this reaction by using the bond dissociation energies in Table 6.2.

b. Draw out a stepwise mechanism for the reaction, including the initiation, propagation, and termination steps.

c. Calculate Δ H ο for each propagation step.

d. Draw an energy diagram for the propagation steps.

e. Draw the structure of the transition state of each propagation step.

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