A Small Scale Approach to Organic Laboratory Techniques
A Small Scale Approach to Organic Laboratory Techniques
4th Edition
ISBN: 9781305799875
Author: Donald L. Pavia; George S. Kriz; Gary M. Lampman
Publisher: Cengage Learning US
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Chapter 13, Problem 4Q
Interpretation Introduction

Interpretation:

The boiling point for caryophyllene needs to be determined. If the reported boiling point is not at atmospheric pressure, it must be corrected to 760 mm Hg.

Concept Introduction:

The structure of caryophyllene, a terpene is represented as follows:

  A Small Scale Approach to Organic Laboratory Techniques, Chapter 13, Problem 4Q

The boiling point of caryophyllene is 129-1300C at 14 mm Hg. According to a rule of thumb, for many liquids, the boiling point drops approximately 0.5 oC for 10 mm decrease in pressure.

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