CHEMISTRY+CHEM...HYBRID ED.(LL)>CUSTOM<
9th Edition
ISBN: 9781305020788
Author: John C.Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: CENGAGE C
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Textbook Question
Chapter 1.3, Problem 2RC
Which of the following is not characteristic of a pure substance?
- (a) Has a uniform composition throughout
- (b) Has a fixed melting temperature
- (c) Can be separated into two other pure substances
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19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water?
Group of answer choices
LiBr
LiI
LiF
LiCl
Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism
of the reactions.
Br
MeOH
OSO2CH3
MeOH
Chapter 1 Solutions
CHEMISTRY+CHEM...HYBRID ED.(LL)>CUSTOM<
Ch. 1.3 - Which of the following is a pure substance? (a)...Ch. 1.3 - Which of the following is not characteristic of a...Ch. 1.4 - Prob. 1RCCh. 1.4 - Prob. 2RCCh. 1.5 - Prob. 1RCCh. 1.5 - 2. Which of the following is NOT a...Ch. 1.6 - Which of the following is NOT a physical property?...Ch. 1.6 - 2. A piece of a polypropylene rope (used for water...Ch. 1.6 - Which of the following is an extensive property of...Ch. 1.7 - When camping in the mountains, you boil a pot of...
Ch. 1.8 - Much has been written about CO2.What is its name?Ch. 1.8 - Prob. 2QCh. 1.8 - Prob. 3QCh. 1.8 - The spines of the sea urchin, corals, and...Ch. 1.8 - Which of the following has the highest thermal...Ch. 1.8 - Prob. 2RCCh. 1 - Give the name of each of the following elements:...Ch. 1 - Give the name of each of the following elements:...Ch. 1 - Give the symbol for each of the following...Ch. 1 - Give the symbol for each of the following...Ch. 1 - In each of the following pairs, decide which is an...Ch. 1 - In each of the following pairs, decide which is an...Ch. 1 - In each case, decide if the underlined property is...Ch. 1 - In each case, decide if the change is a chemical...Ch. 1 - Which part of the description of a compound or...Ch. 1 - Which part of the description of a compound or...Ch. 1 - The flashlight in the photo does not use...Ch. 1 - A solar panel is pictured in the photo. When light...Ch. 1 - Determine which of the following represent...Ch. 1 - Prob. 14PSCh. 1 - Prob. 15GQCh. 1 - Iron pyrite (fool's gold, page 11) has a shiny...Ch. 1 - Which observations below describe chemical...Ch. 1 - Which observations below describe chemical...Ch. 1 - The mineral fluorite contains the elements calcium...Ch. 1 - Azurite, a blue, crystalline mineral, is composed...Ch. 1 - You have a solution of NaCI dissolved in water....Ch. 1 - Small chips of iron are mixed with sand (see...Ch. 1 - Identify the following as either physical changes...Ch. 1 - Identify the following as either physical changes...Ch. 1 - In Figure 1.2 you see a piece of salt and a...Ch. 1 - In Figure 1.5 you see macroscopic and particulate...Ch. 1 - Prob. 27GQCh. 1 - The following photo shows copper balls, immersed...Ch. 1 - Categorize each of the following as an element, a...Ch. 1 - Categorize each of the following as an element, a...Ch. 1 - Make a drawing, based on the kinetic-molecular...Ch. 1 - Make a drawing, based on the kinetic-molecular...Ch. 1 - Hexane (C6H14, density = 0.766 g/cm3),...Ch. 1 - You have a sample of a white crystalline substance...Ch. 1 - You can figure out whether a solid floats or sinks...Ch. 1 - You are given a sample of a silvery metal. What...Ch. 1 - Milk in a glass bottle was placed in the freezing...Ch. 1 - Describe an experimental method that can be used...Ch. 1 - Diabetes can alter the density of urine, so urine...Ch. 1 - Prob. 40GQCh. 1 - The following photo shows the element potassium...Ch. 1 - Prob. 42GQCh. 1 - Four balloons are each filled with a different...Ch. 1 - Prob. 44GQCh. 1 - The photo below shows elemental iodine dissolving...Ch. 1 - A few years ago a young chemist in Vienna,...
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