Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card
5th Edition
ISBN: 9781305367487
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 13, Problem 38QRT
Interpretation Introduction
Interpretation:
The value of
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
metal:
a) Tris(acetylacetonato)iron(III)
b) Hexabromoplatinate(2-)
c) Potassium diamminetetrabromocobaltate(III)
(6 points)
2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation
constant for [Fe(CN)6] 4 is ~1032, and that:
Fe3+ (aq) + e
= Fe²+ (aq)
E° = +0.77 V
[Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V
(4 points)
Chapter 13 Solutions
Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card
Ch. 13.1 - How could the data in Table 13.2 be used to...Ch. 13.1 - Prob. 13.2CECh. 13.1 - Prob. 13.1PSPCh. 13.1 - Prob. 13.2PSPCh. 13.2 - Prob. 13.3ECh. 13.2 - Determine whether each of these masses of NH4Cl...Ch. 13.4 - Prob. 13.5CECh. 13.4 - Explain why water that has been used to cool a...Ch. 13.4 - If a substance has a positive enthalpy of...Ch. 13.5 - Suppose that a trout stream at 25 C is in...
Ch. 13.6 - Prob. 13.4PSPCh. 13.6 - Prob. 13.8ECh. 13.6 - Drinking water may contain small quantities of...Ch. 13.6 - Prob. 13.9CECh. 13.6 - A 500-mL bottle of Evian bottled water contains 12...Ch. 13.6 - The mass fraction of gold in seawater is 1 103...Ch. 13.6 - Prob. 13.6PSPCh. 13.6 - Prob. 13.7PSPCh. 13.6 - Prob. 13.8PSPCh. 13.6 - Prob. 13.9PSPCh. 13.6 - Prob. 13.12ECh. 13.6 - Prob. 13.13CECh. 13.7 - The vapor pressure of an aqueous solution of urea....Ch. 13.7 - Prob. 13.14ECh. 13.7 - Prob. 13.15ECh. 13.7 - Prob. 13.11PSPCh. 13.7 - Suppose that you are closing a cabin in the north...Ch. 13.7 - A student determines the freezing point to be 5.15...Ch. 13.7 - Prob. 13.17CECh. 13.7 - Prob. 13.13PSPCh. 13.9 - Prob. 13.18CECh. 13.10 - Prob. 13.19ECh. 13.10 - Prob. 13.20ECh. 13 - Prob. 1QRTCh. 13 - Prob. 2QRTCh. 13 - Prob. 3QRTCh. 13 - Prob. 4QRTCh. 13 - Prob. 5QRTCh. 13 - Prob. 6QRTCh. 13 - Prob. 7QRTCh. 13 - Prob. 8QRTCh. 13 - Prob. 9QRTCh. 13 - Prob. 10QRTCh. 13 - Prob. 11QRTCh. 13 - Prob. 12QRTCh. 13 - Prob. 13QRTCh. 13 - Prob. 14QRTCh. 13 - Beakers (a), (b), and (c) are representations of...Ch. 13 - Prob. 16QRTCh. 13 - Simple acids such as formic acid, HCOOH, and...Ch. 13 - Prob. 18QRTCh. 13 - Prob. 19QRTCh. 13 - Prob. 20QRTCh. 13 - Prob. 21QRTCh. 13 - Prob. 22QRTCh. 13 - Prob. 23QRTCh. 13 - Prob. 24QRTCh. 13 - Prob. 25QRTCh. 13 - Prob. 26QRTCh. 13 - Refer to Figure 13.10 ( Sec. 13-4b) to answer...Ch. 13 - Prob. 28QRTCh. 13 - Prob. 29QRTCh. 13 - Prob. 30QRTCh. 13 - The Henrys law constant for nitrogen in blood...Ch. 13 - Prob. 32QRTCh. 13 - Prob. 33QRTCh. 13 - Prob. 34QRTCh. 13 - Prob. 35QRTCh. 13 - Prob. 36QRTCh. 13 - Prob. 37QRTCh. 13 - Prob. 38QRTCh. 13 - Prob. 39QRTCh. 13 - Prob. 40QRTCh. 13 - A sample of water contains 0.010 ppm lead ions,...Ch. 13 - Prob. 42QRTCh. 13 - Prob. 43QRTCh. 13 - Prob. 44QRTCh. 13 - Prob. 45QRTCh. 13 - Prob. 46QRTCh. 13 - Prob. 47QRTCh. 13 - Prob. 48QRTCh. 13 - Prob. 49QRTCh. 13 - Prob. 50QRTCh. 13 - Consider a 13.0% solution of sulfuric acid,...Ch. 13 - You want to prepare a 1.0 mol/kg solution of...Ch. 13 - Prob. 53QRTCh. 13 - Prob. 54QRTCh. 13 - Prob. 55QRTCh. 13 - A 12-oz (355-mL) Pepsi contains 38.9 mg...Ch. 13 - Prob. 57QRTCh. 13 - Prob. 58QRTCh. 13 - Prob. 59QRTCh. 13 - Prob. 60QRTCh. 13 - Prob. 61QRTCh. 13 - Prob. 62QRTCh. 13 - Prob. 63QRTCh. 13 - Prob. 64QRTCh. 13 - Prob. 65QRTCh. 13 - Prob. 66QRTCh. 13 - Calculate the boiling point and the freezing point...Ch. 13 - Prob. 68QRTCh. 13 - Prob. 69QRTCh. 13 - Prob. 70QRTCh. 13 - Prob. 71QRTCh. 13 - Prob. 72QRTCh. 13 - The freezing point of p-dichlorobenzene is 53.1 C,...Ch. 13 - Prob. 74QRTCh. 13 - Prob. 75QRTCh. 13 - A 1.00 mol/kg aqueous sulfuric acid solution,...Ch. 13 - Prob. 77QRTCh. 13 - Prob. 78QRTCh. 13 - Prob. 79QRTCh. 13 - Prob. 80QRTCh. 13 - Prob. 81QRTCh. 13 - Differentiate between the dispersed phase and the...Ch. 13 - Prob. 83QRTCh. 13 - Prob. 84QRTCh. 13 - Prob. 85QRTCh. 13 - Prob. 86QRTCh. 13 - Prob. 87QRTCh. 13 - Prob. 88QRTCh. 13 - Prob. 89QRTCh. 13 - Prob. 90QRTCh. 13 - Prob. 91QRTCh. 13 - Prob. 92QRTCh. 13 - Prob. 93QRTCh. 13 - Prob. 94QRTCh. 13 - Prob. 95QRTCh. 13 - Prob. 96QRTCh. 13 - Prob. 97QRTCh. 13 - Prob. 98QRTCh. 13 - Prob. 99QRTCh. 13 - Prob. 100QRTCh. 13 - Prob. 101QRTCh. 13 - Prob. 102QRTCh. 13 - In The Rime of the Ancient Mariner the poet Samuel...Ch. 13 - Prob. 104QRTCh. 13 - Prob. 105QRTCh. 13 - Calculate the molality of a solution made by...Ch. 13 - Prob. 107QRTCh. 13 - Prob. 108QRTCh. 13 - Prob. 109QRTCh. 13 - Prob. 110QRTCh. 13 - The organic salt [(C4H9)4N][ClO4] consists of the...Ch. 13 - A solution, prepared by dissolving 9.41 g NaHSO3...Ch. 13 - A 0.250-M sodium sulfate solution is added to a...Ch. 13 - Prob. 114QRTCh. 13 - Prob. 115QRTCh. 13 - Prob. 116QRTCh. 13 - Prob. 117QRTCh. 13 - Prob. 118QRTCh. 13 - Prob. 119QRTCh. 13 - Refer to Figure 13.10 ( Sec. 13-4b) to determine...Ch. 13 - Prob. 121QRTCh. 13 - Prob. 122QRTCh. 13 - Prob. 123QRTCh. 13 - Prob. 124QRTCh. 13 - In your own words, explain why (a) seawater has a...Ch. 13 - Prob. 126QRTCh. 13 - Prob. 127QRTCh. 13 - Prob. 128QRTCh. 13 - Prob. 129QRTCh. 13 - Prob. 130QRTCh. 13 - Prob. 131QRTCh. 13 - A 0.109 mol/kg aqueous solution of formic...Ch. 13 - Prob. 133QRTCh. 13 - Maple syrup sap is 3% sugar (sucrose) and 97%...Ch. 13 - Prob. 137QRTCh. 13 - Prob. 13.ACPCh. 13 - Prob. 13.BCPCh. 13 - Prob. 13.CCP
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